Abstract
Improving the purity of glass fiber powder represents a crucial challenge that needs to be addressed in the development of the glass fiber industry. To investigate the flotation behavior of glass fiber powder and the adsorption mechanism of the collector on its surface, the effect of flotation time, collector type, and concentration in flotation experiments was studied. Zeta potential, Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS) were used for systematic analysis. The results show that flotation effectively removes the visible impurities mixed in the glass fiber powder. The collection capacity of poly (propylene glycol) bis (2-aminopropyl ether) (PEA) generally surpasses that of conventional monoamine collectors. With the novel collector PEA, especially at a concentration of 6 × 10−5 mol/L of PEA-D2000, the flotation recovery rate of glass fiber powder can reach approximately 95%. Furthermore, a flotation mechanism for the glass fiber powder using amine-based collectors is proposed. It is adsorbed onto the surface of glass fiber powder through − NH3+/−NH2 groups, primarily by hydrogen bonding, and supplemented by electrostatic adsorption.
Similar content being viewed by others
Data Availability
No datasets were generated or analysed during the current study.
References
Nazir MT, Khalid A, Wang C, Baena JC, Phung BT, Akram S, Wong KL, Yeoh GH (2022) Enhanced fire retardancy with excellent electrical breakdown voltage, mechanical and hydrophobicity of silicone rubber/aluminium trihydroxide composites by milled glass fibres and graphene nanoplatelets. Surf Interfaces 35:102494. https://doi.org/10.1016/j.surfin.2022.102494
Saravanakumar K, Subramanian H, Arumugam V, Dhakal H (2019) Influence of milled glass fillers on the impact and compression after impact behavior of glass/epoxy composite laminates. Polym Test 75:133–141. https://doi.org/10.1016/j.polymertesting.2019.02.007
Zhai H, Zhou X, Fang L, Lu A (2010) Study on mechanical properties of powder impregnated glass fiber reinforced poly(phenylene sulphide) by injection molding at various temperatures. J Appl Polym Sci 115(4):2019–2027. https://doi.org/10.1002/app.31214
Zhang H, Li W, Yang X, Lu L, Wang X, Sun X, Zhang Y (2007) Development of polyurethane elastomer composite materials by addition of milled fiberglass with coupling agent. Mater Lett 61(6):1358–1362. https://doi.org/10.1016/j.matlet.2006.07.031
Zhang H, Li W, Yang X, Zhang Y, Chen Y (2007) Microstructural characterizations and mechanical behavior of polyurethane elastomers strengthened with milled fiberglass. J Mater Process Tech 190(1–3):96–101. https://doi.org/10.1016/j.jmatprotec.2007.02.053
Jing M, Sui G, Zhao J, Zhang Q, Fu Q (2019) Enhancing crystallization and mechanical properties of poly(lactic acid)/milled glass fiber composites via self-assembled nanoscale interfacial structures. Compos Part A-Appl S 117:219–229. https://doi.org/10.1016/j.compositesa.2018.11.020
Luo B, Zhu Y, Sun C, Li Y, Han Y (2018) The flotation behavior and adsorption mechanisms of 2-((2-(decyloxy)ethyl)amino)lauric acid on quartz surface. Min Eng 117:121–126. https://doi.org/10.1016/j.mineng.2017.12.016
Larsen E, Kleiv RA (2017) Flotation of metallurgical grade silicon and silicon metal from slag by selective hydrogen fluoride-assisted flotation. Metall Mater Trans B 48(6):2859–2865. https://doi.org/10.1007/s11663-017-1082-x
Jiang X, Shi J, Chen C, Song W, Ban B, Li J, Wang A, Chen J (2021) Flotation mechanism and application of PEA with different chain lengths in quartz flotation. Chem Eng Sci 246:116813. https://doi.org/10.1016/j.ces.2021.116813
Wang L, Sun W, Hu Y, Xu L (2014) Adsorption mechanism of mixed anionic/cationic collectors in Muscovite-Quartz flotation system. Min Eng 64:44–50. https://doi.org/10.1016/j.mineng.2014.03.021
Vatalis KI, Charalambides G, Benetis NP (2015) Market of high purity quartz innovative applications. Procedia Econ Finance 24:734–742. https://doi.org/10.1016/s2212-5671(15)00688-7
Wei M, Ban B, Li J, Sun J, Li F, Jiang X, Chen J (2019) Flotation behavior, collector adsorption mechanism of Quartz and Feldspar-Quartz systems using PEA as a Novel Green Collector. Silicon 12(2):327–338. https://doi.org/10.1007/s12633-019-00135-3
Crundwell FK (2016) On the mechanism of the flotation of oxides and silicates. Min Eng 95:185–196. https://doi.org/10.1016/j.mineng.2016.06.017
Jada A, Akbour RA, Douch J (2006) Surface charge and adsorption from water onto quartz sand of humic acid. Chemosphere 64(8):1287–1295. https://doi.org/10.1016/j.chemosphere.2005.12.063
Zhou Y, He C, Yang X (2008) Water contents and deformation mechanism in ductile shear zone of middle crust along the Red River fault in southwestern China. Sci China Ser D 51(10):1411–1425. https://doi.org/10.1007/s11430-008-0115-3
Saikia BJ, Parthasarathy G, Sarmah NC (2008) Fourier transform infrared spectroscopic estimation of crystallinity in SiO2 based rocks. B Mater Sci 31(5):775–779. https://doi.org/10.1007/s12034-008-0123-0
Wu J, Zhao L, Chronister EL, Tolbert SH (2002) Elasticity through nanoscale distortions in periodic surfactant-templated porous silica. J Phys Chem B 106(22):5613–5621. https://doi.org/10.1021/jp013497n
Liu W, Liu W, Wei D, Li M, Zhao Q, Xu S (2017) Synthesis of N,N-Bis(2-hydroxypropyl)laurylamine and its flotation on quartz. Chem Eng J 309:63–69. https://doi.org/10.1016/j.cej.2016.10.036
Li J, Lin Y, Shi J, Ban B, Sun J, Ma Y, Wang F, Lv W, Chen J (2020) Recovery of high purity Si from kerf-loss Si slurry waste by flotation method using PEA collector. Waste Manage 115:1–7. https://doi.org/10.1016/j.wasman.2020.07.023
Papini RM, Brandao PRG, Peres AEC (2001) Cationic flotation of iron ores: amine characterization and performance. Min Metall Proc 18(1):5–9. https://doi.org/10.1007/BF03402863
Kasomo RM, Li H, Zheng H, Chen Q, Weng X, Mwangi AD, Kiamba E, Song S (2020) Depression of the selective separation of rutile from almandine by sodium hexametaphosphate. Colloid Surf A 593:124631. https://doi.org/10.1016/j.colsurfa.2020.124631
Wang X, Plackowski CA, Nguyen AV (2016) X-ray photoelectron spectroscopic investigation into the surface effects of sulphuric acid treated natural zeolite. Powder Technol 295:27–34. https://doi.org/10.1016/j.powtec.2016.03.025
Liu W, Liu W, Wang X, Wei D, Wang B (2016) Utilization of novel surfactant N-dodecyl-isopropanolamine as collector for efficient separation of quartz from hematite. Sep Purif Technol 162:188–194. https://doi.org/10.1016/j.seppur.2016.02.033
Buckley AN, Parker GK (2013) Adsorption of n-octanohydroxamate collector on iron oxides. Int J Min Process 121:70–89. https://doi.org/10.1016/j.minpro.2013.03.004
Alagta A, Felhösi I, Bertoti I, Kálmán E (2008) Corrosion protection properties of hydroxamic acid self-assembled monolayer on carbon steel. Corros Sci 50(6):1644–1649. https://doi.org/10.1016/j.corsci.2008.02.008
Xu L, Tian J, Wu H, Deng W, Yang Y, Sun W, Gao Z, Hu Y (2017) New insights into the oleate flotation response of feldspar particles of different sizes: anisotropic adsorption model. J Colloid Interf Sci 505:500–508. https://doi.org/10.1016/j.jcis.2017.06.009
Fuerstenau DW, Pradip (2005) Zeta potentials in the flotation of oxide and silicate minerals. Adv Colloid Interfac 114–115:9–26. https://doi.org/10.1016/j.cis.2004.08.006
Mhlanga SS, O’connor CT, Mcfadzean B (2012) A study of the relative adsorption of guar onto pure minerals. Min Eng 36–38:172–178. https://doi.org/10.1016/j.mineng.2012.03.026
Jiang X, Chen J, Wei M, Li F, Ban B, Li J (2020) Effect of impurity content difference between quartz particles on flotation behavior and its mechanism. Powder Technol 375:504–512. https://doi.org/10.1016/j.powtec.2020.07.107
Jiang X, Chen J, Ban B, Song W, Chen C, Yang X (2022) Application of competitive adsorption of ethylenediamine and polyetheramine in direct float of quartz from quartz-feldspar mixed minerals under neutral pH conditions. Min Eng 188:107850. https://doi.org/10.1016/j.mineng.2022.107850
Acknowledgements
The authors provide their gratitude to University of Science and Technology of China and Hefei Institutes of Physical Science, Chinese Academy of Sciences for their support.
Funding
This work was financially supported by National Natural Science Foundation of China (No.51804294, No.51874272, and No.52111540265); Anhui Provincial Natural Science Foundation (3No. 1808085ME121); Key Laboratory of Photovoltaic and Energy Conservation Materials, Chinese Academy of Science (PECL2021QN003); HFIPS President Foundation (YZJJZX202018); International Clean Energy Talent Program by China Scholarship Council.
Author information
Authors and Affiliations
Contributions
Zhangchao Mo: Conceptualization, Methodology, Writing-original draft. Xiaoxiao Zhu: Investigation, Methodology. Xuesong Jiang: Validation. Juxuan Ding: Visualization. Ling Wang: Resources. Boyuan Ban: Resources. Jifei Sun: Visualization. Jian Chen: Supervision, Resources, Writing – review & editing.
Corresponding author
Ethics declarations
Ethics Approval
Not applicable.
Consent to Participate
Not applicable.
Consent for Publication
Not applicable.
Competing Interests
The authors declare no competing interests.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Mo, Z., Zhu, X., Jiang, X. et al. Study on the Flotation Behavior and Mechanism of Glass Fiber Powder. Silicon (2024). https://doi.org/10.1007/s12633-024-02984-z
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12633-024-02984-z