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Optimization of High Conducting Na3Zr2Si2PO12 Phase by new Phosphate Salt for Solid Electrolyte

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Abstract

A composition of NASICON (Na3Zr2Si2PO12) was synthesized by the solid-state reaction method using a new compound Na2HPO42H2O. The X-ray diffraction patterns of all samples exhibit monoclinic Na3Zr2Si2PO12 as a major phase with a very small amount of monoclinic-ZrO2. The maximum relative density (97 %) and maximum conductivity is obtained in the samples sintered at 1200 °C (N3) which is slightly higher than β-Al2O3. The activation energy is ∼ 0.20 eV for the N3 sample which is lower than for β-Al2O3. The dilatometeric study and Arrhenius plots confirmed a phase transition of NASICON from monoclinic to rhombohedral. The micro-structural study of the samples done by scanning electron microscopy (SEM) indicated a significant influence of the processing conditions on the microstructures. Raman spectroscopy demonstrated that the sample N3 exhibits minor structural changes compared to other samples.

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Authors and Affiliations

  1. School of Physics and Materials Science, Thapar University, Patiala, 147004, India

    Paramjyot Kumar Jha, O. P. Pandey & K. Singh

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  1. Paramjyot Kumar Jha
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  2. O. P. Pandey
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  3. K. Singh
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Correspondence to K. Singh.

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Jha, P.K., Pandey, O.P. & Singh, K. Optimization of High Conducting Na3Zr2Si2PO12 Phase by new Phosphate Salt for Solid Electrolyte. Silicon 9, 411–419 (2017). https://doi.org/10.1007/s12633-015-9396-2

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  • DOI: https://doi.org/10.1007/s12633-015-9396-2

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