Skip to main content
SpringerLink
Log in

Abilities of Some Compounds to Stabilize Mahwa Oil from High Temperature Oxidative Degradation for Biolubricant Applications

  • Original Paper
  • Published:
Waste and Biomass Valorization Aims and scope Submit manuscript

Abstract

Low thermo-oxidative stability of Mahwa oil as frying-oil or industrial lubricant is of great concern. It can be improved by the help of suitable antioxidant. The present antioxidants were developed for petroleum products and majority of these are not suitable for vegetable oil. In future, new type of anti-oxidant preferably non-toxic and eco-friendly will be needed to meet new ecological and performance requirements. This paper presents a systematic approach to identify suitable antioxidant for Mahwa oil and its derivatives. Synthesized and procured compounds were evaluated as anti-oxidant to know their effectiveness in Mahwa oil. Rotary bomb oxidation test, universal oxidation test and panel coker test methods were adopted for this study. The thermo-oxidative stability of Mahwa oil was increased significantly by using some eco-friendly additives. The results indicate that N-alkyl piperazine, anisole, benzoate and citrate are very effective at 200 g/l dose.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Kayisoglu, B., Ulger, P., Akdemir, B., Aytac, S.: A research on determining some performance values by using proportional mixture of vegetable oils and diesel fuel at a diesel engine. J. Tekirdag. Agric. Fac. 3, 16–24 (2006)

    Google Scholar 

  2. Ruger, C.W., Klinker, E.J., Hammond, E.G.: Abilities of some antioxidants to stabilize soybean oil in industrial use condition. J. Am. Oil Chem. Soc. 79, 733–736 (2002)

    Article  Google Scholar 

  3. Bringi, N.V.: Non-traditional Oil Seed and Oils of India. Oxford and IBH Publishing Company Pvt. Ltd., New Delhi (1987)

    Google Scholar 

  4. Bhatt, Y.C., Murthy, N.S., Datta, R.K.: Use of mahua oil (Madhuca indica) as a diesel fuel extender. J. Inst. Eng. Agr. Eng. Div. 85, 10–14 (2004)

    Google Scholar 

  5. Aguilar, G., Mazzamaro, G., Rasberger, M.: Oxidative degradation and stabilisation of mineral oil-based lubricants. In: Mortier, R.M., Orszulik, S.T. (eds.) Chemistry and Technology of Lubricants. VCH Publishers, Inc. (Blackie), New York (1992)

    Google Scholar 

  6. Gilks, J.H.: Antioxidants for petroleum products. J. Inst. Petrol. 50, 309–318 (1964)

    Google Scholar 

  7. Spikes, H.: The history and mechanism of ZDDP. Tribol. Lett. 17, 469–489 (2004)

    Article  Google Scholar 

  8. Hamblin, P.C., Kristen, U., Chasan, D.: A review: ashless antioxidants, copper deactivators, and corrosion inhibitors, their use in lubricating oils. Lubr. Sci. 2, 287–318 (1990)

    Article  Google Scholar 

  9. Ullah, J., Hamayoun, M., Ahmad, T., Ayub, M., Zarafullah, M.: Effect of light, natural and synthetic antioxidants on stability of edible oil and fats. Asian J. Plant Sci. 2, 1192–1194 (2003)

    Article  Google Scholar 

  10. Emanuel, N.M., Lyaskovskaya, Y.N.: The Inhibition of Fat Oxidation Processes. Pergamon Press Ltd, Headington Hill Hall, Oxford 4 & 5 Fitzroy Square, London (1967)

    Google Scholar 

  11. Petlyuk, A.M., Adams, R.J.: Oxidation stability and tribological behavior of vegetable oil hydraulic fluids. Tribol. Trans. 47, 182–187 (2004)

    Article  Google Scholar 

  12. Schwetlick, K., Habicher, W.D.: Antioxidant action mechanism of hindered amine stabilizers. Polym. Degrad. Stab. 78, 35–40 (2002)

    Article  Google Scholar 

  13. Aluyor, E.O., Ori-Jesu, M.: The use of antioxidants in vegetable oils—a review. African J. Biotech. 7, 4836–4842 (2008)

    Google Scholar 

  14. Barclay, L.R.C., Edwards, C.E., Vinqvist, M.R.: Media effects of antioxidant activities of phenols and catechols. J. Am. Chem. Soc. 121, 6226–6231 (1999)

    Article  Google Scholar 

  15. Pedrielli, P., Pedulli, G.F., Skibsted, L.H.: Antioxidant activity of (+)-catechin rate constant for hydrogen-atom transfer to peroxyl radicals. J. Agric. Food Chem. 49, 3034–3040 (2001)

    Article  Google Scholar 

  16. Guillena, G., Ramon, D.J., Yus, M.: Hydrogen autotransfer in the N-alkylation of amines and related compounds using alcohols and amines as electrophiles. Chem. Rev. 110, 1611–1641 (2010)

    Article  Google Scholar 

  17. Vora, B.V., Kocal, J.A., Barger, P.T., Schmidt, R.J., Johnson, J.A.: Alkylation in Krik Othmer’s Encyclopedia of Chemical Technology, a Wiley Interscience Publication. Wiley, New York (2003)

    Google Scholar 

  18. Mannich, C., Krosche, W.: Ueber ein kondensationsprodukt aus formaldehyd, ammonak und antipyrin. Arch. Pharm. 250, 647–667 (1912)

    Article  Google Scholar 

  19. ASTM D 2272-11 Standard test method for oxidation stability of steam turbine oils by rotating pressure vessel. In: Annual Book of ASTM Standards, ASTM International: West Conshohocken, PA (2011)

  20. IP 306 Institute of Petroleum testing methods for petroleum, fuel products: High Temperature Universal Oxidation Test Method, Part I. Institute of Petroleum, UK (2004)

    Google Scholar 

  21. Erhan, S.Z., Asadauskas, S.: Lubricant basestock from vegetable oils. Ind. Crops Prod. 11, 277–282 (2000)

    Article  Google Scholar 

  22. Jung, M.Y., Min, D.B.: Effect of oxidized α-, β- and & δ- tocopherols on the oxidative stability of purified soybean oil. J. Food Chem. 45, 183–187 (1992)

    Article  Google Scholar 

  23. Maiza-Benabdesselam, F., Khentache, S., Bougoffa, K., Chibane, M., Adach, S., Chapeleur, Y., Max, H., Laurain-Mattar, D.: Antioxidant activities of alkaloid extracts of two Algerian species of Fumaria: Fumaria capreolate and Fumaria bastardii. Rec. Nat. Prod. 1, 28–35 (2007)

    Google Scholar 

  24. Fox, N.J., Stachowiak, G.W.: Vegetable oil-based lubricants—a review of oxidation. Tribol. Int. 40, 1035–1046 (2007)

    Article  Google Scholar 

  25. Jipa, S., Gorghiu, L.M., Dumitrescu, C., Bumba, M., Olteanu, R.L., Zaharescu, T., Cuthon-Gourves, H.: Antioxidation activity of several diphosphonates in thermooxidative stability of LDPE. J. Optoelectron. Adv. M. 8, 654–658 (2006)

    Google Scholar 

  26. Huq, M.Z., Chen, X., Aswath, P.B., Elsenbaumer, R.L.: Thermal degradation behavior of zinc dialkyldithiophosphate in presence of catalyst and detergents in neutral oil. Tribol. Lett. 19, 127–134 (2005)

    Article  Google Scholar 

Download references

Acknowledgments

The author kindly acknowledges the Director, IIP for his kind permission to publish these results. The author thanks the analytical division of Institute for providing analysis. CSIR, New Delhi is acknowledged for research funding.

Author information

Authors and Affiliations

  1. Chemical Science Division, Indian Institute of Petroleum (CSIR-IIP), Dehradun, 248 005, India

    Raj Kumar Singh & Arun Kumar Singh

Authors
  1. Raj Kumar Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Arun Kumar Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Raj Kumar Singh.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Singh, R.K., Singh, A.K. Abilities of Some Compounds to Stabilize Mahwa Oil from High Temperature Oxidative Degradation for Biolubricant Applications. Waste Biomass Valor 5, 847–855 (2014). https://doi.org/10.1007/s12649-014-9289-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12649-014-9289-4

Keywords

Search

Navigation