Abstract
Nanosized mesoporous AlKIT-1 molecular sieve was hydrothermally synthesized in the absence of organic salts. The samples were characterized by X-ray diffraction, electron microscopy (TEM and SEM), N2 adsorption isotherm, and NH3-TPD methods. The AlKIT-1 has a particle size of about 60–100 nm, and a three-dimensional network structure with average pore size of 2.7 nm. The sample exhibits good hydrothermal stability and catalytic performance for 1,2,4-trimethylbenzene, suggesting its promising applications in the conversion of large molecules.
Graphical Abstract
The nanosized AlKIT-1 molecular sieve was synthesized by a simple synthetic route. TEM shows that the pore structure is a three-dimensional, disordered network of short wormlike channels. SEM shows that conglomerate particles have the sphere-like shape and the particle size is about 60–100 nm.
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Acknowledgments
This study was financially supported by the National Science Foundation of China (NSFC, Grant 20773019, 20603004) and the National “973” Project of China (2011CB201301).
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Liu, L., Xiong, G., Wang, X. et al. Synthesis of Nanosized AlKIT-1 Mesoporous Molecular Sieve and its Catalytic Performance for the Conversion of 1,2,4-Trimethylbenzene. Catal Lett 141, 1136–1141 (2011). https://doi.org/10.1007/s10562-011-0580-8
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DOI: https://doi.org/10.1007/s10562-011-0580-8