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Dielectric relaxation study of aqueous 2-ethoxyethanol using time domain reflectometry technique

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Abstract

The complex permittivity spectra of 2-ethoxyethanol in water solutions have been studied at different concentrations and temperatures using a picosecond time domain reflectometry technique. The complex dielectric permittivity spectrum of 2-ethoxyethanol shows Cole-Davidson type behavior. Increase in dielectric relaxation time may be due to increase in hetero molecular interaction strength. Minimum in Excess dielectric constant values provides the information about stable complex adduct. The Kirkwood correlation factor, thermodynamic properties and Bruggeman factor have also been determined and the results are interpreted in terms of hydrogen bonding and interactions among the solute — solvent molecules.

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Authors and Affiliations

  1. Department of Electronics, Lal Bahdur Shastri Mahavidyalaya, Dharmabad, Dist.-Nanded, 431 809, Maharashtra, India

    Y. S. Joshi

  2. School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded, 431 606, Maharashtra, India

    P. G. Hudge & A. C. Kumbharkhane

Authors
  1. Y. S. Joshi
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  2. P. G. Hudge
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  3. A. C. Kumbharkhane
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Correspondence to A. C. Kumbharkhane.

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Joshi, Y.S., Hudge, P.G. & Kumbharkhane, A.C. Dielectric relaxation study of aqueous 2-ethoxyethanol using time domain reflectometry technique. Indian J Phys 85, 1603–1614 (2011). https://doi.org/10.1007/s12648-011-0176-6

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  • DOI: https://doi.org/10.1007/s12648-011-0176-6

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