Abstract
Electrochemical charge storage of physically and chemically activated carbon synthesized from oil palm kernel shell (PKS) in three different aqueous electrolytes (1 M H2SO4, 1 M Na2SO4 and 6 M KOH) are presented. Coin type CR2032 cells fabricated using the PKS ACs electrodes separated by fiber glass separator and electrolyte are used as devices for measurements. Achievable operating potential for these devices varied as H2SO4 (1.0 V) < KOH (1.2 V) < Na2SO4 (2.0 V). The highest energy density was obtained in Na2SO4 electrolyte (7.4 Wh kg−1) at a power density of 300 W kg−1. The device stability cycle at low current density (0.5 A g−1) for 3500 times showed capacitance retention in range of 78–114% in all devices.
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Simon, P., Gogotsi, Y., Dunn, B.: Where do batteries end and supercapacitors begin? Science 343, 1210–1211 (2014). https://doi.org/10.1126/science.1249625
Arvind, D., Hegde, G.: Activated carbon nanospheres derived from bio-waste materials for supercapacitor applications: a review. RSC Adv. 5, 88339–88352 (2015). https://doi.org/10.1039/C5RA19392C
Jose, R., Krishnan, S.G., Vidyadharan, B., Misnon, I.I., Harilal, M., Aziz, R.A., Ismail, J., Yusoff, M.M.: Supercapacitor electrodes delivering high energy and power densities. Mater. Today Proc. 3, S48–S56 (2016). https://doi.org/10.1016/j.matpr.2016.01.007
Jiang, L., Yan, J., Hao, L., Xue, R., Sun, G., Yi, B.: High rate performance activated carbons prepared from ginkgo shells for electrochemical supercapacitors. Carbon 56, 146–154 (2013). https://doi.org/10.1016/j.carbon.2012.12.085
Wang, R., Wang, P., Yan, X., Lang, J., Peng, C., Xue, Q.: Promising porous carbon derived from celtuce leaves with outstanding supercapacitance and CO2 capture performance. ACS Appl. Mater. Interfaces 4, 5800–5806 (2012). https://doi.org/10.1021/am302077c
Teo, E.Y.L., Muniandy, L., Ng, E.-P., Adam, F., Mohamed, A.R., Jose, R., Chong, K.F.: High surface area activated carbon from rice husk as a high performance supercapacitor electrode. Electrochim. Acta 192, 110–119 (2016). https://doi.org/10.1016/j.electacta.2016.01.140
Elmouwahidi, A., Zapata-Benabithe, Z., Carrasco-Marín, F., Moreno-Castilla, C.: Activated carbons from KOH-activation of argan (Argania spinosa) seed shells as supercapacitor electrodes. Bioresour. Technol. 111, 185–190 (2012). https://doi.org/10.1016/j.biortech.2012.02.010
Arie, A.A., Kristianto, H., Halim, M., Lee, J.K.: Synthesis and modification of activated carbon originated from Indonesian local orange peel for lithium ion capacitor’s cathode. J. Solid State Electrochem. (2016). https://doi.org/10.1007/s10008-016-3445-7
Misnon, I.I., Zain, N.K.M., Aziz, R.A., Vidyadharan, B., Jose, R.: Electrochemical properties of carbon from oil palm kernel shell for high performance supercapacitors. Electrochim. Acta 174, 78–86 (2015). https://doi.org/10.1016/j.electacta.2015.05.163
Lee, S.G., Park, K.H., Shim, W.G., balathanigaimani, M.S., Moon, H.: Performance of electrochemical double layer capacitors using highly porous activated carbons prepared from beer lees. J. Ind. Eng. Chem. 17, 450–454 (2011). https://doi.org/10.1016/j.jiec.2010.10.025
Choi, J., Kim, N.R., Jin, H.-J., Yun, Y.S.: Nanoporous pyropolymer nanosheets fabricated from renewable bio-resources for supercapacitors. J. Ind. Eng. Chem. 43, 158–163 (2016). https://doi.org/10.1016/j.jiec.2016.08.002
Adinaveen, T., Kennedy, L.J., Vijaya, J.J., Sekaran, G.: Studies on structural, morphological, electrical and electrochemical properties of activated carbon prepared from sugarcane bagasse. J. Ind. Eng. Chem. 19, 1470–1476 (2013). https://doi.org/10.1016/j.jiec.2013.01.010
Shrestha, L.K., Adhikari, L., Shrestha, R.G., Adhikari, M.P., Adhikari, R., Hill, J.P., Pradhananga, R.R., Ariga, K.: Nanoporous carbon materials with enhanced supercapacitance performance and non-aromatic chemical sensing with C1/C2 alcohol discrimination. Sci. Technol. Adv. Mater. 17, 483–492 (2016). https://doi.org/10.1080/14686996.2016.1219971
Adhikari, M.P., Adhikari, R., Shrestha, R.G., Rajendran, R., Adhikari, L., Bairi, P., Pradhananga, R.R., Shrestha, L.K., Ariga, K.: Nanoporous activated carbons derived from agro-waste corncob for enhanced electrochemical and sensing performance. Bull. Chem. Soc. Jpn. 88, 1108–1115 (2015). https://doi.org/10.1246/bcsj.20150092
Zhang, J., Gong, L., Sun, K., Jiang, J., Zhang, X.: Preparation of activated carbon from waste Camellia oleifera shell for supercapacitor application. J. Solid State Electrochem. 16, 2179–2186 (2012). https://doi.org/10.1007/s10008-012-1639-1
Lim, W.C., Srinivasakannan, C., Balasubramanian, N.: Activation of palm shells by phosphoric acid impregnation for high yielding activated carbon. J. Anal. Appl. Pyrolysis 88, 181–186 (2010). https://doi.org/10.1016/j.jaap.2010.04.004
Agensi Inovasi Malaysia: National Biomass Strategy 2020: New Wealth Creation for Malaysia’s Biomass Industry. Agensi Inovasi Malaysia, Selangor (2013)
Huang, C.-C., Chen, Y.-Z.: Electrochemical performance of supercapacitors with KOH activated mesophase carbon microbead electrodes. J. Taiwan Inst. Chem. Eng. 44, 611–616 (2013). https://doi.org/10.1016/j.jtice.2012.12.017
Biswal, M., Banerjee, A., Deo, M., Ogale, S.: From dead leaves to high energy density supercapacitors. Energy Environ. Sci. 6, 1249 (2013). https://doi.org/10.1039/c3ee22325f
Zheng, J., Zhao, Q., Ye, Z.: Preparation and characterization of activated carbon fiber (ACF) from cotton woven waste. Appl. Surf. Sci. 299, 86–91 (2014). https://doi.org/10.1016/j.apsusc.2014.01.190
Wu, X.-L., Wen, T., Guo, H.-L., Yang, S., Wang, X., Xu, A.-W.: Biomass-derived sponge-like carbonaceous hydrogels and aerogels for supercapacitors. ACS Nano 7, 3589–3597 (2013). https://doi.org/10.1021/nn400566d
Demarconnay, L., Raymundo-Piñero, E., Béguin, F.: A symmetric carbon/carbon supercapacitor operating at 1.6 V by using a neutral aqueous solution. Electrochem. Commun. 12, 1275–1278 (2010). https://doi.org/10.1016/j.elecom.2010.06.036
Qu, Q.T., Wang, B., Yang, L.C., Shi, Y., Tian, S., Wu, Y.P.: Study on electrochemical performance of activated carbon in aqueous Li2SO4, Na2SO4 and K2SO4 electrolytes. Electrochem. Commun. 10, 1652–1655 (2008). https://doi.org/10.1016/j.elecom.2008.08.020
Zhang, X., Wang, X., Jiang, L., Wu, H., Wu, C., Su, J.: Effect of aqueous electrolytes on the electrochemical behaviors of supercapacitors based on hierarchically porous carbons. J. Power Sources 216, 290–296 (2012). https://doi.org/10.1016/j.jpowsour.2012.05.090
Tansel, B., Sager, J., Rector, T., Garland, J., Strayer, R.F., Levine, L., Roberts, M., Hummerick, M., Bauer, J.: Significance of hydrated radius and hydration shells on ionic permeability during nanofiltration in dead end and cross flow modes. Sep. Purif. Technol. 51, 40–47 (2006). https://doi.org/10.1016/j.seppur.2005.12.020
Tansel, B.: Significance of thermodynamic and physical characteristics on permeation of ions during membrane separation: hydrated radius, hydration free energy and viscous effects. Sep. Purif. Technol. 86, 119–126 (2012). https://doi.org/10.1016/j.seppur.2011.10.033
Xu, C., Wei, C., Li, B., Kang, F., Guan, Z.: Charge storage mechanism of manganese dioxide for capacitor application: effect of the mild electrolytes containing alkaline and alkaline-earth metal cations. J. Power Sources 196, 7854–7859 (2011). https://doi.org/10.1016/j.jpowsour.2011.04.052
Lufrano, F., Staiti, P., Calvo, E.G., Juárez-Pérez, E.J., Menéndez, J.A., Arenillas, A.: Carbon xerogel and manganese oxide capacitive materials for advanced supercapacitors. Int. J. Electrochem. Sci. 6, 596–612 (2011)
Malak-Polaczyk, A., Matei-Ghimbeu, C., Vix-Guterl, C., Frackowiak, E.: Carbon/λ-MnO2 composites for supercapacitor electrodes. J. Solid State Chem. 183, 969–974 (2010). https://doi.org/10.1016/j.jssc.2010.02.015
Chen, X., Wu, K., Gao, B., Xiao, Q., Kong, J., Xiong, Q., Peng, X., Zhang, X., Fu, J.: Three-dimensional activated carbon recycled from rotten potatoes for high-performance supercapacitors. Waste Biomass Valoriz. 7, 551–557 (2015). https://doi.org/10.1007/s12649-015-9458-0
Wu, M., Li, R., He, X., Zhang, H., Sui, W., Tan, M.: Microwave-assisted preparation of peanut shell-based activated carbons and their use in electrochemical capacitors. New Carbon Mater. 30, 86–91 (2015). https://doi.org/10.1016/S1872-5805(15)60178-0
Ma, F., Wan, J., Wu, G., Zhao, H.: Highly porous carbon microflakes derived from catkins for high-performance supercapacitors. RSC Adv. 5, 44416–44422 (2015). https://doi.org/10.1039/C5RA05090A
Ou, Y., Peng, C., Lang, J., Zhu, D., Yan, X.: Hierarchical porous activated carbon produced from spinach leaves as an electrode material for an electric double layer capacitor. New Carbon Mater. 29, 209–215 (2014). https://doi.org/10.1016/S1872-5805(14)60135-9
Liu, B., Zhou, X., Chen, H., Liu, Y., Li, H.: Promising porous carbons derived from lotus seedpods with outstanding supercapacitance performance. Electrochim. Acta 208, 55–63 (2016). https://doi.org/10.1016/j.electacta.2016.05.020
Rufford, T.E., Hulicova-Jurcakova, D., Khosla, K., Zhu, Z., Lu, G.Q.: Microstructure and electrochemical double-layer capacitance of carbon electrodes prepared by zinc chloride activation of sugar cane bagasse. J. Power Sources. 195, 912–918 (2010). https://doi.org/10.1016/j.jpowsour.2009.08.048
Chang, J., Gao, Z., Wang, X., Wu, D., Xu, F., Wang, X., Jiang, K.: Activated porous carbon prepared from paulownia flower for high performance supercapacitor electrodes. Electrochim. Acta. (2015). https://doi.org/10.1016/j.electacta.2014.12.169
Subramanian, V., Luo, C., Stephan, A.M., Nahm, K.S., Thomas, S., Wei, B.: Supercapacitors from activated carbon derived from banana fibers. J. Phys. Chem. C 111, 7527–7531 (2007). https://doi.org/10.1021/jp067009t
Yu, M., Wang, W., Li, C., Zhai, T., Lu, X., Tong, Y.: Scalable self-growth of Ni@NiO core-shell electrode with ultrahigh capacitance and super-long cyclic stability for supercapacitors. NPG Asia Mater. 6, e129 (2014). https://doi.org/10.1038/am.2014.78
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This work was supported by UMP Research Grant (RDU150354) and UMP Pre-Commercialization Fund (UIC 160305).
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Misnon, I.I., Zain, N.K.M. & Jose, R. Conversion of Oil Palm Kernel Shell Biomass to Activated Carbon for Supercapacitor Electrode Application. Waste Biomass Valor 10, 1731–1740 (2019). https://doi.org/10.1007/s12649-018-0196-y
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DOI: https://doi.org/10.1007/s12649-018-0196-y