Abstract
The role of cadmium sulfide and zinc oxide in the lead-silicate system was studied. Glass compositions: 100 − x (69SiO2–29PbO–2B2O3), x = CdS, ZnO/CdS = 7. By altering the x values in the x = 0, 2, 3, 4 mol% range, the LG-0, LG-2, LG-3 and LG-4 glasses were prepared by the bulk casting method. According to the DTA results, the LG-4 glass has higher glass-forming abilities. The heat treatment between Tg and Td temperatures was selected in the 580–610 °C for nanocrystallization of CdS. FTIR peaks at 500 cm−1 and 1057 cm−1 in all cadmium sulfide-containing samples indicated the formation of zinc–oxygen–cadmium–sulfur nanocomposite bonds. The dual role of zinc oxide in these systems was identified. The FTIR peak in 881 cm−1 corresponded to the bridging oxygen, and the Raman peak in 920 cm−1 related to the nonbridging oxygen was detected in the LG-4 and LG-3 glasses. The blue and redshift of PL peaks were confirmed by increasing the heat treatment temperatures due to the growth of cadmium sulfide–zinc nanocomposite particles and stoichiometric modification in CdS–ZnO nanocomposite in LG-3 and LG-4 glass–ceramics, respectively.
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This study was financially supported by the Materials and Energy Research Center through Grant Number 371398055.
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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by MS. The first draft of the manuscript was written by AF, and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Faeghinia, A., Alizadeh, M. & Siroosian, M. Effect of CdS on optical properties of ZnO–PbO–SiO2 glass–ceramic systems. Indian J Phys 97, 3087–3096 (2023). https://doi.org/10.1007/s12648-023-02642-x
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DOI: https://doi.org/10.1007/s12648-023-02642-x