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Sulfonic Acid-Functionalized Silica-Coated Magnetic Nanoparticles as a Reusable Catalyst for the Preparation of Pyrrolidinone Derivatives Under Eco-Friendly Conditions

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Abstract

The surface of silica-coated CoFe2O4 magnetic nanoparticles (CoFe2O4@SiO2), which is resistant to the oxidation due to silicone coating, was functionalized using chlorosulfonic acid and used as an efficient and recyclable catalyst for the preparation of 3-pyrrolin-2-ones from diethyl acetylenedicarboxylate, an aldehyde and aniline in ethanol solvent at 60 °C. In the presented study, some fascinating chracteritics of such catalyst, such as magnetically separable, simple workup and obtaining a high purity of products by simple recrystallization, have been successfully obtained. The structural features of CoFe2O4@SiO2-SO3H catalyst were elucidated by X-ray powder diffraction (XRPD), thermo-gravimetric studying (TGA), scanning electron microscopy (SEM) and FT-IR spectra.

Sulfnic acid-functionalized silica-coated magnetic nanoparticles as a reusable catalyst for the preparation of pyrrolidinone derivatives under eco-friendly conditions

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Authors and Affiliations

  1. Department of Chemistry, University of Zanjan, P O Box 45195-313, Zanjan, Iran

    Zahra Hosseinzadeh & Ali Ramazani

  2. Department of Chemistry, Abhar Branch, Islamic Azad University, Abhar, Iran

    Hamideh Ahankar

  3. Faculty of Chemistry, University of Wrocław, 14 Joliot-Curie St, 50383, Wrocław, Poland

    Katarzyna Ślepokura & Tadeusz Lis

Authors
  1. Zahra Hosseinzadeh
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  2. Ali Ramazani
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  3. Hamideh Ahankar
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  4. Katarzyna Ślepokura
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  5. Tadeusz Lis
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Correspondence to Ali Ramazani.

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Hosseinzadeh, Z., Ramazani, A., Ahankar, H. et al. Sulfonic Acid-Functionalized Silica-Coated Magnetic Nanoparticles as a Reusable Catalyst for the Preparation of Pyrrolidinone Derivatives Under Eco-Friendly Conditions. Silicon 11, 2933–2943 (2019). https://doi.org/10.1007/s12633-019-0087-2

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  • DOI: https://doi.org/10.1007/s12633-019-0087-2

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