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Nanoporous thin films of fully alicyclic polyimides

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Abstract

Nanopore generation could be accomplished in thin films of fully alicyclic polyimides derived from an alicyclic dianhydride and diamines. A silylation method for the alicyclic diamines was used to synthesize high molecular weight alicyclic polyimides. Triblock copolyimides were prepared using N-silylated alicyclic diamines, alicyclic dianhydride, and a thermally labile polymer. Nanoporous films of fully alicyclic polyimides were prepared through heating of the copolyimide films to induce thermal degradation of the labile block.

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Authors and Affiliations

  1. Department of Chemistry, Yonsei University, Gangwon, 220-710, Korea

    Hwan-Chul Yu, S. Vijay Kumar, Young-Kyu Song & Chan-Moon Chung

  2. Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo, 153-8305, Japan

    Jiyoung Choi & Kazuaki Kudo

  3. Hanwha Chemical R&D Center, Daejeon, 305-345, Korea

    Joong-Gon Kim

  4. Department of Chemical and Biomolecular Engineering, Sogang University, Seoul, 121-742, Korea

    Se-Young Oh

Authors
  1. Hwan-Chul Yu
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  2. S. Vijay Kumar
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  3. Young-Kyu Song
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  4. Jiyoung Choi
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  5. Kazuaki Kudo
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  6. Joong-Gon Kim
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  7. Se-Young Oh
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  8. Chan-Moon Chung
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Correspondence to Chan-Moon Chung.

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Yu, HC., Kumar, S.V., Song, YK. et al. Nanoporous thin films of fully alicyclic polyimides. Macromol. Res. 19, 1272–1277 (2011). https://doi.org/10.1007/s13233-011-1216-y

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  • DOI: https://doi.org/10.1007/s13233-011-1216-y

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