Abstract
The chapter is meant to examine the performance of electrodes blended with nanofibers. This study concerns the synthesis, characterization, and applications of electrodes and polymeric nanofibers. Electrospinning is a basic, simple, and adaptable strategy for creating submicron and nano size filaments. Owing to their enormous surface territory and permeable design, electrospun nanofibers can be utilized widely in biomedical, ecological, defensive attire, and sensors applications. Nano filaments of micron measurement and various compound organizations were prepared. Sensors are set up instruments of synthetic investigation utilized in both electrochemical and optical detecting modes. They permit understanding into ion concentrations in different examples, offering reliable performance. One of the methods of improving this class of sensors is to investigate the advantages of nanoscale receptor layers. In this regard, nanofibers appear to be a profoundly attractive alternative because of novel properties identified with the geometry of this class of nanomaterials. Cyclic voltammetry was applied to examine the changes of behavior of electrodes with various diameters. The result displayed that diameter of nanofibers diminished with decreasing polymer concentration focus and applied voltage and expanding tip-to-collector distance while feeding rate of rate did not have a critical impact on nanofiber diameter. This chapter gives a brief outline of a few electrospun nanofibers applications, focusing on biosensor or nanosensor applications. Here, polymeric nanofibers as an electrode for sensors properties of affectability, selectivity, and identification are fundamentally assessed. Current challenges in this area and prospective future work are likewise discussed.
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References
Iftikhar, F.J., Shah, A., Akhter, M.S., Kurbanoglu, S., Ozkan, S.A.: Introduction to nanosensors. In: New Developments in Nanosensors for Pharmaceutical Analysis, pp 1–46 (2019)
Mane, P.P., Ambekar, R.S., Kandasubramanian, B.: Electrospun nanofiber-based cancer sensors: A review. Int. J. Pharm. 583, 119364 (2020)
Pokropivny, V.V., Skorokhod, V.V.: Classification of nanostructures by dimensionality and concept of surface forms engineering in nanomaterial science. Mater. Sci. Eng. C 27, 990–993 (2007)
Greiner, A., Wendorff, J.H.: Electrospinning: a fascinating method for the preparation of ultrathin fibers. Angew. Chemie. Int. Ed. 46, 5670–5703 (2007)
Qi, S., Zhao, B., Tang, H., Jiang, X.: Determination of ascorbic acid, dopamine, and uric acid by a novel electrochemical sensor based on pristine graphene. Electrochim Acta 161, 395–402 (2015)
Xue, J., Xie, J., Liu, W., Xia, Y.: Electrospun nanofibers: new concepts, materials, and applications. Acc Chem. Res. 50, 1976–1987 (2017)
Thakkar, S., Misra, M.: Electrospun polymeric nanofibers: New horizons in drug delivery. Eur. J. Pharm. Sci. 107, 148–167 (2017)
Thenmozhi, S., Dharmaraj, N., Kadirvelu, K., Kim, H.Y.: Electrospun nanofibers: new generation materials for advanced applications. Mater. Sci. Eng. B 217, 36–48 (2017)
Xu, J., Liu, C., Hsu, P.-C., Liu, K., Zhang, R., Liu, Y., Cui, Y.: Roll-to-Roll transfer of electrospun nanofiber film for high-efficiency transparent air filter. Nano. Lett. 16, 1270–1275 (2016)
Wu, J., Qin, X., Miao, C., He, Y.-B., Liang, G., Zhou, D., Liu, M., Han, C., Li, B., Kang, F.: A honeycomb-cobweb inspired hierarchical core–shell structure design for electrospun silicon/carbon fibers as lithium-ion battery anodes. Carbon. N Y 98, 582–591 (2016)
Supraja, P., Tripathy, S., Krishna Vanjari, S.R., Singh, V., Singh, S.G.: Label free, electrochemical detection of atrazine using electrospun Mn2O3 nanofibers: towards ultrasensitive small molecule detection. Sens. Actuators B Chem. 285, 317–325 (2019)
Zhang, P., Zhao, X., Ji, Y., Ouyang, Z., Wen, X., Li, J., Su, Z., Wei, G.: Electrospinning graphene quantum dots into a nanofibrous membrane for dual-purpose fluorescent and electrochemical biosensors. J. Mater. Chem. B 3, 2487–2496 (2015)
Li, H., Huang, H., Meng, X., Zeng, Y.: Fabrication of helical microfibers from melt blown polymer blends. J. Polym. Sci. Part B Polym. Phys. 56, 970–977 (2018)
Agubra, V.A., De La Garza, D., Gallegos, L., Alcoutlabi, M.: Force Spinning of polyacrylonitrile for mass production of lithium-ion battery separators. J. Appl. Polym. Sci. 133(42847), 1–8 (2016)
Sun, J., Zhang, Z., Lu, B., Mei, S., Xu, Q., Liu, F.: Research on parametric model for polycaprolactone nanofiber produced by centrifugal spinning. J Brazilian Soc. Mech. Sci. Eng. 40, 186 (2018)
Huang, Z.-M., Zhang, Y.-Z., Kotaki, M., Ramakrishna, S.: A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos. Sci. Technol. 63, 2223–2253 (2003)
Su, Z., Ding, J., Wei, G.: Electrospinning: a facile technique for fabricating polymeric nanofibers doped with carbon nanotubes and metallic nanoparticles for sensor applications. RSC Adv. 4, 52598–52610 (2014)
Wang, X., Niu, H., Lin, T., Wang, X.: Needleless electrospinning of nanofibers with a conical wire coil. Polym. Eng. Sci. 49, 1582–1586 (2009)
Kenry, L.C.T.: Nanofiber technology: current status and emerging developments. Prog. Polym. Sci. 70, 1–17 (2017)
Whitesides, G.M., Grzybowski, B.: Self-Assembly at all scales. Science 80-(295), 2418–2421 (2002)
Xia, L., Xi, P., Cheng, B.: High efficiency fabrication of ultrahigh molecular weight polyethylene submicron filaments/sheets by flash-spinning. J. Polym. Eng. 36, 97–102 (2016)
Thomas, M.S., Pillai P.K., Farrow, S.C., Pothan, L.A., Thomas, S.L.: Electrospinning as an important tool for fabrication of nanofibers for advanced applications—a brief review. Gen. Chem. 7, 200022–200022 (2021)
Li, M., Guo, Y., Wei, Y., MacDiarmid, A.G., Lelkes, P.I.: Electrospinning polyaniline-contained gelatin nanofibers for tissue engineering applications. Biomaterials 27, 2705–2715 (2006)
Ma, Z., Kotaki, M., Yong, T., He, W., Ramakrishna, S.: Surface engineering of electrospun polyethylene terephthalate (PET) nanofibers towards development of a new material for blood vessel engineering. Biomaterials 26, 2527–2536 (2005)
Hou, H., Ge, J.J., Zeng, J., Li, Q., Reneker, D.H., Greiner, A., Cheng, S.Z.D.: Electrospun polyacrylonitrile nanofibers containing a high concentration of well-aligned multiwall carbon nanotubes. Chem. Mater. 17, 967–973 (2005)
Yang, E., Qin, X., Wang, S.: Electrospun crosslinked polyvinyl alcohol membrane. Mater. Lett. 62, 3555–3557 (2008)
Deitzel, J.M., Kleinmeyer, J.D., Hirvonen, J.K., Beck Tan, N.C.: Controlled deposition of electrospun poly(ethylene oxide) fibers. Polym. (Guildf) 42, 8163–8170 (2001)
Heikkilä, P., Harlin, A.: Parameter study of electrospinning of polyamide-6. Eur. Polym. J. 44, 3067–3079 (2008)
Zhu, H., Qiu, S., Jiang, W., Wu, D., Zhang, C.: Evaluation of electrospun polyvinyl chloride/polystyrene fibers as sorbent materials for oil spill cleanup. Environ. Sci. Technol. 45, 4527–4531 (2011)
Haider, A., Haider, S., Kang, I.-K.: A comprehensive review summarizing the effect of electrospinning parameters and potential applications of nanofibers in biomedical and biotechnology. Arab. J. Chem. 11, 1165–1188 (2018)
Ramakrishna, S., Fujihara, K., Teo, W.-E., Lim, T.-C., Ma, Z.: An introduction to electrospinning and nanofibers. In: An Introduction to Electrospinning and Nanofibers. World Scientific Publications, pp. 1–382 (2005)
Chen, K., Chou, W., Liu, L., Cui, Y., Xue, P., Jia, M.: Electrochemical sensors fabricated by electrospinning technology: an overview. Sensors (Switzerland) 19, 3676 (1–19) (2019)
Bahrami, G., Ehzari, H., Mirzabeigy, S., Mohammadi, B., Arkan, E.: Fabrication of a sensitive electrochemical sensor based on electrospun magnetic nanofibers for morphine analysis in biological samples. Mater. Sci. Eng. C 106, 110183 (2020)
Samie, H.A., Arvand, M.: Label-free electrochemical aptasensor for progesterone detection in biological fluids. Bioelectrochemistry 133, 107489 (2020)
Tang, Q., Zhu, G., Ge, Y., Yang, J., Huang, M., Liu, J.: AuNPs-polyaniline nanosheet array on carbon nanofiber for the determination of As(III). J. Electroanal Chem. 873, 114381 (2020)
Liu, S., Zhang, X.: Preparation of nitrogen doped carbon nanofibers for electrochemical determination of Cd(II) and Pb(II) Ions. Int. J. Electrochem Sci. 9838–9848 (2020)
Ahmad, W., Jabbar, B., Ahmad, I., Jan, B.M., Stylianakis, M.M., Kenanakis, G., Ikram, R.: Highly sensitive humidity sensors based on polyethylene oxide/CuO/multi walled carbon nanotubes composite nanofibers. Mater. (Basel) 14, 1–19 (2021)
Manikandan, N., Valleti, K., Karupasamy, K., Divagar, M., Subramaniam, S.: The monolithic α, β crystal structural design of piezoelectric poly (vinylidene fluoride) (PVDF) polymer/fullerene based sensor array for the measurement of lung pressure. Sens. Bio-Sensing Res. 32, 100418 (2021)
Wen, H.-Y., Liu, Y.-C., Chiang, C.-C.: The use of doped conductive bionic muscle nanofibers in a tennis racket–shaped optical fiber humidity sensor. Sens. Actuators B Chem. 320, 128340 (2020)
Pavinatto, A., Mercante, L.A., Facure, M.H.M., Pena, R.B., Sanfelice, R.C., Mattoso, L.H.C., Correa, D.S.: Ultrasensitive biosensor based on polyvinylpyrrolidone/chitosan/reduced graphene oxide electrospun nanofibers for 17α—Ethinylestradiol electrochemical detection. Appl Surf Sci 458, 431–437 (2018)
Koo, W.T., Choi, S.J., Kim, N.H., Jang, J.S., Kim, I.D.: Catalyst-decorated hollow WO3 nanotubes using layer-by-layer self-assembly on polymeric nanofiber templates and their application in exhaled breath sensor. Sens. Actuators B Chem 223, 301–310 (2016)
Li, X., Zhuang, Z., Qi, D., Zhao, C.: High sensitive and fast response humidity sensor based on polymer composite nanofibers for breath monitoring and non-contact sensing. Sens. Actuators B Chem. 330, 129239 (2021)
Gao, Y., Guo, F., Cao, P., Liu, J., Li, D., Wu, J., Wang, N., Su, Y., Zhao, Y.: Winding-Locked carbon nanotubes/polymer nanofibers helical yarn for ultrastretchable conductor and strain sensor. ACS Nano 14, 3442–3450 (2020)
Wu, S., Liu, P., Zhang, Y., Zhang, H., Qin, X.: Flexible and conductive nanofiber-structured single yarn sensor for smart wearable devices. Sens. Actuators B Chem. 252, 697–705 (2017)
Liu, K., Zhou, Z., Yan, X., Meng, X., Tang, H., Qu, K., Gao, Y., Li, Y., Yu, J., Li, L.: Polyaniline nanofiber wrapped fabric for high performance flexible pressure sensors. Polymers (Basel) 11, 1120 (2019)
Salami, M.S., Bahrami, G., Arkan, E., Izadi, Z., Miraghaee, S., Samadian, H.: Co-electrospun nanofibrous mats loaded with bitter gourd (Momordica charantia) extract as the wound dressing materials: in vitro and in vivo study. BMC Complement Med. Ther. 21, 111 (2021)
Georgakilas, V., Tiwari, J.N., Kemp, K.C., Perman, J.A., Bourlinos, A.B., Kim, K.S., Zboril, R.: Noncovalent functionalization of graphene and graphene oxide for energy materials, biosensing, catalytic, and biomedical applications. Chem. Rev. 116, 5464–5519 (2016)
Tsiamis, A., Diaz Sanchez, F., Hartikainen, N., Chung, M., Mitra, S., Lim, Y.C., Tan, H.L., Radacsi, N.: Graphene wrapping of electrospun nanofibers for enhanced electrochemical sensing. ACS Omega 6, 10568–10577 (2021)
Chen, H.-M., Wang, L., Zhou, S.-B.: Recent progress in shape memory polymers for biomedical applications. Chinese J. Polym. Sci. 36, 905–917 (2018)
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Rahman, S. et al. (2022). Polymeric Nanofibers as Electrodes for Sensors. In: Gupta, R.K. (eds) Organic Electrodes. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-030-98021-4_21
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DOI: https://doi.org/10.1007/978-3-030-98021-4_21
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