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Manufacturing Porous Materials Using Dabco-Based Ionic Liquid

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Abstract

The long-chain ionic liquid (IL) hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide was used as a template to prepare the hexagonally ordered siliceous mesoporous molecular sieve MCM-41 as well as the disordered mesoporous molecular sieve designated as KIT-1. The synthesized products were studied via X-ray diffraction (XRD), Fourier transform infrared (FTIR), N2 adsorption-desorption analysis, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Also, the surface area (BET), pore volume, and pore diameter (BJH) are determined. These kind of ILs which have 1,4-diazabicyclo[2.2.2]octane (DABCO) in their structures, were prepared with an easy method. When the two templates, cetyltrimethylammonium bromide (CTAB) and IL, have the similar structures, MCM-41 mesoporous molecular sieve produced with more ordered, uniform mesoporous channel and high surface area in comparison to without IL. When just IL used instead of CTAB, the KIT-1 with non-uniform mesoporous was obtained. Here we prepared the KIT-1 mesoporous molecular sieve with IL without CTAB. Also, using dual template CTAB and DABCO based IL leads to increase the pore walls of products. It seems, using dual template with changing IL structures in fabricated of molecular sieve provide new opportunity to design targeted adsorbents and catalysis.

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Acknowledgements

The authors wish to thank the Ahvaz Branch, Islamic Azad University for providing the essential financial support.

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Authors and Affiliations

  1. Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran

    Haleh Sanaeishoar & Sahar Peimanfar

  2. Chemistry Department, Faculty of Sciences, Shahid Rajaee Teacher Training University, PO Box 16785-163, Tehran, Iran

    Maryam Sabbaghan & Maryam Ghanbari

  3. Department of Chemistry, Payame Noor University, Tehran, Iran

    Maryam Ghazvini

Authors
  1. Haleh Sanaeishoar
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  2. Maryam Sabbaghan
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  3. Maryam Ghazvini
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  4. Maryam Ghanbari
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  5. Sahar Peimanfar
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Contributions

HS: Conceptualization; Methodology; Investigation; Writing. MS: Conceptualization; Visualization; Writing—review and editing and discussion. MG: Methodology and Editing MG: Synthesis SP: Synthesis; Formal analysis.

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Correspondence to Haleh Sanaeishoar or Maryam Sabbaghan.

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Sanaeishoar, H., Sabbaghan, M., Ghazvini, M. et al. Manufacturing Porous Materials Using Dabco-Based Ionic Liquid. Silicon 14, 6291–6297 (2022). https://doi.org/10.1007/s12633-021-01403-x

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