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Effect of acid hydrolysis combined with heat moisture treatment on structure and physicochemical properties of corn starch

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Abstract

Modification of starch led to new products with new desirable properties. Corn starch samples modified by acid hydrolysis combined with heat moisture treatment (AH-HMT) were made by changing pH, moisture content and treated temperature. After modification, swelling power at temperature higher than 75 °C of corn starches decreased while solubility of the starches increased. After AH-HMT, pasting temperature (PT) of all treated starch samples increased. But lower peak viscosity (PKV), trough viscosity (TV) and break down (BD) of most treated starch samples were observed. AH-HMT increased the gel hardness of all treated starches. And the biggest hardness of modified starch gel was 148.419 g, improving 93.471 g compared with native starch gel. The melting temperatures (To, Tp, Tc) of modified starch increased, but the melting range and △H decreased. The X-ray pattern remained practically unchanged with or without AH-HMT. Acid hydrolysis combined with heat moisture treatment (AH-HMT) improved the functional properties of corn starch.

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References

  • Abraham TE (1993) Stabilization of paste viscosity of cassava by heat moisture treatment. Starch/Staerke 45:131–135

    Article  CAS  Google Scholar 

  • Adebowale KO, Lawal OS (2003) Microstructure, physicochemical properties and retrogradation behavior of Mucuna bean (Mucuna pruriens) starch on heat moisture treatments. Food Hydrocolloids 17:265–272

    Article  CAS  Google Scholar 

  • Adebowale KO, Afolabi TA, Olu-Owolabi BI (2005) Hydrothermal treatments of Finger millet (Eleusine coracana) starch. Food Hydrocolloids 19:974–983

    Article  CAS  Google Scholar 

  • Biliaderis CG, Grant DR, Vose JR (1981) Structural characterization of legume starch. II. Studies on acid-treated starches. Cereal Chem 58:502–507

    CAS  Google Scholar 

  • Chung H-J, Jeong H-Y, Lim S-T (2003) Effects of acid hydrolysis and defatting on crystallinity and pasting properties of freeze-thawed high amylose corn starch. Carbohydr Polym 54:449–455

    Article  CAS  Google Scholar 

  • Chung HJ, Hoover R, Liu Q (2009) The impact of single and dual hydrothermal modifications on the molecular structure and physicochemical properties of normal corn starch. Int J Biol Macromol 44:203–210

    Article  CAS  Google Scholar 

  • Collado LS, Corke H (1999) Heat-moisture treatment effects on sweetpotato starches differing in amylose content. Food Chem 65:339–346

    Article  CAS  Google Scholar 

  • Collado LS, Mabesa LB, Oates CG, Corke H (2001) Bihon-type noodles from heat–moisture treated sweet potato starch. J Food Sci 66:604–609

    Article  CAS  Google Scholar 

  • Cooke D, Gidley MJ (1992) Loss of crystallinity and molecular order during starch gelatinization: origin of the enthalpic transition. Carbohydr Res 227:103–112

    Article  CAS  Google Scholar 

  • Donovan JW, Lorenz K, Kulp K (1983) Differential scanning calorimetry of heat–moisture treated wheat and potato starches. Cereal Chem 60:381–387

    Google Scholar 

  • Eliasson A-C (1980) Effect of water content on the gelatinization of wheat starch. Starch/ Stärke 32:270–272

    Google Scholar 

  • Eliasson A-C, Gudmundsson M (2006) Starch: physicochemical and functional aspects. In: Eliasson A-C (ed) Carbohydrates in food, 2nd edn. CRC Press, Boca Raton, pp 391–469

    Google Scholar 

  • Franco ML, Preto SJR, Ciacco FC, Tavares DQ (1995) Effect of the heat moisture treatment on the enzymatic susceptibility of corn starch granules. Starch-Starke 47:233–228

    Article  Google Scholar 

  • Gunaratne A, Hoover R (2002) Effect of heat-moisture on the structure and physicochemical properties of tuber and root starches. Carbohydr Polym 49:425–437

    Article  CAS  Google Scholar 

  • Han XZ, Campanella OH, Mix NC, Hamaker BR (2002) Consequence of starch damage on rheological properties of maize starch pastes. Cereal Chem 79:897–901

    Article  CAS  Google Scholar 

  • Hoover R, Manuel H (1996) The e.ect of heat-moisture treatment on the structure and physicochemical properties of normal maize, waxy maize, dull waxy maize and amylomaize V starches. J Cereal Sci 23:153–162

    Article  CAS  Google Scholar 

  • Hoover R, Vasanthan T (1994) The flow properties of native, heat moisture treated and annealed starches from wheat, oat, potato and lentil. J Food Biochem 18:67–82

    Article  CAS  Google Scholar 

  • Hoover R, Swamidas G, Vasanthan T (1993) Studies on the physicochemical properties of native, defatted, and heat moisture treated pigeon pea (Cijanus cajan T) starch. Carbohydr Res 246:185–203

    Google Scholar 

  • Hormdok R, Noomhorm (2007) A. Hydrothermal treatments of rice starch for improvement of rice noodle quality. LWT Food Sci Technol 40:1723–1731

    Article  CAS  Google Scholar 

  • Jiranuntakul W, Puttanlek C, Rungsardthong V, Puncha-arnon S, Uttapap D (2011) Microstructural and physicochemical properties of heat-moisture treated waxy and normal starches. J Food Eng 104:246–258

    Article  CAS  Google Scholar 

  • Kainuma K, French D (1971) Naegeli amylodextrin and it relationship to starch granule structure. I. Preparation and properties of amylodextrins from various starch types. Biopolymers 10:1673–1680

    Article  CAS  Google Scholar 

  • Kim RE, Ahn SY (1996) Gelling properties of acid-modified red bean starch gels. Agric Chem Biotechnol 39:49–53

    CAS  Google Scholar 

  • Koksel H, Masatcioglu T, Kahraman K, Ozturk S (2008) Improving effect of lyophilization on functional properties of resistant starch preparations formed by acid hydrolysis and heat treatment. J Cereal Sci 7(275):282

    Google Scholar 

  • Kulp K, Lorenz K (1981) Heat–moisture treatment of starches. I. Physicochemical properties. Cereal Chem 5:46–48

    Google Scholar 

  • Kurakake M, Tachibana Y, Masaki K, Komaki T (1996) Adsorption of alpha-amylase on heat-moisture treated starch. J Cereal Sci 23:163–168

    Article  CAS  Google Scholar 

  • Maruta I, Kurahashi Y, Takano R, Hayashi K, Yoshino Z, Komaki T, Hara S (1994) Reduced-pressurized heat-moisture treatment: a new method for heat-moisture treatment of starch. Starch/Staerke 46:177–181

    CAS  Google Scholar 

  • Nakazawa Y, Wang Y-J (2003) Acid hydrolysis of native and annealed starches and branch-structure of their Naegeli dextrins. Carbohydr Res 338:2871–2882

    Article  CAS  Google Scholar 

  • Olayinka OO, Adebowale KO, Olu-Owolabi BI (2008) Effect of heatmoisture treatment on physicochemical properties of white sorghum starch. Food Hydrocolloids 22:225–230

    Article  CAS  Google Scholar 

  • Osunsam AT, Akingbala JO, Oguntimein GB (1989) Effect of storage on starch content and modification of cassava starch. Starch-Starke 41:54–57

    Article  Google Scholar 

  • Sandhu KS, Singh N, Lim ST (2007) A comparison of native and acid thinned normal and waxy corn starches: physiochemical, thermal, morphological and pasting properties. LWT Food Sci Technol 40:1527–1536

    Article  CAS  Google Scholar 

  • Schoch TJ (1964) Swelling power and solubility of granular starches: whole starches and modified starches. In: Whistler RL (ed) Methods in carbohydrate chemistry vol. 4. Academic Press, New York, p 106

  • Shin SI, Byun J, Park KH, Moon TW (2004) Effect of partial acid hydrolysis and heat-moisture treatment on formation of resistant tuber starch. Cereal Chem 81(2):194–198

    Article  CAS  Google Scholar 

  • Song Y, Jane J (2000) Characterization of barley starches of waxy, normal, and high amylose varieties. Carbohydr Polym 41:365–377

    Article  CAS  Google Scholar 

  • Stute R (1992) Hydrothermal modification of starches: the difference between annealing and heat moisture treatment. Starch/Staerke 6:205–214

    Article  Google Scholar 

  • Vermeylen R, Goderis B, Delcour JA (2006) An X-ray study of hydrothermal treated potato starch. Carbohydr Polym 64:364–375

    Article  CAS  Google Scholar 

  • Wang YJ, Truong VN, Wang L (2003) Structures and rheological properties of corn starch as affected by acid hydrolysis. Carbohydr Polym 52:327–333

    Article  CAS  Google Scholar 

  • Watcharatewinkul Y, Puttanlek C, Rungsardthong V, Uttapap D (2009) Pasting properties of a heat-moisture treated canna starch in relation to its structural characteristics. Carbohydr Polym 75:505–511

    Article  CAS  Google Scholar 

  • Yoenyongbuddhagal S, Noohorm A (2002) Effect of physicochemical properties of high-amylose Thai rice flours on vermicelli quality. Cereal Chem 79(4):481–485

    Article  CAS  Google Scholar 

  • Zobel HF (1988) Molecules to granules: a comprehensive starch review. Starch-Starke 40:44–50

    Article  CAS  Google Scholar 

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Correspondence to Qingjie Sun.

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Sun, Q., Zhu, X., Si, F. et al. Effect of acid hydrolysis combined with heat moisture treatment on structure and physicochemical properties of corn starch. J Food Sci Technol 52, 375–382 (2015). https://doi.org/10.1007/s13197-013-0998-7

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  • DOI: https://doi.org/10.1007/s13197-013-0998-7

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