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The spatial assessment of acid mine drainage potential within a low-grade ore dump: the role of preferential flow paths

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Abstract

The potential release of pollutants from a low-grade ore dump in the Miduk mine was evaluated based on geochemical and mineralogical characteristics. The main environmental risks associated with the dump were the potential for acid mine drainage (AMD) generation and the transport of acidic leachate with high contents of toxic elements (As, Pb, Cu and Zn) into the depths of Earth. Geochemical characteristics of rocks such as the content of sulphur species (Stotal, Spyrite and Ssulphate) were assessed. In addition, the elemental composition of the rock and leaching solution samples were determined. Based on both static and NAG tests, materials with a paste pH < 4 had the high potential of AMD generation. Principal component analysis (PCA) was employed to integrate the results of AMD prediction tests with mineralogical and geochemical compositions of the rocks. Based on PCA, eight principal components (PC1–PC8) were accounted for 93% of the total variance of data. Two components of PC2 and PC3 were determined as primary factors of AMD generation. The extracted principal components were interpolated within the dump by ordinary kriging method. Based on the environmental risk map of the PC3, the main source of AMD generation is the north-eastern part of the dump, which spatially varied from the dump surface up to a depth of 3 m. Heterogeneous distribution of preferential paths by providing different oxygen and moisture contents is responsible for non-uniform pyrite oxidation at different parts of the dump. The results of the present study will provide useful information for further rock dump management approaches.

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References

  • Abraitis P, Pattrick R, Vaughan D (2004) Variations in the compositional, textural and electrical properties of natural pyrite: a review. Int J Miner Process 74:41–59

    Google Scholar 

  • Akcil A, Koldas S (2006) Acid mine drainage (AMD): causes, treatment and case studies. J Clean Prod 14:1139–1145

    Google Scholar 

  • Amos RT, Blowes DW, Bailey BL, Sego DC, Smith L, Ritchie AIM (2015) Waste-rock hydrogeology and geochemistry. Appl Geochem 57:140–156

    Google Scholar 

  • Antunes I, Albuquerque M, Sanches F (2014) Spatial risk assessment related to abandoned mining activities: an environmental management tool. Environ Earth Sci 72:2631–2641

    Google Scholar 

  • ASTM (2007) ASTM D422-63: standard test method for particle-size analysis of soils

  • ASTM (2010) ASTM D2216-10: standard test methods for laboratory determination of water (moisture) content of soil and rock by mass. ASTM International West Conshohocken, PA

    Google Scholar 

  • ASTM (2012a) ASTM D854-02: standard test methods for specific gravity of soil solids by water pycnometer

  • ASTM (2012b) ASTM D2492-02: standard test method for forms of sulfur in coal

  • Balci N, Demirel C (2018) Prediction of acid mine drainage (AMD) and metal release sources at the Küre Copper Mine Site, Kastamonu, NW Turkey. Mine Water Environ 37:56–74

    Google Scholar 

  • Ball JW, Nordstrom DK (1991) User’s manual for WATEQ4F, with revised thermodynamic data base and test cases for calculating speciation of major, trace, and redox elements in natural waters

  • Blackmore S, Vriens B, Sorensen M, Power IM, Smith L, Hallam SJ, Mayer KU, Beckie RD (2018) Microbial and geochemical controls on waste rock weathering and drainage quality. Sci Total Environ 640:1004–1014

    Google Scholar 

  • Boomeri M, Nakashima K, Lentz DR (2009) The Miduk porphyry Cu deposit, Kerman, Iran: a geochemical analysis of the potassic zone including halogen element systematics related to Cu mineralization processes. J Geochem Explor 103:17–29

    Google Scholar 

  • Carbone C, Dinelli E, Marescotti P, Gasparotto G, Lucchetti G (2013) The role of AMD secondary minerals in controlling environmental pollution: indications from bulk leaching tests. J Geochem Explor 132:188–200

    Google Scholar 

  • Dold B (2017) Acid rock drainage prediction: a critical review. J Geochem Explor 172:120–132

    Google Scholar 

  • Elghali A, Benzaazoua M, Bouzahzah H, Bussière B, Villarraga-Gómez H (2018) Determination of the available acid-generating potential of waste rock, part I: mineralogical approach. Appl Geochem 99:31–41

    Google Scholar 

  • Elghali A, Benzaazoua M, Bussière B, Genty T (2019) Spatial mapping of acidity and geochemical properties of oxidized tailings within the former Eagle/Telbel mine site. Minerals 9:180

    Google Scholar 

  • Fala O, Aubertin M, Bussière B, Chapuis R, Molson J (2008) Stochastic numerical simulations of long term unsaturated flow in waste rock piles. In: Proceedings of GeoEdmonton 2008:61st

  • Fala O, Molson J, Aubertin M, Dawood I, Bussière B, Chapuis R (2013) A numerical modelling approach to assess long-term unsaturated flow and geochemical transport in a waste rock pile. Int J Min Reclam Environ 27:38–55

    Google Scholar 

  • Fetter CW (2018) Applied hydrogeology. Waveland Press

  • Franks DM, Boger DV, Côte CM, Mulligan DR (2011) Sustainable development principles for the disposal of mining and mineral processing wastes. Resour Policy 36:114–122

    Google Scholar 

  • Hageman PL, Seal RR, Diehl SF, Piatak NM, Lowers HA (2015) Evaluation of selected static methods used to estimate element mobility, acid-generating and acid-neutralizing potentials associated with geologically diverse mining wastes. Appl Geochem 57:125–139

    Google Scholar 

  • Hakkou R, Benzaazoua M, Bussière B (2008) Acid mine drainage at the abandoned Kettara mine (Morocco): 1. Environmental characterization. Mine Water Environ 27:145–159

    Google Scholar 

  • Hammarstrom J, Seal Ii R, Meier A, Kornfeld J (2005) Secondary sulfate minerals associated with acid drainage in the eastern US: recycling of metals and acidity in surficial environments. Chem Geol 215:407–431

    Google Scholar 

  • Hou D, O’Connor D, Nathanail P, Tian L, Ma Y (2017) Integrated GIS and multivariate statistical analysis for regional scale assessment of heavy metal soil contamination: a critical review. Environ Pollut 231:1188–1200

    Google Scholar 

  • Kohfahl C, Graupner T, Fetzer C, Pekdeger A (2010) The impact of cemented layers and hardpans on oxygen diffusivity in mining waste heaps A field study of the Halsbrücke lead–zinc mine tailings (Germany). Sci Total Environ 408:5932–5939

    Google Scholar 

  • Lefebvre R, Hockley D, Smolensky J, Lamontagne A (2001) Multiphase transfer processes in waste rock piles producing acid mine drainage: 2. Applications of numerical simulation. J Contam Hydrol 52:165–186

    Google Scholar 

  • Lehner S, Savage K, Ciobanu M, Cliffel DE (2007) The effect of As Co, and Ni impurities on pyrite oxidation kinetics: an electrochemical study of synthetic pyrite. Geochim Cosmochim Acta 71:2491–2509

    Google Scholar 

  • Lin Z, Herbert RB Jr (1997) Heavy metal retention in secondary precipitates from a mine rock dump and underlying soil, Dalarna, Sweden. Environ Geol 33:1–12

    Google Scholar 

  • Lindsay MB, Condon PD, Jambor JL, Lear KG, Blowes DW, Ptacek CJ (2009) Mineralogical, geochemical, and microbial investigation of a sulfide-rich tailings deposit characterized by neutral drainage. Appl Geochem 24:2212–2221

    Google Scholar 

  • Lupankwa K, Love D, Mapani B, Mseka S, Meck M (2006) Influence of the Trojan Nickel Mine on surface water quality, Mazowe valley, Zimbabwe: runoff chemistry and acid generation potential of waste rock. Phys Chem Earth Parts A/B/C 31:789–796

    Google Scholar 

  • Marescotti P, Carbone C, De Capitani L, Grieco G, Lucchetti G, Servida D (2008) Mineralogical and geochemical characterisation of open-air tailing and waste-rock dumps from the Libiola Fe–Cu sulphide mine (Eastern Liguria, Italy). Environ Geol 53:1613–1626

    Google Scholar 

  • Molson J, Fala O, Aubertin M, Bussière B (2005) Numerical simulations of pyrite oxidation and acid mine drainage in unsaturated waste rock piles. J Contam Hydrol 78:343–371

    Google Scholar 

  • Moore F, Dehghani S, Keshavarzi B (2014) Characterization of soil contamination in Miduk mining district, SW Iran. Soil Sediment Contam 23:614–627

    Google Scholar 

  • Nichol C, Smith L, Beckie R (2005) Field-scale experiments of unsaturated flow and solute transport in a heterogeneous porous medium. Water Resour Res. https://doi.org/10.1029/2004wr003035

    Article  Google Scholar 

  • Nicholson RR, Shaw S, Barabash S, Lundagan J (2018) Evaluation of acid rock drainage potential in a retrospective study 25 years after mine closure: acid base accounting statistics are not sufficient

  • Nieber JL, Bauters T, Steenhuis T, Parlange J-Y (2000) Numerical simulation of experimental gravity-driven unstable flow in water repellent sand. J Hydrol 231:295–307

    Google Scholar 

  • Noble TL, Lottermoser BG, Parbhakar-Fox A (2016) Evaluation of pH testing methods for sulfidic mine waste. Mine Water Environ 35:318–331

    Google Scholar 

  • Nordstrom DK, Blowes DW, Ptacek CJ (2015) Hydrogeochemistry and microbiology of mine drainage: an update. Appl Geochem 57:3–16

    Google Scholar 

  • Odong J (2007) Evaluation of empirical formulae for determination of hydraulic conductivity based on grain-size analysis. J Am Sci 3:54–60

    Google Scholar 

  • Parbhakar-Fox A, Fox N, Hill R, Ferguson T, Maynard B (2018) Improved mine waste characterisation through static blended test work. Miner Eng 116:132–142

    Google Scholar 

  • Parkhurst DL, Appelo C (2013) Description of input and examples for PHREEQC version 3: a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. US Geological Survey

  • Pereira HG, Renca S, Saraiva J (2003) A case study on geochemical anomaly identification through principal components analysis supplementary projection. Appl Geochem 18:37–44

    Google Scholar 

  • Price WA (2009) Prediction manual for drainage chemistry from sulphidic geologic materials. CANMET Mining and Mineral Sciences Laboratories, Canada

    Google Scholar 

  • Remy N, Boucher A, Wu J (2009) Applied geostatistics with SGeMS: a user’s guide. Cambridge University Press, Cambridge

    Google Scholar 

  • Richards JP, Sholeh A (2016) The Tethyan tectonic history and Cu-Au metallogeny of Iran. Tectonics and Metallogeny of the Tethyan Orogenic Belt Society of Economic Geologists, Special Publication 19:193–212

    Google Scholar 

  • Romero F, Armienta M, González-Hernández G (2007) Solid-phase control on the mobility of potentially toxic elements in an abandoned lead/zinc mine tailings impoundment, Taxco, Mexico. Appl Geochem 22:109–127

    Google Scholar 

  • Roussel C, Néel C, Bril H (2000) Minerals controlling arsenic and lead solubility in an abandoned gold mine tailings. Sci Total Environ 263:209–219

    Google Scholar 

  • Servida D, Comero S, Dal Santo M, de Capitani L, Grieco G, Marescotti P, Porro S, Forray FL, Gál A, Szakács A (2013) Waste rock dump investigation at Roşia Montană gold mine (Romania): a geostatistical approach. Environ Earth Sci 70:13–31

    Google Scholar 

  • Shahhoseiny M, Ardejani FD, Shafaei SZ, Noaparast M, Hamidi D (2013) Geochemical and mineralogical characterization of a pyritic waste pile at the Anjir Tangeh coal washing plant, Zirab, Northern Iran. Mine Water Environ 32:84–96

    Google Scholar 

  • Shahhosseini M, Ardejani FD, Baafi E (2017) Geochemistry of rare earth elements in a neutral mine drainage environment, Anjir Tangeh, northern Iran. Int J Coal Geol 183:120–135

    Google Scholar 

  • Shahhosseini M, Ardejani FD, Amini M, Ebrahimi L, Poorkani AM (2019) Environmental geochemistry of As and Pb in a copper low-grade dump, Miduk copper mine, Kerman province, SE Iran. J Geochem Explor 198:54–70

    Google Scholar 

  • Smart R, Skinner W, Levay G, Gerson A, Thomas J, Sobieraj H, Schumann R, Weisener C, Weber P, Miller S (2002) ARD test handbook: project P387A, prediction and kinetic control of acid mine drainage. AMIRA, International Ltd, Ian Wark Research Institute, Melbourne

    Google Scholar 

  • Smith LJ, Blowes DW, Jambor JL, Smith L, Sego DC, Neuner M (2013) The Diavik Waste Rock Project: particle size distribution and sulfur characteristics of low-sulfide waste rock. Appl Geochem 36:200–209

    Google Scholar 

  • Smuda J, Dold B, Friese K, Morgenstern P, Glaesser W (2007) Mineralogical and geochemical study of element mobility at the sulfide-rich Excelsior waste rock dump from the polymetallic Zn–Pb–(Ag–Bi–Cu) deposit, Cerro de Pasco, Peru. J Geochem Explor 92:97–110

    Google Scholar 

  • Soregaroli BA, Lawrence RW (1997) Waste rock characterization at Dublin Gulch: a case study. In: Proceedings of the 4th international conference on acid rock drainage, Vancouver, pp 631–645

  • SPSS (2013) IBM SPSS statistics 22

  • Stockwell J, Smith L, Jambor JL, Beckie R (2006) The relationship between fluid flow and mineral weathering in heterogeneous unsaturated porous media: a physical and geochemical characterization of a waste-rock pile. Appl Geochem 21:1347–1361

    Google Scholar 

  • Strömberg B, Banwart SA (1999) Experimental study of acidity-consuming processes in mining waste rock: some influences of mineralogy and particle size. Appl Geochem 14:1–16

    Google Scholar 

  • Stumbea D (2013) Preliminaries on pollution risk factors related to mining and ore processing in the Cu-rich pollymetallic belt of Eastern Carpathians, Romania. Environ Sci Pollut Res 20:7643–7655

    Google Scholar 

  • Stumbea D, Chicoș MM, Nica V (2019) Effects of waste deposit geometry on the mineralogical and geochemical composition of mine tailings. J Hazard Mater 368:496–505

    Google Scholar 

  • Swanson D, Savci G, Danziger G, Mohr R, Weiskopf T (1999) Predicting the soil-water characteristics of mine soils. Tailings and Mine Waste, pp 345–349

  • Taghipour N, Aftabi A, Mathur R (2008) Geology and Re-Os geochronology of mineralization of the Miduk porphyry copper deposit, Iran. Resour Geol 58:143–160

    Google Scholar 

  • Tangestani M, Moore F (2002) Porphyry copper alteration mapping at the Meiduk area, Iran. Int J Remote Sens 23:4815–4825

    Google Scholar 

  • Vriens B, Peterson H, Laurenzi L, Smith L, Aranda C, Mayer KU, Beckie RD (2019) Long-term monitoring of waste-rock weathering at the Antamina mine, Peru. Chemosphere 215:858–869

    Google Scholar 

  • Webster R, Oliver MA (2007) Geostatistics for environmental scientists. Wiley, New York

    Google Scholar 

  • Wesley LD (2010) Fundamentals of soil mechanics for sedimentary and residual soils. Wiley, New York

    Google Scholar 

  • Yazdani J, Barbour L, Wilson W (2000) Soil water characteristic curve for mine waste rock containing coarse material. Proc of the CSCE Annual Conf, London, pp 198–202

    Google Scholar 

  • Yousefi S, Ardejani FD, Ziaii M, Abedi A, Zadeh EE (2015) Investigating the origin and geochemical behaviour of toxic elements within the waste dumps using statistical analyses: a case study at waste dumps of Sarcheshmeh copper mine, SE of Iran. Environ Earth Sci 73:1555–1572

    Google Scholar 

  • Yucel DS, Baba A (2016) Prediction of acid mine drainage generation potential of various lithologies using static tests: Etili coal mine (NW Turkey) as a case study. Environ Monit Assess 188:473. https://doi.org/10.1007/s10661-016-5462-5

    Article  Google Scholar 

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Acknowledgements

This study was benefited by the financial support of National Iranian Copper Industries Company (NICICO), Kerman branch, Iran. The authors would like to acknowledge the continuous support of the School of Mining, College of Engineering, University of Tehran, Tehran, Iran. The research was conducted under the encouragement of Mine Environment and Hydrogeology Research Laboratory (MEHR Lab.), School of Mining, College of Engineering, University of Tehran, Tehran, Iran.

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Correspondence to Faramarz Doulati Ardejani.

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Shahhosseini, M., Doulati Ardejani, F., Amini, M. et al. The spatial assessment of acid mine drainage potential within a low-grade ore dump: the role of preferential flow paths. Environ Earth Sci 79, 28 (2020). https://doi.org/10.1007/s12665-019-8782-2

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