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Electrochemical Behavior of Titanium (IV) Silsesquioxane Occluded in the MCM-41 Cavity and their Application in the Electro-Oxidation of Sulphite and Dipyrone Compounds

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Abstract

Titanium (IV) silsesquioxane was occluded in the cavities of a mesoporous silica MCM-41. The material was chemically modified with nickel hexacyanoferrate (III) (named MTTiPNiH) and subsequently characterized by spectroscopic techniques: Fourier Transform Infrared, X-ray Dispersive Energy Spectroscopy, Scanning Electron Microscopy and cyclic voltammetry. The voltammetric studies of MTTiPNiH was obtained using a graphite paste electrode which was possible to observe one well-defined redox pair with formal potential E°′ = +0.53 V attributed to FeII(CN)6 / FeIII(CN)6 in the presence of Ni2+ ions. As an application, the graphite paste electrode modified with MTTiPNiH was tested for sulphite and dipyrone detection.

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Authors and Affiliations

  1. Departamento de Física e Química, Faculdade de Engenharia de Ilha Solteira UNESP, Universidade Estadual Paulista, Av. Brasil Centro, 56. CEP, Ilha Solteira, SP, 15385-000, Brazil

    Devaney Ribeiro Do Carmo, Priscila Fernanda Pereira Barbosa & Loanda Raquel Cumba

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  1. Devaney Ribeiro Do Carmo
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  2. Priscila Fernanda Pereira Barbosa
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  3. Loanda Raquel Cumba
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Correspondence to Devaney Ribeiro Do Carmo.

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Do Carmo, D.R., Barbosa, P.F.P. & Cumba, L.R. Electrochemical Behavior of Titanium (IV) Silsesquioxane Occluded in the MCM-41 Cavity and their Application in the Electro-Oxidation of Sulphite and Dipyrone Compounds. Silicon 12, 1111–1123 (2020). https://doi.org/10.1007/s12633-019-00215-4

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