Abstract
N,N′-Dioctyl-3,4,9,10 perylenedicarboximide (PTCDI-C8) organic semiconductor have vast applications in solar cells, thermoelectric generators, thin film photovoltaics and many other optoelectronic devices. These applications of the materials are based on their spectral and optical properties. The solutions of the PTCDI-C8 for different molarities were prepared and the spectral and optical mesaurements were analyzed. Effects of the molarities on optical properties were investigated. Vibronic structure has been observed based on the absorption bands of PTCDI-C8 semiconductor with seven peaks at 2.292, 2.451, 2.616, 3.212, 3.851, 4.477 and 4.733 eV. The important spectral parameteres such as molar/mass extinction coefficients, absorption coefficient of the PTCDI-C8 molecule were calculated. Optical properties such as angle of incidence/refraction, optical band gap, real and imaginary parts of dielectric constant, loss factor and electrical susceptibility of the the PTCDI-C8 were obtained. Finally, we discussed these parameters for optoelectronic applications and compared with related parameters in literature.
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T. Hori, T. Masuda, N. Fukuoka, T. Hayashi, Y. Miyake, T. Kamikado, H. Yoshida, A. Fujii, Y. Shimizu, and M. Ozaki, Org. Electron. 13, 335 (2012).
M. Leclerc and A. Najari, Nat. Mater. 10, 409 (2011).
K. Sulaiman, Z. Ahmad, M. S. Fakir, F. A. Wahab, S. M. Abdullah, and Z. A. Rahman, Mater. Sci. Forum 737, 126 (2013).
A. Datar, R. Oitker, and L. Zang, Chem. Commun. 50, 1649 (2006).
R. Rahimi, V. Narang, and D. Korakakis, Int. J. Photoenergy 2013, 205105 (2013).
T. N. Krauss, E. Barrena, X. N. Zhang, D. G. de Oteyza, J. Major, V. Dehm, F. Würthner, L. P. Cavalcanti, and H. Dosch, Langmuir 24, 12742 (2008).
T. Abhijith, M. Yoosuf Ameen, and V. S. Reddy, IOP Conf. Series: Materials Science and Engineering 73, 012052 (2015).
K. Lament, W. Kaminski, P. Mazur, S. Zuber, and A. Ciszewski, Appl. Surf. Sci. 304, 50 (2014).
S. Pradhan, J. Redwine, J. T. McLeskey, and J. A. Dhar, Thin Solid Films 562, 423 (2014).
P. R. L. Malenfant, C. D. Dimitrakopoulos, J. D. Gelorme, L. L. Kosbar, T. O. Graham, A. Curioni, and W. Andreoni, Appl. Phys. Lett. 80, 2517 (2002).
S. Karak, V. S. Reddy, S. K. Ray, and A. Dhar, Org. Electron. 10, 1006 (2009).
S. Karak, S. K. Ray, and A. Dhar, Sol. Energ. Mat. Sol. C. 94, 836 (2010).
S. Karak, S. K. Ray, and A. Dhar, Appl. Phys. Lett. 97, 043306-1 (2010).
G. Boobalan, P. M. Imran, and S. Nagarajan, Superlattice. Microst. 51, 921 (2012).
M. Oltean, A. Calborean, G. Mile, M. Vidrighin, M. Iosin, L. Leopold, D. Maniu, N. Leopold, and V. Chi, Spectrochim. Acta A 97, 703 (2012).
B. Gündüz, Sens. Lett. 13, 52 (2015).
G. Boobalan, P. K. M. Imran, C. Manoharan, and S. Nagarajan, J. Colloid Interf. Sci. 393, 377 (2013).
S. S. Cheng, M. Ramesh, G. Y. Chen, C. L. Fung, L. M. Chen, M. C. Wu, H. C. Lin, and C. W. Chu, Org. Electron. 14, 2284 (2013).
M. Murugavelu, P. K. M. Imran, K. R. Sankaran, and S. Nagarajan, Mat. Sci. Semicon. Proc. 16, 461 (2013).
B. Gündüz, Polym. Advan. Technol. 27, 144 (2016).
A. Yeltik, S. Delikanli, M. Olutas, Y. Kelestemur, B. Guzelturk, and H. V. Demir, J. Phys. Chem. C 119, 26768 (2015).
A. Beer, Ann. Phys. 86, 78 (1852).
R. V. Maikala, Int. J. Ind. Ergonom. 40, 125 (2010).
B. Gündüz, Opt. Mater. 36, 425 (2013).
Y. Li, N. Scales, R. E. Blankenship, R. D. Willows, and M. Chen, Biochim. Biophys. Acta 1817, 1292 (2012).
B. Gündüz, Polym. Bull. 72, 3241 (2015).
M. El-Nahhas, H. Abdel-Khalek, and E. Salem, Am. J. Mater. Sci. 2, 131 (2012).
A. Moliton, Optoelectronics of Molecules and Polymers, Springer, New York, USA (2010).
F. Abeles, Optical Properties of Solids, North-Holland Publishing Company, Amsterdam, Netherlands (1972).
S. Adachi, Optical Constants of Crystalline and Amorphous Semiconductors, Kluwer Academic Publishers, Boston, USA (1999).
J. Tauc and A. Menth, J. Non-Cryst. Solids 8-10, 569 (1972).
J. P. Dakin and R. G. W. Brown, (Eds.) Handbook of Optoelectronics (two-volume set), CRC Press, London, UK (2006).
B. Gündüz, J. Nanoelectron. Optoe. 10, 1 (2015).
A. Kurt, Turk. J. Chem. 34, 67 (2010).
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Erdoğan, E., Gündüz, B. Controlling of the optical properties of the solutions of the PTCDI-C8 organic semiconductor. Electron. Mater. Lett. 12, 773–778 (2016). https://doi.org/10.1007/s13391-016-6146-6
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DOI: https://doi.org/10.1007/s13391-016-6146-6