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Effect of Boron Incorporation on the Mechanical, and Radiation Shielding Behaviors of Borosilicate Bioactive Glasses

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A Correction to this article was published on 10 July 2023

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Abstract

The current research report aimed the use of a bioactive glass systems of the chemical composition (80-x)SiO2–15CaO–5P2O5–xB2O3; 0 (MBG) ≤ x ≤ 15 (15.0B-MBG) mol% as radiation protection candidate for γ-rays. The density (ρ) of the investigated glasses reduced slightly from 2.6785 to 2.6637 g/cm3 and the molar volume (Vm) increased from 23.7353 to 24.4042 cm3/mol. The mass attenuation coefficient (MAC) for photon energies ranging from 15 keV to 100 keV using the XCOM code and Phys-X software was estimated. The highest discrepancy among the MAC values calculated by XCOM and Phys-X was found less than 2.5% at 15.0 keV and 5% at 100 keV. In terms of the effective-atomic-number (Zeff), it found that the sample encoded as MBG had the uppermost Zeff. In general, the analysis showed that the selected MBG-15.0B-MBG glasses provide adequate protection against low-energy photons (i.e., E < 30 keV), but their shielding ability decreases at high energies (60 < E < 100 keV). In addition, the various elastic-mechanical intrinsic of samples were calculated, including the total dissociation energy (G), which decreased from 65.425 to 57.565 kJ/cm3 as the B2O3 content increased from 0.0 to 15.0 mol%. The Poisson’s ratio (σ) improved from 0.41253 to 0.41603 and Young’s modulus reduced from 79.110 to 72.510 GPa. Results shows a significantly impact of B2O3 insertion into the investigated glasses network.

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Acknowledgments

The authors express their gratitude to Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2023R60), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.

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To Princess Nourah Bint Abdulrahman University Researchers Supporting Project number (PNURSP2023R60).

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Norah A. M. Alsaif: Conceptualization, assisted in data collection & analysis and rearranging the manuscript first draft; Z. Khattari: Conceptualization, review & editing, writing manuscript first draft; Hanan Al-Ghamdi: Conceptualization, review & editing, writing manuscript first draft; Neslihan Ekinci: Assisted in data collection & analysis and rearranging the manuscript first draft; Y.S. Rammah: Supervision and finalized the last version of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Neslihan Ekinci or Y. S. Rammah.

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Alsaif, N.A.M., Khattari, Z.Y., Al-Ghamdi, H. et al. Effect of Boron Incorporation on the Mechanical, and Radiation Shielding Behaviors of Borosilicate Bioactive Glasses. Silicon 15, 7137–7145 (2023). https://doi.org/10.1007/s12633-023-02562-9

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