Abstract
Bioenergy production has become a significant and effective technique to overcome the energy crises. In the current study, the photoelectrochemical cell has been used for the hydrogen evolution from biomass (animal waste). Bismuth vanadate (BiVO4)/tungsten trioxide (WO3) nanocomposites were used as photoanodes in the photoelectrochemical cell. BiVO4 (0.5%, 1.0%, 1.5% and 2.0%) nanoparticles were fused on the lattice sites of the WO3 via hydrothermal method at 180 °C operating temperature. The properties investigated by the X-ray diffraction (XRD), scanning electron microscopy (SEM), Ultraviolet–Visible (UV–Vis) and photoluminescence (PL) revealed the dispersion of BiVO4 material on the lattice sites of the WO3 nanoparticles. Phase transformations occurred from monoclinic to hexagonal up to BiVO4/WO3 − 1.5 and then orthorhombic for further. Incorporated BiVO4/WO3 − 1.5 shows the lowest band gap with 40–50 nm grain size and performs excellent conversion of the organic waste into electricity. The coupling of BiVO4 with WO3 caused the red shift for photo absorption up to BiVO4/WO3 − 1.5 which resulted in an effective and extraneous efficiency of the sample due to interaction among electron and redox potential established across the electrodes for efficient photocatalytic activity to produce hydrogen gas fuel. This was further confirmed by the BET results with a specific surface area of 83.31 m2/g for the aforementioned sample as the highest value among all the prepared nanocomposites. This work considered as an effective and favorable photocatalyst for the biochemical production of energy applications from biomass and biowastes.
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References
Aktamis H (2011) determining energy saving behavior and energy awareness of secondary school students according to socio-demographic characteristics. Educ Res Rev 6:243
Ali B (2017) The cost of conserved water for power generation from renewable energy technologies in Alberta, Canada. Energy Convers Manag 150:201–213
Archana B, Nagaraju G, Yatish KV, Udayabhanu, Chandra Sekhar KB, Kottam N (2018) Bio-derived ZnO nanoparticles as an efficient catalyst for photocatalytic activity and biodiesel production. AIP Conf Proc 1992(1):030004
Caravaca A, Jones W, Hardacre C, Bowker M (2016) H2 production by the photocatalytic reforming of cellulose and raw biomass using Ni, Pd, Pt and Au on titania. Proc R Soc A 472(2191):20160054
Chatchai P et al (2009) Efficient photocatalytic activity of water oxidation over WO3/BiVO4 composite under visible light irradiation. Electrochimica Acta 54.3:1147–1152
Chatchai P, Kishioka S, Murakami Y, Nosaka AY, Nosaka Y (2010) Enhanced photoelectrocatalytic activity of FTO/WO3/BiVO4 electrode modified with gold nanoparticles for water oxidation under visible light irradiation. Electrochim Acta 55:592–596
Clarizia L, Spasiano D, Di Somma I, Marotta R, Andreozzi R, Dionysiou DD (2014) Copper modified-TiO2 catalysts for hydrogen generation through photoreforming of organics. A short review. Int J Hydrog Energy 39:16812–16831
Cui J et al (2019a) Ultrahigh recovery of fracture strength on mismatched fractured amorphous surfaces of silicon carbide. ACS Nano 13(7):7483–7492
Cui J et al (2019b) Unprecedented piezoresistance coefficient in strained silicon carbide. Nano Lett 19(9):6569–6576
Dastan D (2015) Nanostructured anatase titania thin films prepared by sol–gel dip coating technique. J Atomic Molecul Condensate Nano Phys (JAMCNP) 2(2):109–114
Dastan D (2017) Effect of preparation methods on the properties of titania nanoparticles: solvothermal versus sol–gel. Appl Phys A 123(699):1–13
Dastan D, Chaure NB (2014) Influence of surfactants on TiO2 nanoparticles grown by sol-gel technique. J Mater Mech Manufact 2(1):21–24
Dastan D, Londhe PU, Chaure NB (2014) Characterization of TiO2 nanoparticles prepared using different surfactants by sol–gel method. J Mater Sci: Mater Electron 25:3473–3479
Dastan D, Panahi SL, Yengantiwar AP, Banpurkar AG (2016a) Morphological and electrical studies of titania powder and films grown by aqueous solution method. Adv Sci Lett 22(4):950–953
Dastan D, Panahi SL, Chaure NB (2016b) Characterization of titania thin films grown by dip-coating technique. J Mater Sci: Mater Electron 27:12291–12296
Dastan D, Chaure N, Kartha M (2017) Surfactants assisted solvothermal derived titania nanoparticles: synthesis and simulation. J Mater Sci: Mater Electron 28:7784–7796
Dincer I, Acar C (2014) Review and evaluation of hydrogen production methods for better sustainability. Int J Hydrogen Energy 5:1–18
Dincer I, Acar C (2015) A review on clean energy sources for better sustainability. Int J Energy Res 39:585–606
Hassan A, Iqbal T, Tahir MB, Afseen S (2018) A review on copper vanadate based nanostructures for photocatalysis energy production. Int J Energy Res 1:1. https://doi.org/10.1002/er.4195
He QS, McNutt J, Yang J (2017) Utilization of the residual glycerol from biodiesel production for renewable energy generation. Renew Sustain Energy Rev 71:63–76
Hosseini SE, AbdulWahid M (2016) Hydrogen production from renewable and sustainable energy resources: promising green energy carrier for clean development. Renew Sustain Energy Rev 57:850–866
Kanakaraju D, Wong SP (2018) Photocatalytic efficiency of TiO2-biomass loaded mixture for wastewater treatment. J Chem
Kim T, Choi K (2014) Nanoporous BiVO4 photoanodes with dual-layer oxygen evolution catalysts for solar water splitting. Science 343:990–994
Liu W, Mu W, Liu M, Zhang X, Cail H, Deng Y (2014) Solar-induced direct biomass-to-electricity hybrid fuel cell using polyoxometalates as photocatalyst and charge carrier. Nat Commun 5:3208
Lu X et al (2014) Photoelectrochemical hydrogen production from biomass derivatives and water. Chem Soc Rev 4322:7581–7593
Meloa MO, Silva LA (2011) Photocatalytic production of hydrogen: an innovative use for biomass derivatives. J Braz Chem Soc 22:1399–1406
Navarro TG, Pérez DR (2018) Assessing the obstacles to the participation of renewable energy sources in the electricity market of Colombia. Renew Sustain Energy Rev 90:131–141
Panahi SL, Dastan D, Chaure NB (2016) Characterization of zirconia nanoparticles grown by sol–gel method. Adv Sci Lett 22(4):941–944
Pihosh Y et al (2015) Photocatalytic generation of hydrogen by core-shell WO3/BiVO4 nanorods with ultimate water splitting efficiency. Sci Rep 5:11141
Rao P, Cai L, Liu C, Cho IS, Lee CH, Weiss JM, Yang P, Zheng X (2014) Simultaneously efficient light absorption and charge separation in WO3/BiVO4 core/shell nanowire photoanode for photoelectrochemical water oxidation. Nano Lett 14:1099–1105
Reddy NL, Cheralathan KK, Kumari VD, Neppolian B, Venkatakrishnan SM (2018) Photocatalytic reforming of biomass derived crude glycerol in water: a sustainable approach for improved hydrogen generation using Ni(OH)2 decorated TiO2 nanotubes under solar light irradiation. ACS Sustainable Chem Eng 6:3754–3764
Shi X et al (2014) Efficient photoelectrochemical hydrogen production from bismuth vanadate-decorated tungsten trioxide helix nanostructures. Nat Commun 5:4775
Shukla AK, Suresh P, Berchmans S, Rajendran A (2004) Biological fuel cells and their application. Curr Sci 87:455
Su J et al (2011a) Nanostructured WO3/BiVO4 heterojunction films for efficient photoelectrochemical water splitting. Nano Lett 11(5):1928–1933
Su J, Guo L, Bao N, Grimes CA (2011b) Nanostructured WO3/BiVO4 heterojunction films for efficient photoelectrochemical water splitting. Nano Lett 11:1928–1933
Tahir MB, Nabi G, Rafique M, Khalid NR (2017) Nanostructured-based WO3 photocatalysts: recent development, activity enhancement, perspectives and applications for wastewater treatment. Int J Environ Sci Technol 14(11):2519–2542
Wang B et al (2018) New deformation-induced nanostructure in silicon. Nano Lett 18(7):4611–4617
Xiaa L, Baia J, Lia J, Zenga Q, Lia X, Zhoua B (2016) A highly efficient BiVO4/WO3/W heterojunction photoanode for visible-light responsive dual photoelectrode photocatalytic fuel cell. Appl Catal B 183:224–230
Yin Chao, Zhu Shenmin, Zhang Di (2017) 3D nanostructured WO3/BiVO4 heterojunction derived from Papilio paris for efficient water splitting. RSC Adv 7(44):27354–27360
Zhang X, Lu X, Shen Y, Han J, Yuan L, Gong L, Xu Z, Bai X, Wei M, Tong Y, Gao Y, Chen J, Zhou J, Wang ZL (2011) Three-dimensional WO3 nanostructures on carbon paper: photoelectrochemical property and visible light driven photocatalysis. Chem Commun 47:5804–5806
Zhang Z et al (2012a) A novel model for undeformed nanometer chips of soft-brittle HgCdTe films induced by ultrafine diamond grits. Scripta Mater 67(2):197–200
Zhang Z et al (2012b) Fabrication and size prediction of crystalline nanoparticles of silicon induced by nanogrinding with ultrafine diamond grits. Scripta Mater 67(7–8):657–660
Zhang Z, Huo Y, Guo D (2013) A model for nanogrinding based on direct evidence of ground chips of silicon wafers. Sci China Technol Sci 56(9):2099–2108
Zhang Z et al (2015a) Changes in surface layer of silicon wafers from diamond scratching. CIRP Ann 64(1):349–352
Zhang Z et al (2015b) A novel approach of high speed scratching on silicon wafers at nanoscale depths of cut. Sci Rep 5:16395
Zhang Z et al (2016a) A novel approach of chemical mechanical polishing using environment-friendly slurry for mercury cadmium telluride semiconductors. Sci Rep 6:22466
Zhang Z et al (2016b) A novel approach of chemical mechanical polishing for cadmium zinc telluride wafers. Sci Rep 6:26891
Zhang Z et al (2017a) A novel approach of mechanical chemical grinding. J Alloy Compd 726:514–524
Zhang Z et al (2017b) Nanoscale wear layers on silicon wafers induced by mechanical chemical grinding. Tribol Lett 65(4):132
Zhang Z et al (2018) A novel approach of chemical mechanical polishing for a titanium alloy using an environment-friendly slurry. Appl Surf Sci 427:409–415
Zhang Z et al (2019) Environment friendly chemical mechanical polishing of copper. Appl Surf Sci 467:5–11
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The authors are thankful to Deanship of Scientific Research at King Khalid University for funding this work through Research Group Project under Grant number (R.G.P. 2/17/40).
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Tahir, M.B., Sagir, M., Muhammad, S. et al. Hierarchical WO3@ BiVO4 nanostructures for improved green energy production. Appl Nanosci 10, 1183–1190 (2020). https://doi.org/10.1007/s13204-019-01180-5
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DOI: https://doi.org/10.1007/s13204-019-01180-5