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Voltammetric Properties of Nickel Hexacyanoferrate (III) Obtained on the Titanium (IV) Silsesquioxane Occluded into the H-FAU Zeolite for Detection of Sulfite

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Abstract

A composite prepared from titanium (IV) silsesquioxane and phosphoric acid (TTiP) was prepared and occluded into the H-FAU zeolite (ZTTiP). The material was chemically modified with nickel and subsequently by potassium hexacyanoferrate (III) (ZTTiPNiH). It was preliminarily characterized by infrared spectroscopy (IR), energy dispersive X-ray spectroscopy (EDS) and cyclic voltammetry (CV). The voltammetric behavior of ZTTipNiH was obtained employing a modified graphite paste electrode (GPE) showing one well-defined redox couple with a formal potential of E\(^{{\theta ^{\prime }}}=\) 0.51V (vs Ag/AgCl(sat)), KCl (3M) (20% w/w; v = 20 mV s− 1; KCl; 1.00 mol L− 1) corresponding to the NiIIFeII(CN)6/NiIIFeIII(CN)6 redox process. After rigorous voltammetric studies, the GPE modified with ZTTiPNiH was applied for facile and rapid detection of sulfite. From the analytical curve, a linear response was obtained in a concentration range of 0.05 to 0.80 mmol L− 1 and a detection limit (3σ) of 0.05 mmol L− 1 with a relative standard deviation of 4.21% (n = 3) and an amperometric sensitivity of 14.42 mA L mol− 1 for sulfite.

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Funding

The authors would like to express their gratitude for the financial support by the Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP- Proc. 2012/05438-1 and Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES).

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  1. Departamento de Física e Química, Faculdade de Engenharia de Ilha Solteira, UNESP - Universidade Estadual Paulista, Av. Brasil Centro, 56, CEP 15385-000, Ilha Solteira, SP, Brazil

    Devaney Ribeiro do Carmo, Vitor Alexandre Maraldi & Loanda Raquel Cumba

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  1. Devaney Ribeiro do Carmo
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  2. Vitor Alexandre Maraldi
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Correspondence to Devaney Ribeiro do Carmo.

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do Carmo, D.R., Maraldi, V.A. & Cumba, L.R. Voltammetric Properties of Nickel Hexacyanoferrate (III) Obtained on the Titanium (IV) Silsesquioxane Occluded into the H-FAU Zeolite for Detection of Sulfite. Silicon 11, 267–276 (2019). https://doi.org/10.1007/s12633-018-9918-9

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