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Dielectric relaxation and hydrogen bonding interaction in xylitol–water mixtures using time domain reflectometry

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Abstract

The measurements of complex dielectric permittivity of xylitol–water mixtures have been carried out in the frequency range of 10 MHz–30 GHz using a time domain reflectometry technique. Measurements have been done at six temperatures from 0 to 25 °C and at different weight fractions of xylitol (0 < W X  ≤ 0.7) in water. There are different models to explain the dielectric relaxation behaviour of binary mixtures, such as Debye, Cole–Cole or Cole–Davidson model. We have observed that the dielectric relaxation behaviour of binary mixtures of xylitol–water can be well described by Cole–Davidson model having an asymmetric distribution of relaxation times. The dielectric parameters such as static dielectric constant and relaxation time for the mixtures have been evaluated. The molecular interaction between xylitol and water molecules is discussed using the Kirkwood correlation factor (g eff) and thermodynamic parameter.

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Acknowledgments

The financial support from the Department of Science and Technology, New Delhi is gratefully acknowledged (Project No. SR/S2/LOP-25/2007). Author YSJ is also thankful to SERB, DST, New Delhi (Project No. SR/FTP/PS-203/2012). We thank to Prof. S.C. Mehrotra, Department of Computer Science, Dr. B.A.M. University, Aurangabad for fruitful discussion. We are thankful to Dr. G. N. Shinde, Principal, Indira Gandhi College, CIDCO, Nanded for encouragement.

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Authors and Affiliations

  1. Department of Physics, Lal Bahadur Shastri Mahavidyalaya, Dharmabad, Dist. Nanded, 431809, Maharashtra, India

    D N Rander & K S Kanse

  2. Department of Electronics, Lal Bahadur Shastri Mahavidyalaya, Dharmabad, Dist. Nanded, 431809, Maharashtra, India

    Y S Joshi

  3. School of Physical Sciences, S.R.T.M. University, Nanded, 431606, Maharashtra, India

    A C Kumbharkhane

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  1. D N Rander
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  2. Y S Joshi
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  3. K S Kanse
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  4. A C Kumbharkhane
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Correspondence to A C Kumbharkhane.

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Rander, D.N., Joshi, Y.S., Kanse, K.S. et al. Dielectric relaxation and hydrogen bonding interaction in xylitol–water mixtures using time domain reflectometry. Indian J Phys 90, 67–72 (2016). https://doi.org/10.1007/s12648-015-0728-2

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