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Fluorescence behaviors of metal complexes/PVC composites

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Abstract

16 kinds of metal complexes were synthesized using ZnCl2, AlCl3, BiCl3, EuCl3, and ligands of 1,10-phenanthroline (phen), salicylic acid (Hsal) and 8-hydroxyquinoline (Oxin). Then metal complexes/polyvinyl chloride (PVC) composite thin films were produced using melt blending method with metal complexes and PVC resin as raw materials. The optimal addition ratio was obtained by changing the dosage of metal complexes. Fluorescence excitation and emission spectrum of metal complexes and the produced thin films were also investigated by thermogravimetric analysis (TG), fluorescence spectrum, transmissivity and haze test and tensile test. All the complexes show luminescent emissions in the solid phase.

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Authors and Affiliations

  1. College of Chemical Engineering and Material, Tianjin University of Science and Technology, Tianjin, 300457, P. R. China

    Chenxi Fan & Yongyan Cui

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  1. Chenxi Fan
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  2. Yongyan Cui
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Correspondence to Yongyan Cui.

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These authors equally contributed to this work.

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Fan, C., Cui, Y. Fluorescence behaviors of metal complexes/PVC composites. Macromol. Res. 25, 357–364 (2017). https://doi.org/10.1007/s13233-017-5047-3

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  • DOI: https://doi.org/10.1007/s13233-017-5047-3

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