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Dielectric relaxation and hydrogen bond interaction study of diol-water mixtures

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Abstract

Complex dielectric permittivity measurements in the frequency range 10MHz-20GHz have been carried out in diol-water mixtures over the entire concentration range using a time domain reflectometry (TDR) method at 25°C. A hydrogen bonded theory is applied to compute the dielectric constant for the mixtures. It adequately reproduces the experimental values of static dielectric constants for the diol-water mixtures. The dielectric parameters confirm that the intermolecular homogeneous and heterogeneous hydrogen bonding vary significantly with the increase in concentration of the constituents of the diol-water mixtures.

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Authors and Affiliations

  1. School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded, 431 606, Maharashtra, India

    S. D. Chavan, B. D. Watode, P. G. Hudge, D. B. Suryawanshi, C. G. Akode & A. C. Kumbharkhane

  2. Department of Computer Science & Information Technology, Dr. B A Marathwada University, Aurangabad, 431 004, Maharashtra, India

    S. C. Mehrotra

Authors
  1. S. D. Chavan
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  2. B. D. Watode
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  3. P. G. Hudge
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  4. D. B. Suryawanshi
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  5. C. G. Akode
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  6. A. C. Kumbharkhane
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  7. S. C. Mehrotra
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Correspondence to A. C. Kumbharkhane.

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Chavan, S.D., Watode, B.D., Hudge, P.G. et al. Dielectric relaxation and hydrogen bond interaction study of diol-water mixtures. Indian J Phys 84, 419–429 (2010). https://doi.org/10.1007/s12648-010-0027-x

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  • DOI: https://doi.org/10.1007/s12648-010-0027-x

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