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Plastic fats from sal, mango and palm oil by lipase catalyzed interesterification

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Abstract

Speciality plastic fats with no trans fatty acids suitable for use in bakery and as vanaspati substitute were prepared by interesterification of blends of palm stearin (PSt) with sal and mango fats using Lipozyme TLIM lipase as catalyst. The blends containing PSt/sal or PSt/mango showed short melting range and hence are not suitable as bakery shortenings. Lipase catalysed interesterification extended the plasticity or melting range of all the blends. The blends containing higher proportion of PSt with sal fat (50/50) were harder having high solids at and above body temperature and hence cannot be used as bakery shortenings. The blends with PSt/sal (30–40/60–70) after interesterification showed melting profiles similar to those of commercial hydrogenated bakery fats. Similarly, the blends containing PSt/mango (30–40/60–70) after interesterification also showed melting profiles similar to those of commercial hydrogenated shortenings. The slip melting point and solidification characteristics also confirm the plastic nature of these samples. The improvement in plasticity after interesterification is due to formation of higher melting as well as lower melting triglycerides during lipase catalysed interesterification.

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References

  • Adhikari S, Dasgupta J, Bhattacharyya DK, Chakraborty MM (1981) Studies on preparation of plastic fats from non-traditional oils and fats by interesterification. Fette Seifen Anstrichmittel 83:262–267

    Article  CAS  Google Scholar 

  • AOCS (2002–2003) Official methods and recommended practices of the American Oil Chemists’ Society, 5th edn. American Oil Chemists Society, AOCS Press, Champaign, IL

  • Boleslaw K, Tarnowska K, Gruczynska E, Bekas W (2004) Chemical and enzymatic interesterification of beef tallow and rape seed oil equal-weight blend. Eur J Lipid Sci Technol 106:655–664

    Article  Google Scholar 

  • Daniel U, Markovits A, Erazo S (2001) Cocoa butter equivalent through enzymatic interesterification of palm oil mid fraction. Process Biochem 36:933–939

    Article  Google Scholar 

  • De Man L, D’Souza V, De Man JM, Blackman B (1992) Polymorphic stability of some shortening as influenced by the fatty acid and glyceride composition of solid phase. J Am Oil Chem Soc 69:246–250

    Article  Google Scholar 

  • De Martini Soares FAS, da Silva RC, Guimarães da Silva KC, Lourenco MB, Soares DF, Gioielli LA (2009) Effects of chemical interesterification on physicochemical properties of blends of palm stearin and palm olein. Food Res Int 42:1287–1294

    Article  Google Scholar 

  • Duncan DB (1955) New multiple range and multiple F test. Biometrics 11:1–42

    Article  Google Scholar 

  • Etherton PK (1995) Trans fatty acid and coronary heart diseases risk. Am J Clin Nutr 62:655S–708S

    Google Scholar 

  • Farmani J, Hamedi M, Safari M, Madadlou A (2007) Trans free Iranian vanaspati through ezymatic and chemical transesterification of triple blends of fully hydrogenated soybean, rapeseed and sunflower oils. Food Chem 102:827–833

    Article  CAS  Google Scholar 

  • Haryati T, Che Man YB, Jinap S, Ghazali HM (1999) Optimization of chemical transesterification of palm oil using surface methodology. J Food Lipids 6:91–106

    Article  CAS  Google Scholar 

  • Hodgson BF (1996) Refining and bleaching. In: Hui YH (ed) Bailey’s industrial oils and fats products. Interscience Publication, Johan Wiley and Sons Inc, New York

    Google Scholar 

  • International Union of pure and applied Chemistry (IUPAC) (1987) In: Paquot C, Hautfenne A (eds) Standard methods for the analysis of oils, fats and derivatives, 7th edn. Blackwell Scientific Publications, London

    Google Scholar 

  • Khatoon S (2000) Semisolid fat by interesterification of red palm oil with other vegetable oils. J Food Lipids 7:83–93

    Article  CAS  Google Scholar 

  • Khatoon S, Bhattacharya DK (1985) Preparation of vanaspati and margarine fat base from sal fat and selective vegetable oils by interesterification reaction. J Oil Technol Assoc India 17:58–60

    CAS  Google Scholar 

  • Khatoon S, Reddy SY (2005) Plastic fats with zero trans fatty acid by interesterification of mango, mahua and palm oils. Eur J Lipid Sci Technol 107:786–791

    Article  CAS  Google Scholar 

  • List GR (2004) Processing and reformulation for nutritional labeling of trans fatty acids. Lipid Technol 16:173–177

    CAS  Google Scholar 

  • Liu Y, Zong M, Liang S, Jin Q, Wang X (2010) Preparation of specialty fats from beef tallow and canola oil by chemical interesterification: physico-chemical properties and bread applications of the products. Int J Food Sci Technol 45:1321–1329

    Article  Google Scholar 

  • Mayamol PN, BalachandranC SamuelT, Sundaresan A, Arumughan C (2009) Zero trans shortening using rice bran oil, palm oil and palm stearin through interesterification at pilot scale. Int J Food Sci Technol 44:18–28

    Article  CAS  Google Scholar 

  • Mitra K, Lee JH, Lee KT, Kim SA (2010) Production tactic and physiochemical properties of low w6⁄w3 ratio structured lipid synthesized from perilla and soybean oil. Int J Food Sci Technol 45:1321–1329

    Article  CAS  Google Scholar 

  • Natália MO, Eric D, da Maria MR, Fonseca SFD (2009) Lipase/acyl transferase catalysed interesterification of fat blends containing n-3 polyunsaturated fatty acids. Eur J Lipid Sci Technol 111:120–134

    Article  Google Scholar 

  • Noor Lida HMD, Sundram K, Idris NA (2007) Effect of chemical interesterification on Triacylglycerol and solid fat content of palm stearin, sunflower oil and palm kernel olein blends. Eur J Lipid Sci Technol 109:147–156

    Article  Google Scholar 

  • Norizzah AR, Chong CL, Cheow CS, Zaliha O (2004) Effects of chemical interesterification on physicochemical properties of palm stearin and palm kernel olein blends. Food Chem 86:229–235

    Article  CAS  Google Scholar 

  • Reddy SY, Jeyarani T (2001) Trans free bakery shortenings from mango kernel and mahua fats by fractionation and blending. J Am Oil Chem Soc 78:635–640

    Article  CAS  Google Scholar 

  • Reshma MV, Saritha SS, BalachandranC AC (2008) Lipase catalyzed interesterification of palm stearin and ricebran oil blends for preparation of zero trans shortening withbioactive phytochemicals. Bioreso Technol 99:5011–5019

    Article  CAS  Google Scholar 

  • Ribeiro AB, Rodrigo CB, Grimaldi R, Luiz AG, Lireny AGG (2009) Effect of chemical interesterification on physicochemical properties and industrial applications of canola oil and fully hydrogenated cottonseed oil blends. J F Lipids 16:362–381

    Article  CAS  Google Scholar 

  • Rodriguez A, Castro E, Maria CS, Lopez R, Miranda M (2001) Interesterification of tallow and sunflower oil. J Am Oil Chem Soc 78:431–436

    Article  CAS  Google Scholar 

  • Sabine D, Claude D (2003) Blending of hydrogenated low erucic acid rapeseed oil, low erucic acid rapeseed oil; low erucic acid rapeseed oil and hydrogenated palm oil or palm oil in the preparation of shortenings. J Am Oil Chem Soc 80:1069–1075

    Article  Google Scholar 

  • Wai LS, Cheah KY, Tang WL (2007) Physical properties of lipase catalyzed interesterification of palm stearin with canola oil blends. Eur J Lipid Sci Technol 109:97–106

    Article  Google Scholar 

  • Wang J, Shahidi F (2011) Effect of enzymatic randomization on positional distribution and stability of seal blubber and menhaden oils. J Agr Food Chem 59:4232–4237

    Article  CAS  Google Scholar 

  • Wilton I, Wode G (1963) Quick and simple methods for studying crystallization behavior of fats. J Am Oil Chem Soc 40:707–711

    Article  CAS  Google Scholar 

  • Zahra KY, Alemzadeh I (2011) Improvement of palm oil and sunflower oil blends by enzymatic Interesterification. Int Food Sci Technol 46:1093–1099

    Article  Google Scholar 

  • Zarringhalami S, Sahari MA, Barzegar M, Hamidi-Esfehani Z (2010) Enzymatically modified tea seed oil as cocoa butter replacer in dark chocolate. Int J Food Sci Technol 45:540–545

    Article  CAS  Google Scholar 

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Acknowledgement

The authors thank Dr. Lokesh, B.R., Head of the Department, and Dr. Prakash, V., Director of the Institute, for their keen interest in the work.

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Correspondence to Sakina Khatoon.

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Shankar Shetty, U., Sunki Reddy, Y.R. & Khatoon, S. Plastic fats from sal, mango and palm oil by lipase catalyzed interesterification. J Food Sci Technol 51, 315–321 (2014). https://doi.org/10.1007/s13197-011-0492-z

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  • DOI: https://doi.org/10.1007/s13197-011-0492-z

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