Skip to main content

Advertisement

SpringerLink
Log in

Study of Acid–Rock Reaction Kinetics Under High Temperature and Pressure Conditions Based on the Rotating Disk Instrument

  • Research Article - Chemistry
  • Published:
Arabian Journal for Science and Engineering Aims and scope Submit manuscript

Abstract

In this paper, a rotating disk instrument was used to simulate the acid–rock reaction under high temperature and pressure reservoir conditions. By changing the reaction temperature, pressure, rotational speed and acid concentration, the reaction rate was measured first, and then the reaction parameters such as reaction rate constant, reaction order and effective mass transfer coefficient of H+ were analyzed through data processing and regression analysis; reaction kinetics equation was therefore obtained, and the effect of various factors on the acid–rock reaction rate were also analyzed. Test results indicated the following: Acid–rock reaction rate increased first and then decreased with acid concentration; minimum value of H+ effective mass transfer coefficient was found with the variation of rotational Reynolds number; the effect of pressure can be neglected when the pressure is above 6 MPa; reaction rate increases with the increase of reaction temperature, which shortened the effective time for acid reaction, but the conductivity can be enhanced by non-uniform etching.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kalfayan, L.J.: Fracture acidizing: history, present state, and future. In: SPE Hydraulic Fracturing Technology Conference (2007)

  2. Nasr-El-Din H.A., Al-Driweesh S.M., Metcalf A.S.: Fracture acidizing: what role does formation softening play in production response?. SPE Prod. Oper. 23(02), 184–191 (2008)

    Google Scholar 

  3. Milne, A.; Tellez, F.; Quevedo, M.: Hybrid matrix acidizing techniques successfully stimulate geothermal wells in Latin America. In: SPE International Symposium and Exhibition on Formation Damage Control (2014)

  4. Kamitsuji, R.; Yokoi, S.; Okajima, T.: Acid stimulation of onnagawa tight oil formation in Ayukawa field Japan. In: SPE Unconventional Resources Conference and Exhibition-Asia Pacific (2013)

  5. Gengliang, C.; Ying, H.: An analysis of acidizing reaction mechanism of carbonates. Nat. Gas Ind. 26(1):104–108 (2006) (in Chinese with English abstract)

  6. Hartman R., Lecerf B., Frenier W.: Acid-sensitive aluminosilicates: dissolution kinetics and fluid selection for matrix-stimulation treatments. SPE Prod. Oper. 21(2), 194–204 (2006)

    Google Scholar 

  7. Bulgakova, G.; Kharisov, R.; Sharifullin, A.: Optimizing the design of matrix treatments. In: European Formation Damage Conference (2011)

  8. Taylor K.C., Nasr-El-DIN H.A.: Measurement of acid reaction rates with the rotating disk apparatus. J. Can. Pet. Technol. 48(6), 66–70 (2009)

    Article  Google Scholar 

  9. Samadi, F.; Esmaeilzadeh, F.; Mowla D.: Modeling of dissolution patterns for carbonate acidizing in the porous media. J. Porous Media 16(10), 167–170 (2013)

  10. Maheshwari, P.; Balakotaiah V.: 3D Simulation of carbonate acidization with HCl: comparison with experiments. In: SPE Production and Operations Symposium (2013)

  11. Safari H., Jamialahmadi M.: Estimating the kinetic parameters regarding barium sulfate deposition in porous media: a genetic algorithm approach. Asia Pac. J. Chem. Eng. 9(2), 477–505 (2014)

    Article  MathSciNet  Google Scholar 

  12. Saeed Z.K.R., Uddin F.: Medium effect on activation parameters for the kinetics of reaction between β-bromopropionate and thiosulfate ions. Arab. J. Sci. Eng. 31(2A), 169–175 (2006)

    Google Scholar 

  13. Williams B.B., Gidley J.L., Guin J.A. et al.: Characterization of liquid–solid reactions. Hydrochloric acid-calcium carbonate reaction. Ind. Eng. Chem. Fundam. 9(4), 589–596 (1970)

    Article  Google Scholar 

  14. Chou L., Garrels R.M., Wollast R.: Comparative study of the kinetics and mechanisms of dissolution of carbonate minerals. Chem. Geol. 78(3–4), 269–282 (1989)

    Article  Google Scholar 

  15. Conway, M.W.; Asadi, M.; Penny, G.S. et al.: A comparative study of straight/gelled/emulsified hydrochloric acid diffusivity coefficient using diaphragm cell and rotating disk. In: SPE Annual Technical Conference and Exhibition (1999)

  16. Nierode D.E., Williams B.B.: Design of acid fracturing treatments. J. Pet. Technol. 24(07), 849–859 (1972)

    Article  Google Scholar 

  17. Nierode D.E., Williams B.B.: Characteristics of acid reaction in limestone formations. Soc. Pet. Eng. J. 11(04), 406–418 (1971)

    Article  Google Scholar 

  18. Lund K., Fogler H.S., McCune C.C.: Acidization I: the dissolution of dolomite in hydrochloric acid. Chem. Eng. Sci. 28(3), 691–700 (1973)

    Article  Google Scholar 

  19. Rabie A.I., Gomaa A.M., Nasr-El-Din H.A.: Reaction of in-situ-gelled acids with calcite: reaction-rate study. SPE J. 16(4), 194–204 (2011)

    Article  Google Scholar 

  20. Rabie, A.; Mahmoud, M.; Nasr-El-Din, H.: Reaction of GLDA with calcite: reaction kinetics and transport study. In: International Symposium on Oilfield Chemistry (2011)

  21. Economides M.J., Hill A.D.: Petroleum Production Systems, pp. 248–259. PRT Prentice Hall, Englewood Cliffs (1994)

    Google Scholar 

  22. Al-Mutairi S., Nasr-El-Din H., Hill A. et al.: Effect of droplet size on the reaction kinetics of emulsified acid with calcite. SPE J. 14(4), 606–616 (2009)

    Article  Google Scholar 

  23. Taylor K., Nasr-El-Din H., Mehta S.: Anomalous acid reaction rates in carbonate reservoir rocks. SPE J. 11(4), 488–496 (2006)

    Article  Google Scholar 

  24. Alkhaldi M., Nasr-El-Din H., Sarma H.: Kinetics of the reaction of citric acid with calcite. SPE J. 15(3), 704–713 (2010)

    Article  Google Scholar 

  25. Zhang X.T., Zhang R.H.: Kinetics study of zeolite in hydrothermal solutions. Acta Phys. Chim. Sin. 21(06), 616–621 (2005)

    MATH  Google Scholar 

  26. Adenuga, O.O.; Sayed, M.A.; Nasr-El-Din, H.A.: Reactions of simple organic acids and chelating agents with dolomite. In: SPE Production and Operations Symposium (2013)

  27. Williams, B.B.; Gidley, J.L.; Schechter R.S.: Acidizing fundamentals. Henry L. Doherty Memorial Fund of AIME, Society of Petroleum Engineers of AIME (1979)

  28. Sayed M.A., Nasr-El-Din H.A., Nasrabadi H.: Reaction of emulsified acids with dolomite. J. Can. Pet. Technol. 52(3), 164–174 (2013)

    Article  Google Scholar 

  29. Song, S.M.; Wang, Z.L.; Li, W.B.: Physical Chemistry, 3th edn.. Higher Education Press, Beijing (1993)

Download references

Author information

Authors and Affiliations

  1. State Key Lab of Oil and Gas Reservoir Geology and Exploitation, South West Petroleum University, Chengdu, 610500, Sichuan, People’s Republic of China

    Nianyin Li, Yinsheng Feng, Pingli Liu, Zhifeng Luo & Liqiang Zhao

Authors
  1. Nianyin Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yinsheng Feng
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Pingli Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhifeng Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Liqiang Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Nianyin Li.

Additional information

The project was supported by the highlights discipline construction projects funded science foundation for young teachers.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, N., Feng, Y., Liu, P. et al. Study of Acid–Rock Reaction Kinetics Under High Temperature and Pressure Conditions Based on the Rotating Disk Instrument. Arab J Sci Eng 40, 135–142 (2015). https://doi.org/10.1007/s13369-014-1504-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13369-014-1504-x

Keywords

Search

Navigation