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Baseline establishment for metals in the western Clarion-Clipperton Zone

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Abstract

Resource exploitation in the Clarion-Clipperton Zone (CCZ) is of major research interest worldwide, but its influence on the environment is poorly understood, especially due to the lack of baseline values for metals in the surrounding sediment. This work aimed to establish the baseline values of 17 metals (Ba, Ca, K, Mg, Mn, Na, Ag, As, B, Cd, Co, Cr, Cu, Hg, Ni, Pb, and Zn) using normalization, the cumulative frequency curve method considering a total of 172 samples taken from 8 multitube cores and 1 box sediment core collected in the western CCZ during the COMRA-45 cruise campaign from August to September 2017. The baseline values of the evaluated metals were as follows: 1 932 mg/kg for Ba, 29 512 mg/kg for Ca, 18 150 mg/kg for K, 17 120 mg/kg for Mg, 6 747 mg/kg for Mn, 28 546 mg/kg for Na, 0.571 mg/kg for Ag, 5.00 mg/kg for As, 94.4 mg/kg for B, 0.626 mg/kg for Cd, 104 mg/kg for Co, 76.1 mg/kg for Cr, 370 mg/kg for Cu, 0.028 mg/kg for Hg, 190 mg/kg for Ni, 27.5 mg/kg for Pb and 156 mg/kg for Zn. Our findings would fill the baseline value gap in the study area and further improve accuracy of environmental impact assessments on the impact of resource exploitation.

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References

  • Bischoff J L, Heath G R, Leinen M L. 1979. Geochemistry of deep-sea sediments from the Pacific manganese nodule province: DOMES sites A, B, and C. In: Bischoff J L, Piper D Z, eds. Marine Geology and Oceanography of the Pacific Manganese Nodule Province. New York: Plenum Press, 397–436

    Chapter  Google Scholar 

  • Chatterjee M, Filho E V S, Sarkar S K, et al. 2007. Distribution and possible source of trace elements in the sediment cores of a tropical macrotidal estuary and their ecotoxicological significance. Environment International, 33(3): 346–356, doi: https://doi.org/10.1016/j.envint.2006.11.013

    Article  Google Scholar 

  • Colizza E, Fontolan G, Brambati A. 1996. Impact of a coastal disposal site for inert wastes on the physical marine environment, Barcola-Bovedo, Trieste, Italy. Environmental Geology, 27(4): 270–285, doi: https://doi.org/10.1007/BF00766697

    Article  Google Scholar 

  • Deng Yinan, Ren Jiangbo, Guo Qingjun, et al. 2018. Geochemistry characteristics of REY-rich sediment from deep sea in Western Pacific, and their indicative significance. Acta Petrologica Sinica, 34(3): 733–747

    Google Scholar 

  • El-Hasan T, Jiries A. 2001. Heavy metal distribution in valley sediments in Wadi Al-Karak catchment area, South Jordan. Environmental Geochemistry and Health, 23(2): 105–116, doi: https://doi.org/10.1023/A:1010918014577

    Article  Google Scholar 

  • General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, Standardization Administration of China. 2007. The Specification of Oceanographic Survey—Part 8: Marine Geology and Geophysics Survey (GB/T 12763.8-2007). Beijing: Standards Press of China, 7–9

    Google Scholar 

  • General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, Standardization Administration of China. 2008. The Specification for Marine Monitoring—Part 5: Sediment Analysis (GB 17378.5-2007). Beijing: Standards Press of China, 80

    Google Scholar 

  • Huang Mu, Liu Jihua, Shi Xuefa, et al. 2014. Geochemical characteristics and material sources of rare earth elements in sediments from the CC area in the eastern Pacific Ocean. Advances in Marine Science, 32(2): 175–187

    Google Scholar 

  • Jiang Jianbin, Wang Jing, Liu Shaoqing, et al. 2013. Background, baseline, normalization, and contamination of heavy metals in the Liao River Watershed sediments of China. Journal of Asian Earth Sciences, 73: 87–94, doi: https://doi.org/10.1016/j.jseaes.2013.04.014

    Article  Google Scholar 

  • Karim Z, Qureshi B A, Mumtaz M. 2015. Geochemical baseline determination and pollution assessment of heavy metals in urban soils of Karachi, Pakistan. Ecological Indicators, 48: 358–364, doi: https://doi.org/10.1016/j.ecolind.2014.08.032

    Article  Google Scholar 

  • Korfali S I, Davies B E. 2003. A comparison of metals in sediments and water in the river Nahr-Ibrahim, Lebanon: 1996 and 1999. Environmental Geochemistry and Health, 25(1): 41–50, doi: https://doi.org/10.1023/A:1021284126632

    Article  Google Scholar 

  • Kuang Yaoqiu, Huang Yongyang, Zhong Hexian. 2004. Clues to the geochemical evolution of the sedimentary environment as revealed by factor analysis of sediments in area CC of the East Pacific oceanic basin. Geology in China, 31(3): 325–331

    Google Scholar 

  • Li Zhichun. 2013. Research on the pollution characteristics of heavy metals in sediments from the Tuohe River, Suzhou City, Anhui Province (in Chinese) [dissertation]. Huainan: Anhui University of Science & Technology

    Google Scholar 

  • Li Tong, Yuan Huaiyu. 2011. Element abundance in the oceanic and the continental lithospheres. Geochimica, 40(1): 1–5

    Google Scholar 

  • Liang Ying, He Jiang, Lv Changwei, et al. 2009. Concentration and spatial distribution of bio-available fraction of heavy metals in the sediments from the Nanhai Lake. Journal of Agro-Environment Science, 28(6): 1208–1213

    Google Scholar 

  • Lin Cai, Lin Hui, Chen Jinmin, et al. 2011. Pollution assessment of heavy metals in the sediment of Jiulong River Estuary. Marine Sciences, 35(8): 11–17

    Google Scholar 

  • Lin Cai, Liu Yang, Li Wenquan, et al. 2014. Speciation, distribution, and potential ecological risk assessment of heavy metals in Xiamen Bay surface sediment. Acta Oceanologica Sinica, 33(4): 13–21, doi: https://doi.org/10.1007/s13131-014-0453-2

    Article  Google Scholar 

  • Lv Huahua. 2005. Study on the typical characteristics and application of clay sediments from the Northern Equatorial Pacific (in Chinese) [dissertation]. Qingdao: The Institute of Oceanology, Chinese Academy of Sciences

    Google Scholar 

  • Mandour A, El-Sayed M K, El-Gamal A A, et al. 2021. Temporal distribution of trace metals pollution load index in the Nile Delta coastal surface sediments. Marine Pollution Bulletin, 167: 112290, doi: https://doi.org/10.1016/j.marpolbul.2021.112290

    Article  Google Scholar 

  • Matschullat J, Maenhaut W, Zimmermann F, et al. 2000. Aerosol and bulk deposition trends in the 1990’s, Eastern Erzgebirge, Central Europe. Atmospheric Environment, 34(19): 3213–3221, doi: https://doi.org/10.1016/S1352-2310(99)00516-6

    Article  Google Scholar 

  • Newman B K, Watling R J. 2007. Definition of baseline metal concentrations for assessing metal enrichment of sediment from the south-eastern Cape coastline of South Africa. Water SA, 33(5): 675–691

    Google Scholar 

  • Niu Siping, Gao Liangmin, Wang Xuan. 2019. Characterization of contamination levels of heavy metals in agricultural soils using geochemical baseline concentrations. Journal of Soils and Sediments, 19(4): 1697–1707, doi: https://doi.org/10.1007/s11368-018-2190-1

    Article  Google Scholar 

  • O’Donnell K E, Freestone S E, Nice S E. 2004. Geochemical Baseline Data for the Urban Area of Kingston-upon-Hull. London: NERC

    Google Scholar 

  • Pratap A, Mani F S, Prasad S. 2020. Heavy metals contamination and risk assessment in sediments of Laucala Bay, Suva, Fiji. Marine Pollution Bulletin, 156: 111238, doi: https://doi.org/10.1016/j.marpolbul.2020.111238

    Article  Google Scholar 

  • Rate A W, Robertson A E, Borg A T. 2000. Distribution of heavy metals in near-shore sediments of the Swan River Estuary, Western Australia. Water, Air, and Soil Pollution, 124(1): 155–168

    Article  Google Scholar 

  • Ren Jiangbo, Yao Huiqiang, Zhu Kechao, et al. 2015. Enrichment mechanism of rare earth elements and yttrium in deep-sea mud of Clarion-Clipperton Region. Earth Science Frontiers, 22(4): 200–211

    Google Scholar 

  • Schiff K C, Weisberg S B. 1999. Iron as a reference element for determining trace metal enrichment in southern California coastal shelf sediments. Marine Environmental Research, 48(2): 161–176, doi: https://doi.org/10.1016/S0141-1136(99)00033-1

    Article  Google Scholar 

  • Siddiqui E, Pandey J. 2019. Assessment of heavy metal pollution in water and surface sediment and evaluation of ecological risks associated with sediment contamination in the Ganga River: a basin-scale study. Environmental Science and Pollution Research, 26(11): 10926–10940, doi: https://doi.org/10.1007/s11356-019-04495-6

    Article  Google Scholar 

  • Sim S F, Chai H P, Nyanti L, et al. 2016. Baseline trace metals in water and sediment of the Baleh River—a tropical river in Sarawak, Malaysia. Environmental Monitoring and Assessment, 188(9): 537, doi: https://doi.org/10.1007/s10661-016-5553-3

    Article  Google Scholar 

  • Singh M, Müller G, Singh I B. 2003. Geogenic distribution and baseline concentration of heavy metals in sediments of the Ganges River, India. Journal of Geochemical Exploration, 80(1): 1–17, doi: https://doi.org/10.1016/S0375-6742(03)00016-5

    Article  Google Scholar 

  • Singh H, Pandey R, Singh S K, et al. 2017. Assessment of heavy metal contamination in the sediment of the River Ghaghara, a major tributary of the River Ganga in Northern India. Applied Water Science, 7(7): 4133–4149, doi: https://doi.org/10.1007/s13201-017-0572-y

    Article  Google Scholar 

  • State Oceanic Administration. 2013. Code of Practice for Marine Monitoring Technology—Part 2: Sediment (HY/T 147.2-2013). Beijing: Standards Press of China, 55

    Google Scholar 

  • Sun Houyun, Wei Xiaofeng, Gan Fengwei, et al. 2019. Determination of heavy metal geochemical baseline values and its accumulation in soils of the Luanhe River basin, Chengde. Environmental Science, 40(8): 3753–3763

    Google Scholar 

  • Taylor M P. 2007. Distribution and storage of sediment-associated heavy metals downstream of the remediated Rum Jungle Mine on the East Branch of the Finniss River, Northern Territory, Australia. Journal of Geochemical Exploration, 92(1): 55–72, doi: https://doi.org/10.1016/j.gexplo.2006.07.005

    Article  Google Scholar 

  • Teng Yanguo, Ni Shijun, Wang Jinsheng, et al. 2009. Geochemical baseline of trace elements in the sediment in Dexing area, South China. Environmental Geology, 57(7): 1649–1660, doi: https://doi.org/10.1007/s00254-008-1446-2

    Article  Google Scholar 

  • Veinott G, Perron-Cashman S, Anderson M R. 2001. Baseline metal concentrations in coastal Labrador sediments. Marine Pollution Bulletin, 42(3): 187–192, doi: https://doi.org/10.1016/S0025-326X(00)00141-7

    Article  Google Scholar 

  • Wang Fenlian. 2017. The characteristics of REE and Nd isotopes and their provenance significance of the pelagic sediments from the Pacific Ocean. Geological Review, 2017,63(S1): 201–202

    Google Scholar 

  • Wang Jiankang, Peng Wenqi, Wang Shaoming, et al. 2020. Establishment of geochemical baseline and multiple assessment of vanadium pollution in sediment cores from the two cascade reservoirs, North China. Environmental Science and Pollution Research, 27(11): 11565–11574, doi: https://doi.org/10.1007/s11356-020-07673-z

    Article  Google Scholar 

  • Wei Chaoyang, Wen Hailong. 2012. Geochemical baselines of heavy metals in the sediments of two large freshwater lakes in China: implications for contamination character and history. Environmental Geochemistry and Health, 34(6): 737–748, doi: https://doi.org/10.1007/s10653-012-9492-9

    Article  Google Scholar 

  • Yang Rui, Li Guosheng, Zhang Hongrui. 2007a. Analysis on the geochemical characteristics and material origin of the surface sediments in the Mid-Pacific Ocean. Geology and Resources, 16(3): 200–208

    Google Scholar 

  • Yang Rui, Li Guosheng, Zhang Hongrui. 2007b. Geochemical characteristics of quaternary sediments in Mid-Pacific Ocean and an analysis of the material source in CC areas. Geophysical & Geochemical Exploration, 31(4): 293–297

    Google Scholar 

  • Zhang Congwei, Li Liang, Long Genyuan, et al. 2018. Geochemical characteristics and environmental assessment of heavy metal elements in surface sediments from the offshore area of eastern Sanya. Journal of Marine Sciences, 36(2): 55–63

    Google Scholar 

  • Zhang Fuyuan, Yang Qunhui, Yin Ruguang, et al. 2001. Material sources and distribution characteristics of polymetallic nodules in the Eastern Pacific. Acta Geologica Sinica, 75(4): 537–547

    Google Scholar 

  • Zhu Aimei, Zhang Hui, Cui Jingjing, et al. 2019. Environmental quality assessment and influence factor of heavy metals in the surface sediments from the Bohai Sea. Haiyang Xuebao (in Chinese), 41(12): 134–144

    Google Scholar 

  • Zhuang Wen, Zhou Fengxia. 2021. Distribution, source and pollution assessment of heavy metals in the surface sediments of the Yangtze River Estuary and its adjacent East China Sea. Marine Pollution Bulletin, 164: 112002, doi: https://doi.org/10.1016/j.marpolbul.2021.112002

    Article  Google Scholar 

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Acknowledgements

The authors thank all crew member and researchers on R/V Xiangyanghong 03 aboard in COMRA-45 Cruise.

Funding

The Eastern Pacific Eco-environment Monitoring and Protection Project under contract No. DY135-E2-5-02; the Scientific Research Foundation of Third Institute of Oceanography, Ministry of Natural Resources of China under contract No. 2017014; the Global Change and Air-Sea Interaction II under contract No. GASI-01-NPAC-STsum; the Fund of COMRA-45 Cruise under contract No. DYHC-135-45.

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Correspondence to Yang Liu or Hui Lin.

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Lin, C., Liu, Y., Jiang, R. et al. Baseline establishment for metals in the western Clarion-Clipperton Zone. Acta Oceanol. Sin. 41, 12–22 (2022). https://doi.org/10.1007/s13131-021-1908-x

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