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Groundwater appraisal of Dhekiajuli, Assam, India: an insight of agricultural suitability and arsenic enrichment

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Abstract

The present work is an effort to develop an appraisal of the hydrogeochemical regime for the aquifers of Dhekiajuli, Sonitpur district, Assam, which is imperative considering: (i) excessive use of groundwater for irrigation; (ii) reported high arsenic (As) contamination; (iii) application of fertilizer is an inevitable process undergoing in this region to achieve higher yield owing to deteriorating water quality; and (iv) study area being the location of many tea estates of Assam, that export tea in many foreign countries. The highest As concentration of 44.39 µg/L was detected in this study (Bachasimalu and Sitalmari region), implying high As-contaminated aquifers being used for drinking and irrigation purposes in the area. The relative abundance pattern of major cations and anions was in the order of Na+ > Mg2+ > Ca2+ > K+ and HCO3 − > Cl− > SO4 2−, respectively. Majority of the samples belong to Na+–K+–Cl−–HCO3 − and mixed water type. Closer inspection of Piper plot reveals that a higher As value (>40 µg/L) was prevalent in HCO3 − water type. Results of hydrogeochemical plots suggest silicate and carbonate weathering, ion exchange and anthropogenic activities to be the dominant processes governing groundwater contamination, including As which is further supported from PCA loadings. The Singri area to the east of the affected areas and adjacent to the Brahmaputra River has oxic aquifers owing to the absence of mass deposition of younger sediments, while reducing conditions prevails in the Bachasimalu and Sitalmari region. High positive correlation between As and Fe (r = 0.83**) and a negative correlation between ORP and Fe (r = −0.68**) further add that Fe (hydr)oxides are the direct source of As release in the affected region, the mechanism being reductive hydrolysis of such (hydr)oxides. The study implies that although groundwater is suitable for irrigation use, there is a high probability of As getting into the food chain through tea and other edible plants irrigated with As-contaminated water; thus, the area has a maximum probability of facing health hazards caused by As-contaminated groundwater.

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References

  • Ahmed KM, Bhattacharya P, Hasan MA, Akhter SH, Alam SMM, Bhuyian MAH, Imam MB, Khan AA, Sracek O (2004) Arsenic enrichment in groundwater of the alluvial aquifers in Bangladesh: an overview. Appl Geochem 19(2):181–200

    Article  Google Scholar 

  • APHA American Public Health Association (1995) Standard method for the examination of water and waste water, 19th edn. In: Eaton AD, Clesceri LS, Greenberg AE (eds) American Public Health Association, Washington, USA

  • Back W, Hanshaw BB (1965) Chemical geohydrology. In: Chow VT (ed) Advances in hydroscience, vol 2. Academic Press, New York, pp 49–109

  • Ben DS, Berner Z, Chandrasekharam D, Karmakar J (2003) Arsenic enrichment in groundwater of West Bengal, India: geochemical evidence for mobilization of As under reducing conditions. Appl Geochem 18:1417–1434

    Article  Google Scholar 

  • Bhattacharyya R, Jana J, Nath B, Sahu S, Chatterjee D, Jacks G (2003) Groundwater arsenic mobilization in the Bengal Delta Plain, the use of ferralite as a possible remedial measure—a case study. Appl Geochem 18(9):1435–1451

    Article  Google Scholar 

  • Bibi MH, Ahmed F, Ishiga H (2008) Geochemical study of arsenic concentrations in groundwater of the Meghna River Delta, Bangladesh. J Geochem Explor 97(2–3):43–58

    Article  Google Scholar 

  • Bundschuh J, Bonorino G, Viero AP, Albouy R, Fuertes A (2000) Arsenic and other trace elements in sedimentary aquifers in the Chaco-Pampean Plain, Argentina: origin, distribution, speciation, social and economic consequences. In: Arsenic in groundwater of sedimentary aquifers, 31st international geological congress, Rio de Janeiro, pp 27–32

  • Bundschuh J, Farias B, Martin R, Storniolo A, Bhattacharya P, Cortes J, Bonorino G, Alboury R (2004) Groundwater arsenic in the Chaco-Pampean Plain, Argentina: case study from Robles County, Santiago del Estero Province. Appl Geochem 19(2):231–243

    Article  Google Scholar 

  • Carbonell-Barrachina AA, Burlo F, Valero D, Lopez E, Martinez-Romero D, Martinez-Sanchez F (1999) Arsenic toxicity and accumulation in turnip as affected by arsenic chemical speciation. J Agric Food Chem 47(6):2288–2294

    Article  Google Scholar 

  • Chakraborti D, Mukherjee SC, Pati S, Sengupta MK, Rahman MM, Chowdhury UK, Chowdhury UK, Lodh D, Chanda CR, Chakraborti AK, Basu GK (2003) Arsenic groundwater contamination in middle Ganga Plain, Bihar, India: a future danger? Environ Health Perspect 111(9):1194–1201

    Article  Google Scholar 

  • Das N, Patel AK, Deka G, Das A, Sarma KP, Kumar M (2015) Geochemical controls and future perspective of arsenic mobilization for sustainable groundwater management: a study from Northeast India. Groundw Sustain Dev 1:92–104

    Article  Google Scholar 

  • Das N, Sarma KP, Patel AK, Deka JP, Das A, Kumar A, Shea PJ, Kumar M (2017) Seasonal disparity in the co-occurrence of arsenic and fluoride in the aquifers of the Brahmaputra flood plains, Northeast India. Environ Earth Sci 76:183

    Article  Google Scholar 

  • Fisher RS, Mulican WF (1997) Hydrochemical evolution of sodium–sulphate and sodium–chloride groundwater beneath the Northern Chihuahuan Desert, Trans-Pecos, Texas, USA. Hydrogeol J 5(2):4–16

    Article  Google Scholar 

  • Gibbs RJ (1970) Mechanism controlling world water chemistry. Science 170:1088–1090

    Article  Google Scholar 

  • Ground Water Information Booklet Sonitpur District (2013) Assam technical report series: D Central Ground Water Board North Eastern Region Ministry of Water Resources, Guwahati

  • Han WY, Shi YZ, Ma LF, Ruan JY (2005) Arsenic, cadmium, chromium, cobalt and copper in different types of Chinese tea. Bull Environ Contam Toxicol 75(2):272–277

    Article  Google Scholar 

  • Jankowski J, Acworth RI (1997) Impact of debris flow deposits on hydrogeochemical processes and the development of dry land salinity in the Yass River catchment, New South Wales, Australia. Hydrogeol J 5(4):71–88

    Article  Google Scholar 

  • Jha A, Mann RS, Balachandran R (1996) Tea: a refreshing beverage. Indian Food Ind 15:22–29

    Google Scholar 

  • Kannamkumarath SS, Wrobel K, Wrobel K, Caruso JA (2004) Speciation of arsenic in different types of nuts by ion chromatography—inductively coupled plasma mass spectrometry. J Agric Food Chem 52(6):1458–1463

    Article  Google Scholar 

  • Kim SH, Kim K, Ko KS, Kim Y, Lee KS (2012) Co-contamination of arsenic and fluoride in the groundwater of unconsolidated aquifers under reducing environments. Chemosphere 87:851–856

    Article  Google Scholar 

  • Kumar M, Ramanathan AL, Rao MS, Kumar B (2006) Identification and evaluation of hydrogeochemical processes in the groundwater environment of Delhi, India. Environ Geol 50:1025–1039

    Article  Google Scholar 

  • Kumar M, Kumari K, Ramanathan AL, Saxena R (2007) A comparative evaluation of groundwater suitability for irrigation and drinking purposes in two intensively cultivated districts of Punjab, India. Environ Geol 53(3):553–574

    Article  Google Scholar 

  • Kumar M, Kumar P, Ramanathan AL, Bhattacharya P, Thunvik R, Singh UK, Tsujimura M, Sracek O (2010a) Arsenic enrichment in groundwater in the middle Gangetic Plain of Ghazipur District in Uttar Pradesh, India. J Geochem Explor 105:83–94

    Article  Google Scholar 

  • Kumar P, Kumar M, Ramanathan AL, Tsujimura M (2010b) Tracing the factors responsible for arsenic enrichment in groundwater of the middle Gangetic Plain, India: a source identification perspective. Environ Geochem Health 32:129–146

    Article  Google Scholar 

  • Kumar M, Das N, Goswami R, Sarma KP, Bhattacharya P, Ramanathan AL (2016) Coupling fractionation and batch desorption to understand arsenic and fluoride co-contamination in the aquifer system. Chemosphere 164:657–667

    Article  Google Scholar 

  • Lin D, Zhu L (2004) Polycyclic aromatic hydrocarbons: pollution and source analysis of a black tea. J Agric Food Chem 52(26):8268–8271

    Article  Google Scholar 

  • Mayo AL, Loucks MD (1995) Solute and isotopic geochemistry and groundwater flow in the Central Wasatch Range, Utah. J Hydrol 172(1–4):31–59

    Article  Google Scholar 

  • McArthur JM, Ravenscroft P, Safiullah S, Thirlwall MF (2001) Arsenic in groundwater: testing pollution mechanisms for sedimentary aquifers in Bangladesh. Water Resour Res 37(1):109–117

    Article  Google Scholar 

  • McArthur JM, Banerjee DM, Hudson-Edwards KA, Mishra R, Purohit R, Ravenscroft P, Cronin A, Howarth RJ, Chatterjee A, Talukder T, Lowry D, Houghton S, Chadha DK (2004) Natural organic matter in sedimentary basins and its relation to arsenic in anoxic ground water: the example of West Bengal and its worldwide implications. Appl Geochem 19(8):1255–1293

    Article  Google Scholar 

  • Meybeck M (1987) Global chemical weathering of surficial rocks estimated from river dissolved loads. Am J Sci 287:401–428

    Article  Google Scholar 

  • Nickson RT, McArthur JM, Burgess WG, Ahmed KM, Ravenscroft P, Rahman M (1998) Arsenic poisoning of Bangladesh groundwater. Nature 395:33

    Article  Google Scholar 

  • Nickson RT, McArthur JM, Ravenscroft P, Burgess WG, Ahmed KM (2000) Mechanism of arsenic release to groundwater, Bangladesh and West Bengal. Appl Geochem 15(4):403–413

    Article  Google Scholar 

  • Paliwal KV (1972) Irrigation with saline water. Monogram no. 2 (new series). IARI, New Delhi, p 198

    Google Scholar 

  • Pedersen GA, Mortensen GK, Larsen EH (1994) Beverages as a source of toxic trace element intake. Food Addit Contam 11(3):351–363

    Article  Google Scholar 

  • Piper AM (1944) A graphic procedure in the geochemical interpretation of water analysis. Trans Am Geophys Union 25:914–923

    Article  Google Scholar 

  • Reddy AGS, Reddy DV, Rao PN, Prasad KM (2010) Hydrogeochemical characterization of fluoride rich groundwater of Wailpalli watershed, Nalgonda District, Andhra Pradesh, India. Environ Monit Assess 171(1–4):561–577

    Article  Google Scholar 

  • Richards LA (1954) Diagnosis and improvement of saline and alkaline soils. USSL, Handbook no. 60, USDA, Washington, DC

  • Sarin MM, Krishnaswami S, Dilli K, Somayajulu BLK, Moore WS (1989) Major ion chemistry of the Ganga–Brahmaputra river system: weathering processes and fluxes to the Bay of Bengal. Geochim Cosmochim Acta 53(5):997–1009

    Article  Google Scholar 

  • Sawyer GN, McCartly DL (1967) Chemistry of sanitary engineers, 2nd edn. McGraw-Hill, New York, p 518

    Google Scholar 

  • Shah BA (2010) Arsenic contaminated groundwater in Holocene sediments from parts of Middle Ganga Plain, Uttar Pradesh. Curr Sci 98:1359–1365

    Google Scholar 

  • Singh H (1983) Crop production in India. Agric Situat India 38(9):635–639

    Google Scholar 

  • Singh AK (2004) Arsenic contamination in groundwater of North Eastern India. In: Proceeding of 11th national symposium on hydrology with focal theme on water quality. National Institute of Hydrology, Roorkee, pp 255–262

  • Smedley PL, Kinniburgh DG (2002) A review of the source, behaviour and distribution of arsenic in natural waters. Appl Geochem 17(5):517–568

    Article  Google Scholar 

  • Smedley PL, Nicolli HB, Macdonald DMJ, Barros AJ, Tullio JO (2002) Hydrogeochemistry of arsenic and other inorganic constituents in groundwaters from La Pampa, Argentina. Appl Geochem 17(3):259–284

    Article  Google Scholar 

  • Smedley PL, Zhang M, Zhang G, Luo Z (2003) Mobilisation of arsenic and other trace elements in fluviolacustrine aquifers of the Huhhot basin, Inner Mongolia. Appl Geochem 18:1453–1477

    Article  Google Scholar 

  • Soltan ME (1998) Characterisation, classification, and evaluation of some groundwater samples in Upper Egypt. Chemosphere 37:735–745

    Article  Google Scholar 

  • Stallard RF, Edmond JM (1983) Geochemistry of the Amazon 2: the influence of geology and weathering environment on the dissolved load. J Geophys Res 88:9671–9688

    Article  Google Scholar 

  • Todd DK (1959) Groundwater hydrology. Wiley, Hoboken, p 336

    Google Scholar 

  • Tokalioglu S, Kartal S (2004) Bioavailability of soil-extractable metals to tea plant by BCR sequential extraction procedure. Instrum Sci Technol 32(4):387–400

    Article  Google Scholar 

  • Wilcox LV (1995) Classification and use of irrigation waters. USDA, Circular 969, Washington, DC

    Google Scholar 

  • Williams PN, Price AH, Raab A, Hossain SA, Feldmann J, Meharg AA (2005) Variation in arsenic speciation and concentration in paddy rice related to dietary exposure. Environ Sci Technol 39(15):5531–5540

    Article  Google Scholar 

  • World Health Organization (WHO) (2008) Guidelines for drinking-water quality, incorporating 1st and 2nd addenda Geneva, Recommendations 3rd edn, vol 1. http://www.who.int/water_sanitation_health/dwq/fulltext.pdf. Accessed 12 Feb 2017

  • Zheng Y, Stute M, van Geen A, Gavrieli I, Dhar R, Simpson HJ, Schlosser P, Ahmed KM (2004) Redox control of arsenic mobilization in Bangladesh groundwater. Appl Geochem 19:201–221

    Article  Google Scholar 

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Acknowledgements

The authors would like to thank Sophisticated Analytical Instrumentation Centre (SAIC), Tezpur University, for offering their instrumental support for carrying out arsenic analysis. The research was conducted in the Department of Environmental Science Tezpur University, Napaam, Tezpur 784028, Assam (India).

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  1. Tezpur University, Tezpur, Assam, India

    Latu Khanikar, Rashmi Rekha Gogoi, Nilotpal Das, Jyoti Prakash Deka, Aparna Das, Manish Kumar & K. P. Sarma

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  1. Latu Khanikar
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  2. Rashmi Rekha Gogoi
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Correspondence to K. P. Sarma.

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Khanikar, L., Gogoi, R.R., Das, N. et al. Groundwater appraisal of Dhekiajuli, Assam, India: an insight of agricultural suitability and arsenic enrichment. Environ Earth Sci 76, 530 (2017). https://doi.org/10.1007/s12665-017-6841-0

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