Skip to main content
Log in

Rapid Determination of Ethyl Alcohol in Alcoholic Beverages Using a Fluorescent Nanofiber Film

  • Original Article
  • Published:
BioChip Journal Aims and scope Submit manuscript

Abstract

Electrospinning has been recognized as a simple, versatile, and viable technique to fabricate ultrathin nanofibers from various materials, e.g., polymers and composites, in aqueous solutions. In this study, we used polyvinyl alcohol (PVA) as a substrate to synthesize nanofibers by using an electric field between the syringe needle and PVA. The nanofibers demonstrate an immense potential for developing fluorescent detection system of ethyl alcohol from several types of beverages due to their special characteristics of a simple, albeit useful, and effective top-down fabrication process. The development of nanofibers, a fundamental understanding of electrospinning, and properties of the nanofibers, as well as their applications to determine the alcohol content in beverages by direct injection into the fiber surface, were described. This method was accomplished using a PVA nanofiber scaffold as the immobilized sensing film in samples of wine, beer, or some alcohol beverages. Various beverages were tested, which were found to contain low alcohol concentrations. The optical properties of nanofibers in an aqueous PVA solution were observed by fluorescence spectra. The PVA nanofiber films could be useful for detecting the alcohol upto 1.0vol% in a real sample within several seconds. Details of the type of electrospun fibers, and their characteristics were also explained. This study should serve as a guiding tool for nanoscience researchers in fibers, textiles, food validations, and polymer fields.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Gunduz, S., Yilmaz, H. & Goren, A.C. Halal Food and Metrology: Ethyl Alcohol Contents of Beverages. J. Chem. Metrol. 7, 7–9 (2013).

    Google Scholar 

  2. Mahajan, R., Garg, S. & Sharma, P.B. Food Safety in India: A Case of Deli Processed Food Products Ltd. Int. J. Prod. Qual. Manag. 14, 1–20 (2014).

    Google Scholar 

  3. Logan, B.K. & Distefano, S. Ethanol Content of Various Foods and Soft Drinks and Their Potential for Interference with a Breath-alcohol Test. J. Anal. Toxicol. 22, 181–183 (1998).

    Article  CAS  PubMed  Google Scholar 

  4. Engs, R.C., Slawinska, J.B. & Hanson, D.J. The Drinking Patterns of American and Polish University Students: A Cross-national Study. Drug Alcohol Depen. 27, 167–175 (1991).

    Article  CAS  Google Scholar 

  5. Jamaludin, M.A. et al. Determination of Permissible Alcohol and Vinegar in Shariah and Scientific Perspectives. Int. Food Res. J. 23, 2737–2743 (2016).

    CAS  Google Scholar 

  6. Head, K. & Mayer, T. What Separates Us? Sources of Resistance to Globalization. Can. J. Econ. 46, 1196–1231 (2013).

    Article  Google Scholar 

  7. Li, D., Babel, A., Jenekhe, S.A. & Xia, Y.N. Nanofibers of Conjugated Polymers Prepared by Electrospinning with a Two-capillary Spinneret. Adv. Mater. 16, 2062–2066 (2004).

    Article  CAS  Google Scholar 

  8. Marega, C. et al. Polyvinyl Alcohol Electrospun Nanofibers Containing Ag Nanoparticles Used as Sensors for the Detection of Biogenic Amines. Nanotechnology 26, 7 (2015).

    Article  CAS  Google Scholar 

  9. Li, Y., Chen, R. & Liu, F.J. Comparison Between Electrospun and Bubbfil-spun Polyether Sulfone Fibers. Matéria 19, 363–369 (2014).

    CAS  Google Scholar 

  10. Huan, S. et al. Effect of Experimental Parameters on Morphological, Mechanical and Hydrophobic Properties of Electrospun Polystyrene Fibers. Materials 8, 2718–2734 (2015).

    Article  CAS  PubMed Central  Google Scholar 

  11. Jeong, S.-I., Kang, Y.-J., Lee, K.-S., Shin, H. & Lee, B.-K. Efficacy of Mechanically Modified Electrospun Poly (L-lactide-co-e-caprolactone)/Gelatin Membrane on Full-thickness Wound Healing in Rats. Biotechnol. Biopro. Eng. 22, 200–209 (2017).

    Article  CAS  Google Scholar 

  12. MacDiarmid, A.G. et al. Electrostatically-generated Nanofibers of Electronic Polymers. Synth. Met. 119, 27–30 (2001).

    Article  CAS  Google Scholar 

  13. Wu, C.M., Yu, S.A. & Lin, S.L. Graphene Modified Electrospun Poly (vinyl alcohol) Nanofibrous Membranes for Glucose Oxidase Immobilization. Express Polym. Lett. 8, 565–573 (2014).

    Article  Google Scholar 

  14. Hong, S.P. et al. Fabrication of Wafer-scale Free-standing Quantum Dot/polymer Nanohybrid Down-conversion Films for White-light-emitting Diodes Using an Electrospray Method. J. Mater. Chem. C 2, 10439–10445 (2014).

    Google Scholar 

  15. Huanga, Z.-M., Zhangb, Y.-Z., Kotakic, M. & Ramakrishna, S. A Review on Polymer Nanofibers by Electrospinning and Their Applications in Nanocomposites. Compos. Sci. Technol. 63, 2223–2253 (2003).

    Article  CAS  Google Scholar 

  16. Liu, L., Zhang, Y. & Xin, B. Synthesis of Briaryls and Polyaryls by Ligand-free Suzuki Reaction in Aqueous Phase. J. Org. Chem. 71, 3994–3997 (2006).

    Article  CAS  PubMed  Google Scholar 

  17. Greiner, A. & Wendorff, J.H. Electrospinning: A Fascinating Method for the Preparation of Ultrathin Fibers. Angew. Chem. Int. Ed. 46, 5670–5703 (2007).

    Article  CAS  Google Scholar 

  18. Li, D. & Xia, Y. Electrospinning of Nanofibers: Reinventing the Wheel? Adv. Mater. 16, 1151–1170 (2004).

    Article  CAS  Google Scholar 

  19. Park, H.S., Choi, B.G., Hong, W.H. & Jang, S.Y. Controlled Assembly of Graphene Oxide Nanosheets within One-dimensional Polymer Nanostructure. J. Colloid Interface Sci. 406, 24–29 (2013).

    Article  CAS  PubMed  Google Scholar 

  20. Tran, T.B., Son, S.J. & Min, J. Nanomaterials in Label- free Impedimetric Biosensor: Current Process and Future Perspectives. BioChip J. 10, 318–330 (2016).

    Article  CAS  Google Scholar 

  21. Joly, D., Jung, J.-W., Kim, I.-D. & Demadrille, R. Electrospun Materials for Solar Energy Conversion: Innovations and Trends. J. Mater. Chem. C 4, 10173–10197 (2016).

    Google Scholar 

  22. Lachenmeier, D.W. et al. Rapid and Mobile Determination of Alcoholic Strength in Wine, Beer and Spirits Using a Flow-through Infrared Sensor. Chem. Cent. J. 4, 5 (2010).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  23. Akamatsu, M. et al. Detection of Ethanol in Alcoholic Beverages or Vapor Phase Using Fluorescent Molecules Embedded in a Nanofibrous Polymer. ACS Appl. Mater. Interfaces 7, 6189–6194 (2015).

    Article  CAS  PubMed  Google Scholar 

  24. Min, K. & Yoo, Y.J. Recent Progress in Nanobiocatalysis for Enzyme Immobilization and Its Application. Biotechnol. Bioproc. Eng. 19, 553–567 (2014).

    Article  CAS  Google Scholar 

  25. Wen, G., Li, Z. & Choi, M.M.F. Detection of Ethanol in Food: A New Biosensor based on Bacteria. J. Food Eng. 118, 56–61 (2013).

    Article  CAS  Google Scholar 

  26. Ishihara, S., Iyi, N. & Labuta, J. Naked-eye Discrimination of Methanol from Ethanol Using Composite Film of Oxoporphyrinogen and Layered Double Hydroxide. ACS Appl. Mater. Interfaces 5, 5927–5930 (2013).

    Article  CAS  PubMed  Google Scholar 

  27. Yamaguchi, I., Goto, K. & Sato, M. Synthesis of Oligophenylenes Containing Hydroxyl Group and their Solvatochromic Behavior. Tetrahedron 65, 3645–3652 (2009).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Jong Pil Park or Tae Jung Park.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nguyen, N.L.T., Baek, S.H., Akbar, Z.A. et al. Rapid Determination of Ethyl Alcohol in Alcoholic Beverages Using a Fluorescent Nanofiber Film. BioChip J 12, 240–248 (2018). https://doi.org/10.1007/s13206-017-2305-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13206-017-2305-6

Keywords

Navigation