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Infrared Absorption of Some Alkali Borate and Alkali Silicate Glasses Containing Nickel & Iron Oxides

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Abstract

This work has been carried out to investigate the infrared absorption spectra, of a number of alkali borate and alkali silicate glasses containing nickel oxide and/or iron oxide to investigate the structure of theses glasses. All glasses studied were melted in platinum 2 % rhodium crucibles in an electrically heated furnace at different temperature (1000 – 1400) 0C for two hours. The results are explained on the basis that the nickel and ferric ions exist in glass as divalent nickel and trivalent ferric ions respectively in two different states, i.e., octahedral and tetrahedral coordinations.

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Authors and Affiliations

  1. Glass Research Department, National Research Centre, Dokki, Cairo, Egypt

    A. M. Fayad & F. A. Moustaffa

  2. Physics Department, Faculty of Science, Suez Canal University, Arish, Egypt

    I. M. El-Kashef

Authors
  1. A. M. Fayad
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  2. I. M. El-Kashef
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  3. F. A. Moustaffa
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Correspondence to A. M. Fayad.

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Fayad, A.M., El-Kashef, I.M. & Moustaffa, F.A. Infrared Absorption of Some Alkali Borate and Alkali Silicate Glasses Containing Nickel & Iron Oxides. Silicon 9, 555–561 (2017). https://doi.org/10.1007/s12633-015-9300-0

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  • DOI: https://doi.org/10.1007/s12633-015-9300-0

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