Abstract
The major concern in multilateral drilling is the torque and drag that arises as we drill deeper coupled with the escalation of bottomhole temperature, which can be overcome through the use of a lubricant: a solid or liquid form. Solid lubricants have been proved to be able to reduce the coefficient of friction substantially. In this research work, polymer beads were used as a lubricating agent in a high-temperature condition. The polymer beads which possessed improved physical properties were constructed using polymerization of styrene monomer added with divinylbenzene. The molecular structure and thermal properties of the polymer beads were evaluated using Fourier transform infrared analysis (FTIR) and thermogravimetric analysis (TGA), respectively. The lubricity test was conducted on four different types of sample, namely oil-based mud, water-based mud, and water-based mud with polymer and glass beads, at temperatures ranging from 60 to 180 °C. The experimental results were found to give an average reduction of 27.5 % of coefficient of friction at elevated temperature and the rheological properties experienced slight changes above 100 °C as compared to water-based mud. In a nutshell, the polymer beads show the potential to be used as a lubricating agent in high-temperature conditions.
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Introduction
Directional drilling and horizontal drilling techniques have led to the invention of extended reach drilling (ERD) (K & M Technology 2003). Nowadays, it becomes a common practice throughout the world as a means to reach a maximum number of wells from single location. This technique also has the ability to achieve horizontal well departures and total vertical depth to deviation ratio beyond the conventional experience of a particular field. The particular concerns on this technique are the torque and drag arises as we drill farther and deeper. Torque and drag minimization become a big challenge for ERD (Payne et al. 1995; Rubiandini 2008).
Mud lubricity is an indicator to measure the effect of torque and drag in ERD. The usage of oil-based mud as a drilling fluid had already proved to increase mud lubricity. However, due to the environmental concern that caused by the consumption of oil-based mud, it is strictly prohibited. So, the most suitable drilling fluid for ERD is water-based mud. Even though the performance of this type of drilling fluid is not as encouraging as oil-based mud in reducing torque and drag, an addition of the additive would mitigate the torque and drag problem (Aston et al. 1998). Usage of synthetic- or mineral–oil-based mud may give better lubricity performance than water-based mud, but it is proved more costly.
Solid particle is one of the lubricating agents, which is being used widely in water-based mud. This type of lubricating agent has the advantage of being compatible to all mud chemistry compared to the liquid type. Liquid lubricant is depending greatly on mud type to work effectively and it may be reduced by the presence of another mud additives (Cameroon 2001). It works by creating a thin film between two surfaces to minimize any contact between the surfaces. Meanwhile, solid particles usually beads will create a small stand-off distance for pressure communication and flow as well (Schamp and Estes 2006).
The result from the previous study had shown that the microbeads could reduce the friction in water-based mud significantly. Therefore, this research study was conducted to evaluate the characteristic and the performance of polymer beads in water-based mud as a lubricating agent under a high-temperature well condition.
Materials and experimental procedures
Four different drilling muds were used in this study: water-based mud, oil-based mud, water-based mud with polymer, and water-based mud with glass beads. Polymer beads were constructed using polymerization of styrene monomer and divinylbenzene. The constructed polymer beads have undergone several tests to determine its properties. Basically, all of the mud samples underwent lubricity and rheological test under normal and elevated temperatures.
The preparation of water-based mud
In the experimental works, fresh water-based mud was used as the base mud. It was prepared using water, potassium chloride (KCl), caustic soda (NaOH), bentonite, hydro-PAC, hydro-STAR and polymer beads. The mud additives were supplied by Scomi Oiltools. The compositions of drilling mud used were based on 1 lab barrel (1 lab barrel = 350 cc).
The preparation of oil-based mud
In order to make a comparison for reduction of coefficient of friction, oil-based mud had been used. This is important since we need to design our mud that can replicate the oil-based mud’s lubricity which possesses low value of coefficient of friction. The mud additives were supplied by Scomi Oiltools and the mud compositions were prepared based on 1 lab barrel (1 lab barrel = 350 cc).
The preparation of polymer beads
For this study, the polymer beads were constructed via the emulsion polymerization process. It was then added into water-based mud to study its effectiveness as a lubricating agent. The step of the polymer beads construction can be divided into two parts: purification styrene and divinylbenzene and emulsion. As shown in Figs. 1 and 2, the experimental apparatus and arrangement for polymer beads polymerization process.
Polymer beads characterization
The study on polymer beads properties was done to determine its ability to work under harsh wellbore condition. It also determines its compatibility to work in a drilling mud as a lubricating agent. The tests conducted on polymer beads sample are as follows:
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1.
Themogravimetric analysis (TGA)
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2.
Fourier Transform Infrared (FTIR) analysis
Lubricity test
Four different types of drilling mud sample were used in this study. The temperature range was from 60 to 180 °C. Lubricity Evaluation Monitor (LEM 4100) (Temco 2006) was used to study the mud lubricity behavior at normal and elevated temperatures. Note that all experiments were conducted in the following specific conditions:
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Test chamber pressure = 300–600 psig.
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Test chamber temperature = 60–180 °C.
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Reservoir temperature = 60–180 °C.
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Type of surface contact = Steel/rock.
Rheological properties study
The rheological properties of mud were studied at normal and elevated temperatures. For elevated temperature, the sample was placed in an aging cell and then heated-up in a roller oven for 16 h. The rheological properties tested in this study are as follows:
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1.
Mud weight
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2.
Plastic viscosity
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3.
Yield point
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4.
Gel strength
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5.
Fluid loss
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6.
Mud cake thickness
The experiments were conducted using standard laboratory equipment that recommended by American Petroleum Institute—Recommended Practices for Field Testing Water-based Drilling Fluids (API–RP–13B–1) (American Petroleum Institute 2009). The study of rheological properties is of utmost importance to determine the mud performance in sustaining its performance at high temperatures.
Results and discussion
The discussion of experimental results comprises polymer beads characteristics, mud lubricity performance, and rheological property changes of all muds at normal and elevated temperatures.
Polymer beads characteristics
Study conducted on polymer beads showed that it was suitable to be used under high-temperature condition due to its thermal stability. Based on the test conducted, it was found of having 24 %-degree of cross-linking which was a good value to work in drilling muds. The polymer beads were found to be decomposed at 423 °C, and the presence of benzene ring in the polymer beads allows the melting point to be that high, as shown in Figs. 3 and 4. This finding shows that the synthesized polymer beads would be able to sustain the Malaysian wellbore condition with average temperature 104 °C (Selamat et al. 2008) and can be up to 160 °C as recorded by Angsi Field (Murrey et al. 2003). Size of polymer beads which gave the lowest coefficient of friction in previous study was found to be in the range of 66–88 μm.
Mud lubricity
The main focus of this research study was to evaluate the lubricity among water-based mud, oil-based mud, water-based mud with glass beads, and water-based mud with polymer beads in high-temperature conditions. The temperature used for this study was from 60 to 180 °C. The equipment used for this study was Lubricity Evaluation Monitor (LEM-4100). The pump rate and bob speed were kept constant at 850 and 250 rpm, respectively. Pump speed represents the rate of mud flow into wellbore through nozzle on a drill bit while bob rotation represents drill bit rotation in a wellbore. Stationary sample used for this study was steel to rock surface.
Figure 5 shows the average coefficient of friction (CoF) for all of the samples tested at different temperatures. It showed that the polymer beads gave a comparable performance to glass beads in water-based mud at the elevated temperatures as a lubricity agent. This gives us an indication that the polymer beads have the potential to work well in a high-temperature condition. The average CoF reduction for polymer beads was 27.5 % while for glass beads was 26.5 %. The oil-based mud recorded about 86.8 % CoF reduction.
Polymer employed for this study was made of polystyrene (PS) crosslinked with divinylbenzene (DVB). This copolymer is thermally stable with properties of pore size distribution and degree of crosslinking are easy to control as mentioned by Skalle et al. (1999). As shown in the Fig. 5, the mud plus polymer beads gave comparable performance with the mud plus glass beads and do not affect by the temperature changes. This findings was supported by polymer beads characterization analysis. Based on polymer beads characterization, it was found to decompose at 423 °C. This indicates its ability of surviving under the high downhole temperature condition.
Rheological properties
Several tests were conducted to investigate the mud rheological properties in normal and elevated temperature conditions. The results were as follows:
Mud weight
Figure 6 shows the changes experienced by those four muds after being subjected to different elevated temperatures. Water-based mud experienced significant changes after being exposed to elevated temperatures. For water-based mud with polymer beads, it gave almost the same performance as water-based mud with glass beads. This is due to the melting points of these two products which were above 180 °C. This was proved by the data from TGA analysis which recorded that the weight loss happened at 423 °C, which represents the melting point. Meanwhile for glass beads, the melting point is at 730 °C. The presence of this glass and polymer beads in drilling mud did not have any effect on their mud weight.
Plastic viscosity
With the addition of a solid lubricant in drilling mud, the value of plastic viscosity will increase. Skalle at al. (1999) highlighted in their study that the presence of beads increases viscosity. Despite the slight fluctuation in value of plastic viscosity, it still shows a good agreement with ‘Scomi Oiltools’ recommended 20 cp of plastic viscosity value
Figure 7 shows the plastic viscosity of the tested mud at different elevated temperatures. Oil-based mud showed an increasing value of plastic viscosity as temperature increased. This trend was followed by water-based mud with glass beads, water-based mud with polymer beads, and water-based mud until 100 °C. These results showed that the presence of solids in drilling mud increases the viscosity. Polymer beads recorded lower plastic viscosity compared to glass beads. The absence of high-temperature additive in drilling mud was of main concern where the drilling mud could not sustain its rheological properties. Despite the changes in plastic viscosity values, it still shows a comparable performance with Scomi Oiltools’s recommended value of 20 cp. This happened after mud was exposed to elevated temperatures for 16 h in an aging cell. Except oil-based mud, the plastic viscosity of other mud samples was found to deteriorate after 100 °C.
Yield point
Figure 8 shows the results of those four types of drilling mud after being exposed to elevated temperatures. The oil-based mud experienced increase linearly in yield point as the temperature increased up to 180 °C. But, water-based mud plus glass beads, water-based mud plus polymer beads, and basic water-based mud increased in yield point up to 100 °C only and experienced decrease as temperature increased from 100 °C until 180 °C. This is due to the effect of beads present in the mud. However, water-based mud with glass beads gave higher yield point compared to polymer beads. After 100 °C, yield strength for water-based mud and water-based mud with both solid lubricants decreased. The absence of high-temperature additive in drilling mud once again affected the mud rheological properties. The rheological properties were found to experience changes significantly above 100 °C.
Gel strength
Figures 9 and 10 show the gel strength of the mud after being exposed to elevated temperatures. Oil-based mud revealed an increasing trend. This trend, however, was not followed by other drilling mud samples. All the drilling mud showed significant changes after 100 °C. Again, it was found that the gel strength of drilling mud with polymer beads and glass beads was similar. This rapid reduction in gel strength, however, failed to match the result achieved by Lummus and Azar (1986), which stated the recommended initial gel strength of 2–8 lb/100 ft2 for both 10 s and 10 min. It shows that after 100 °C, mud rheological properties were completely altered due to absence of high-temperature drilling mud additives.
Fluid loss
Figure 11 shows the fluid loss of the different types of mud under normal room condition. Water-based mud was found to produce the highest filtrate volume (i.e., 4.5 ml) as compared to others. Water-based mud with glass beads came next and followed by water-based mud with polymer beads and oil-based mud. They recorded 2.6, 2.4, and 1.6 ml of filtrate loss, respectively. It showed that the presence of beads in drilling mud has significantly reduced filtrate loss. The volume of filtrate loss for all those drilling muds was found to be in a good agreement with field standard, which stated that the volume of filtrate loss should be less than 5 ml (Bloemendal 1978).
The filtrate loss should be low enough to prevent excessive mud cake thickness and to reduce the chances of differential pressure sticking. Based on this statement, it was found that polymer beads produced lower filtrate volume compared to glass beads and water-based mud. According to Nazir and Ismail (2010), the presence of solid lubricants in the drilling mud seals the mud cake’s pores, thus reduces the volume of filtrate loss. Based on the experimental results, it showed that polymer beads are more effective in sealing the pores of mud cake than glass beads. Figure 12 shows the volume of filtrate loss for different types of mud that had been exposed to elevated temperatures. Water-based mud showed the highest volume of filtrate loss as temperature increased. It was followed by water-based mud with glass beads, water-based mud with polymer beads, and finally oil-based mud. It is important to keep the volume of filtrate as low as possible to create a thin and tough mud cake on a wellbore’s porous surface. At high temperatures, polymer beads once again produced lower filtrate loss as compared to glass beads. This shows the ability of polymer beads to fill the pores in the mud cake, and thus prevents excessive amount of filtrate loss. Polymer beads characteristic which is not as brittle as glass beads contributes to this phenomenon where it will be more easily packed together than glass beads.
Mud cake thickness
Figure 13 shows the mud cake thickness of four different types of drilling mud at elevated temperatures. Water-based mud produced thicker mud cakes as temperature increased. This trend was followed by water-based mud with glass beads, water-based mud with polymer beads, and oil-based mud. A similar trend was achieved at room temperature where water-based mud produced the thickest mud cake while oil-based mud gave the thinnest mud cake. Meanwhile, polymer beads were found to give a comparable performance at room and elevated temperature conditions, i.e., produced a thin mud cake compared to glass beads. Properties of polymer beads which were less brittle than glass beads allowed it to pack together, thus would reduce the thickness of its layer compared to glass beads.
Conclusions
Based on the research works accomplished on polymer beads in water-based mud as a lubricating agent, several conclusions could be framed out accordingly:
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1.
Polymer beads constructed were compatible for high-temperature condition since it could sustain until 450 °C. The chemical bonding of this polymer beads comprised benzene ring which makes it more resilient at high temperature.
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2.
These experimental results showed that polymer beads could be used as a lubricating agent in water-based mud at high-temperature wells. It gave a 27.5 % of CoF reduction. This result was found to be comparable to the performance shown by commercial solid lubricant which gave 26.5 % of CoF reduction. It was found to effectively reduce the CoF up to 100 °C.
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3.
The use of polymer beads did change the rheological properties of water-based mud. Those properties, however, were found to be within the recommended field range or values.
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Mamat, N.S., Ismail, I., Hashim, S. et al. The performance of polymer beads in water-based mud and its application in high-temperature well. J Petrol Explor Prod Technol 3, 151–158 (2013). https://doi.org/10.1007/s13202-013-0059-9
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DOI: https://doi.org/10.1007/s13202-013-0059-9