Abstract
The hydrochemistry of groundwater from the Mogher Al Mer area, located in southwestern Syria, has been used as a tool to identify and assess the hydrogeological systems and associated conditions. In this arid region of Syria, groundwater is considered as the main source of water supply for both drinking and irrigation purposes. The detailed description of hydrogeochemical conditions, including major ions, physico-chemical and in situ field parameters, has underlined the very complex variability of the stratigraphic sequences and hence the numerous hydrogeological units within the study area. On the one hand, groundwater chemical signature is found to be mainly controlled by the water–rock interaction processes in the mountainous western part of the study area. On the other hand, anthropogenic influences are observed in the eastern plain. In terms of recharge mechanisms, the region can be considered as a part of a main intermediate or even regional flow system instead of a local one.
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References
Aghazadeh N, Mogaddam AA (2011) Investigation of hydrochemical characteristics of groundwater in the Harzandat aquifer, Northwest of Iran. Environ Monit Assess 176:183–195
Al-Charideh A (2011) Environmental isotope study of groundwater discharge from the large karst springs in West Syria: a case study of Figeh and Al-sin springs. Environ Earth Sci 63:1–10
Al-Charideh A (2012a) Geochemical and isotopic characterization of groundwater from shallow and deep limestone aquifers system of Aleppo basin (north Syria). Environ Earth Sci 65:1157–1168
Al-Charideh A (2012b) Recharge rate estimation in the Mountain karst aquifer system of Figeh spring, Syria. Environ Earth Sci 65:1169–1178
Al-Charideh A, Abou-Zakhem B (2009) Geochemical and isotopic characterization of groundwater from the Paleogene limestone aquifer of the Upper Jezireh, Syria. Environ Earth Sci 59:1065–1078
Anastasiadis P (2003) Vulnerability of groundwater to agricultural activities Pollution. In: Proceedings of the 8th international conference on environmental science and technology, Lemnos Island, Greece, 8–10 September Full paper, vol B, pp 24–30
Angelakis AN (2000) Water resources management in SAR, with emphasis on non-conventional sources. FAO RNE, Egypt
Appelo CAJ, Postma D (1993) Geochemistry, groundwater and pollution. A.A. Balkema, Rotterdam
Appelo CAJ, Postma D (2005) Geochemistry, groundwater and pollution, 2nd edn. Taylor & Francis, Amsterdam
Barbieri P, Adami G, Favretto A, Lutman A, Avoscan W, Reisenhofer E (2001) Robust cluster analysis for detecting physicochemical typologies of freshwater from wells of the plain of Friuli (north-eastern Italy). Anal Chim Acta 440:161–170
Barbieri M, Boschetti T, Petitta M, Tallini M (2005) Stable isotope (2H, 18O and 87Sr/86Sr) and hydrochemistry monitoring for groundwater hydrodynamics analysis in a karst aquifer (Gran Sasso, Central Italy). Appl Geochem 20:2063–2081
Batiot C, Emblanch C, Blavoux B (2003) Carbone organique total (COT) et magnésium (Mg+2): deux traceurs complémentaires du temps de séjour dans l’aquifère karstique Total Organic Carbon (TOC) and magnesium (Mg+2): two complementary tracers of residence time in karstic systems. CR Geosci 335(2):205–214
Bicalho CC, Batiot-Guilhe C, Seidel JL, Exter SV, Jourde H (2012) Geochemical evidence of water source characterization and hydrodynamic responses in a karst aquifer. J Hydrol 450–451:206–218
Burdon DJ, Safadi C (1964) The karst groundwater of Syria. J Hydrol 2:324–347
Capaccioni B, Didero M, Paletta C, Salvadori P (2001) Hydrochemistry of groundwater from carbonate formation with basal gypsiferous layers. J Hydrol 253:14–26
Deutsch WJ (1997) Groundwater geochemistry: fundamentals and application to contamination. CRC Press, Boca Raton
Domenico PA, Schwartz FW (1990) Physical and chemical hydrogeology. Wiley, New York, p 824
Drever JI (1988) The geochemistry of natural waters. Prentice-Hall, Upper Saddle River
Dubertret L (1932) L’Hydrologie et aperçu sur l’Hydrographie de la Syrie et du Liban dans leurs relations avec la géologie. Rev Géogr Phys Géol Dynamique, TVI fas.4
Edmunds WM, Smedley PL (2000) Residence time indicators in groundwater: the East Midlands Triassic sandstone aquifer. Appl Geochem 15(6):737–752
Edmunds WM, Ma JZ, Aeschbach-Hertig W, Kipfer R, Darbyshire DPF (2006) Groundwater recharge history and hydrogeochemical evolution in the Minqin Basin, North West China. Appl Geochem 21:2148–2170
European Commission (1995) COST Action 65: hydrogeological aspects of groundwater protection in karstic areas. Final report. EUR 16457, Brussels
Fairchild IJ, Borsato A, Tooth AF, Frisia S, Hawkesworth CJ, Huang Y, McDermott F, Spiro B (2000) Controls on trace element (Sr-Mg) compositions of carbonate cave waters: implications for speleothem climatic records. Chem Geol 166(3–4):255–269
FAO (1993) Integrated rural water management. In: Proceedings of the technical consultation on integrated water management, Rome, Italy
Flakova R (1998) Formation and changes of groundwater chemical composition of the Western Carpathian carbonate systems. ACTA Geologica Universitatis Comenianae Nr. 53. Bratislava, Slovakia, pp 5–25
Folch A, Mencio A, Puig R, Soler A, Mas-Pla J (2011) Groundwater development effects on different scale hydrogeological systems using head, hydrochemical and isotopic data and implications for water resources management: the Selva basin (NE Spain). J Hydrol 403:83–102
Freeze RA, Cherry JA (1979) Groundwater. Prentice-Hall, Englewood Cliffs
Guendouz A, Moulla AS, Edmunds WM, Zouari K, Shand P, Mamou A (2003) Hydrogeochemical and isotopic evolution of water in the Complexe Terminal aquifer in the Algerian Sahara. Hydrogeol J 11:483–495
Guler C, Thyne GD (2004a) Delineation of hydrochemical facies distribution in a regional groundwater system by means of fuzzy c-means clustering. Water Resour Res 40:1–11
Guler C, Thyne GD (2004b) Hydrologic and geologic factors controlling surface and groundwater chemistry in Indian Wells-Owens Valley area, southeastern California, USA. J Hydrol 285:177–198
Guler C, Thyne GD, McCray JE, Turner KA (2002) Evaluation of graphical and multivariate statistical methods for classification of water chemistry data. Hydrogeology J10:455–474
Han G, Liu C (2004) Water geochemistry controlled by carbonate dissolution: a study of the river waters draining karst-dominated terrain, Guizhou Province, China. Chem Geol 204:1–21
Hem JD (1985) Study and interpretation of the chemical characteristics of natural water, 3rd edn. U.S. Geological Survey, Water Supply Paper 2254
Hsu KJ (1963) Solubility of dolomite and the composition of Florida groundwaters. J Hydrol 1:288–310
Huneau F, Dakoure D, Celle-Jeanton H, Vitvar T, Ito M, Compaore NF, Traore S, Jirakova H, Le Coustumer P (2011) Flow pattern and residence time of groundwater within the south-eastern Taoudeni sedimentary basin (Burkina Faso, Mali). J Hydrol 409:423–439
INECO Studies and Integration Consulting (2009) Institutional framework and decision-making practices for water management in Syria. Towards the development of strategy for water pollution prevention and control in the Barada River Basin, Greater Damascus area. Contract No: INCO‐CT‐2006‐517673
Jianhua S, Qi F, Xiaohu W, Yonghong S, Haiyang X, Zongqiang C (2009) Major ion chemistry of groundwater in the extreme arid region northwest China. Environ Geol 57:1079–1087
JICA (2001) The study of water resources development in the western and central basins in Syrian Arab Republic, phase I, Ministry of Irrigation (MOI) (in Arabic) (unpublished report)
Kattan Z (1997) Environmental isotope study of the major karst springs in Damascus limestone aquifer systems: case of the Figeh and Barada springs. J Hydrol 193:161–182
Kattan Z (2006) Characterization of surface water and groundwater in the Damascus Ghotta basin: hydrochemical and environmental isotopes approaches. Environ Geol 51:173–201
Kortatsi BK (2007) Hydrochemical framework of groundwater in the Ankobra Basin, Ghana. Aquat Geochem 13:41–74
La-Moreaux PE, Hughes TH, Memon BA, Lineback N (1989) Hydrogeologic assessment—Figeh Spring, Damascus, Syria. Environ Geol Water Sci 13(2):73–127
Langmuir D (1971) The geochemistry of some carbonate groundwaters in central Pennsylvania. Geochim Cosmochim Acta 35:1023–1045
Lawrence AR, Gooddy DC, Kanatharana P, Meesilp M, Ramnarong V (2000) Groundwater evolution beneath Hat Yai, a rapidly developing city in Thailand. Hydrogeol J 8:564–575
Li X, Zhang L, Hou X (2008) Use of hydrogeochemistry and environmental isotopes for evaluation of groundwater in Qingshuihe Basin, northwestern China. Hydrogeol J 16:335–348
López-Chicano M, Bouamama M, Vallejos A, Pulido-Bosch A (2001) Factors which determine the hydrogeochemical behaviour of karstic springs. A case study from the Betic Cordilleras, Spain. Appl Geochem 16(9–10):1179–1192
Ma JZ, Edmunds WM (2006) Groundwater and lake evolution in the Badain Jaran desert ecosystem, Inner Mongolia. Hydrogeol J 14:1231–1243
Ma JZ, Wang XS, Edmunds WM (2005) The characteristics of groundwater resources and their changes under the impacts of human activity in the arid Northwest China, a case study of the Shiyang River Basin. J Arid Environ 61:277–295
Mahlknecht J, Gárfias-Solis J, Aravena R, Tesch R (2006) Geochemical and isotopic investigations on groundwater residence time and flow in the Independence Basin, Mexico. J Hydrol 324:283–300
McMahon PB, Böhlke JK, Christenson SC (2004) Geochemistry, radiocarbon ages, and paleorecharge conditions along a transect in the central High Plains aquifer, southwestern Kansas, USA. Appl Geochem 19(11):1655–1686
Meslmani Y, Wardeh M F (2010) Strategy and action plan for adaptation to climate change in Syria, (INC-SY_ Strategy & NAPA-En). Ministry of State for Environment Affairs (MSEA)/United Nations Development Programme (UNDP) Damascus, Syria
MOI (2005) Annual water resources report of Barada and Awaj Basin, Damascus, Syria (in Arabic) (unpublished report)
Moral F, Cruz-Sanjulián JJ, Olías M (2008) Geochemical evolution of groundwater in the carbonate aquifers of Sierra de Segura (Betic Cordillera, southern Spain). J Hydrol 360:281–296
Mourad KA, Berndtsson R (2011) Syrian water resources between the present and the future. Air Soil Water Res 4:93–100. doi:10.4137/ASWR.S8076
Palmer PC, Gannett MW, Stephen R, Hinkle SR (2007) Isotopic characterization of three groundwater recharge sources and inferences for selected aquifers in the upper Klamath Basin of Oregon and California, USA. J Hydrol 336:17–29
Parkhurst DL, Appelo CAJ (1999) PHREEQC for windows version 1.4.07. A hydrogeochemical transport model. U.S. Geological Survey Software
Plummer LN (1977) Defining reactions and mass transfer in part of the Floridan aquifer. Water Resour Res 13(5):801–812
Plummer LN, Wigley TML, Parkhurst DL (1978) The kinetics of calcite dissolution in CO2 water systems at 5–60 °C and 0.0–1.0 atm CO2. Am J Sci 278(2):179–216
Plummer LN, Busby JF, Lee RW, Hanshaw BB (1990) Geochemical modeling of the Madison aquifer in parts of Montana, Wyoming, and south Dakota. Water Resour Res 26(9):1981–2014
Ponikarov VO (1967) The geology of Syria, explanatory notes on the map of Syria, Scale 1:500,000. Part II. Mineral deposits and underground water resources. Technoexport, Moscow
Rakhmatullaev S, Huneau F, Kazbekov J, Le Coustumer P, Jumanov J, El Oifi B, Motelica-Heino M, Hrkal Z (2010) Groundwater resources and management in the Amu Darya River Basin (Central Asia). Environ Earth Sci 59:1183–1193
Rakhmatullaev S, Huneau F, Kazbekov J, Celle-Jeanton H, Motelica-Heino M, Le Coustumer P, Jumanov J (2012) Groundwater resources of Uzbekistan: an environmental and operational overview. Cent Eur J Geosci 4:67–80
RDAWSA (2006) Interim report—hydrogeological study of Mougher El Mer Area, Damascus Rural water and sanitation project
Schoeller H (1956) Géochimie des eaux souterraines. Application aux eaux des gisements de petrole. Soc Ed Technip, Paris
Selkhozpromexport (1986) Water resources use in Barada and Awaj Basins for irrigation of crops, Syria Arab Republic. USSR, Ministry of Land Reclamation and Water Management, Moscow
Stadler S, Geyh MA, Ploethner D, Koeniger P (2012) The deep Cretaceous aquifer in the Aleppo and Steppe basins of Syria: assessment of the meteoric origin and geographic source of the groundwater. Hydrogeol J 20:1007–1026. doi:10.1007/s10040-012-0862-2
Stuyfzand PJ (1989) A new hydrochemical classification of water type. IAHS Red Books 182:89–98
Suk H, Lee K–K (1999) Characterization of a ground water hydrochemical system through multivariate analysis: clustering into groundwater zones. Ground Water 37:358–366
Vengosh A, Rosenthal E (1994) Saline groundwater in Israel: its bearing on the water crisis in the country. J Hydrol 156:389–430
Wen X, Wu Y, Zhang Y, Liu F (2005) Hydrochemical characteristics and salinity of groundwater in the Ejina basin, northwestern China. Environ Geol 48:665–675
Wolfart R (1964) Hydrogeology of the Damascus Basin (southwest-Syria). IAHS Red Books 64:402–413
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Asmael, N.M., Huneau, F., Garel, E. et al. Hydrochemistry to delineate groundwater flow conditions in the Mogher Al Mer area (Damascus Basin, Southwestern Syria). Environ Earth Sci 72, 3205–3225 (2014). https://doi.org/10.1007/s12665-014-3226-5
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DOI: https://doi.org/10.1007/s12665-014-3226-5