Abstract
The effects of trace yttrium (Y) element on the microstructure, mechanical properties, and corrosion resistance of Mg—2Zn—0.1Mn—0.3Ca—xY (x = 0, 0.1, 0.2, 0.3) biological magnesium alloys are investigated. Results show that grain size decreases from 310 to 144 µm when Y content increases from 0wt% to 0.3wt%. At the same time, volume fraction of the second phase increases from 0.4% to 6.0%, yield strength of the alloy continues to increase, and ultimate tensile strength and elongation decrease initially and then increase. When the Y content increases to 0.3wt%, Mg3Zn6Y phase begins to precipitate in the alloy; thus, the alloy exhibits the most excellent mechanical property. At this time, its ultimate tensile strength, yield strength, and elongation are 119 MPa, 69 MPa, and 9.1%, respectively. In addition, when the Y content is 0.3wt%, the alloy shows the best corrosion resistance in the simulated body fluid (SBF). This investigation has revealed that the improvement of mechanical properties and corrosion resistance is mainly attributed to the grain refinement and the precipitated Mg3Zn6Y phase.
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J.L. Su, J. Teng, Z.L. Xu, and Y. Li, Biodegradable magnesium-matrix composites: A review, Int. J. Miner. Metall. Mater., 27(2020), No. 6, p. 724.
M. Razzaghi, M. Kasiri-Asgarani, H.R. Bakhsheshi-Rad, and H. Ghayour, In vitro bioactivity and corrosion of PLGA/hardystonite composite-coated magnesium-based nanocomposite for implant applications, Int. J. Miner. Metall. Mater., 28(2021), No. 1, p. 168.
Z. Zhang, J.H. Zhang, J. Wang, Z.H. Li, J.S. Xie, S.J. Liu, K. Guan, and R.Z. Wu, Toward the development of Mg alloys with simultaneously improved strength and ductility by refining grain size via the deformation process, Int. J. Miner. Metall. Mater., 28(2021), No. 1, p. 30.
M.P. Staiger, A.M. Pietak, J. Huadmai, and G. Dias, Magnesium and its alloys as orthopedic biomaterials: A review, Biomaterials, 27(2006), No. 9, p. 1728.
M.W. Yu, J.Y. Li, J.X. Li, J. Wang, H.Y. Lai, and Y. Zhang, Effects of trace Sr on microstructure, mechanical properties and corrosion resistance of Mg—0.2Zn—0.1Mn—xSr biomaterials, Rare Met. Mater. Eng., 48(2019), No. 12, p. 4016.
Y.Z. Xu, J.Y. Li, M.F. Qi, L.H. Liao, and Z.J. Gao, Enhanced mechanical properties of Mg-Zn-Y-Zr alloy by low-speed indirect extrusion, J. Mater. Res. Technol., 9(2020), No. 5, p. 9856.
R.Q. Zhang, J.F. Wang, S. Huang, S.J. Liu, and F.S. Pan, Substitution of Ni for Zn on microstructure and mechanical properties of Mg-Gd-Y-Zn-Mn alloy, J. Magnes. Alloys, 5(2017), No. 3, p. 355.
W.W. He, E.L. Zhang, and K. Yang, Effect of Y on the bio-corrosion behavior of extruded Mg-Zn-Mn alloy in Hank’s solution, Mater. Sci. Eng. C, 30(2010), No. 1, p. 167.
Z.R. Xie, C. Zhang, H.C. Pan, Y.X. Wang, Y.P. Ren, and G.W. Qin, Microstructures and bio-corrosion resistances of as-extruded Mg-Ca alloys with ultra-fine grain size, Rare Met., 2017, DOI: https://doi.org/10.1007/s12598-017-0945-2.
L. Zhang, Z. Liu, and P.L. Mao, Effect of annealing on the microstructure and mechanical properties of Mg-2.5Zn-0.5Y alloy, Int. J. Miner. Metall. Mater., 21(2014), No. 8, p. 779.
E. Aghion, G. Levy, and S. Ovadia, In vivo behavior of biodegradable Mg-Nd-Y-Zr-Ca alloy, J. Mater. Sci. -Mater. Med., 23(2012), No. 3, p. 805.
Y.Z. Xu, J.Y. Li, M.F. Qi, J.B. Gu, and Y. Zhang, Effect of extrusion on the microstructure and corrosion behaviors of biodegradable Mg-Zn-Y-Gd-Zr alloy, J. Mater. Sci., 55(2020), No. 3, p. 1231.
S.Q. Yin, W.C. Duan, W.H. Liu, L. Wu, J.M. Yu, Z.L. Zhao, M. Liu, P. Wang, J.Z. Cui, and Z.Q. Zhang, Influence of specific second phases on corrosion behaviors of Mg-Zn-Gd-Zr alloys, Corros. Sci., 166(2020), art. No. 108419.
C. Zhang, L. Wu, H. Liu, G.S. Huang, B. Jiang, A. Atrens, and F.S. Pan, Microstructure and corrosion behavior of Mg-Sc binary alloys in 3.5wt% NaCl solution, Corros. Sci., 174(2020), art. No. 108831.
T. Kokubo and H. Takadama, How useful is SBF in predicting in vivo bone bioactivity? Biomaterials, 27(2006), No. 15, p. 2907.
D.F. Zhang, X.X. Xu, F.G. Qi, X.X. Guo, and Z.T. Zhu, Research status of yttrium-containing Mg-Zn based magnesium alloys, Foundary, 61(2012), No. 3, p. 266.
J.X. Li, Y. Zhang, J.Y. Li, and J.X. Xie, Effect of trace HA on microstructure, mechanical properties and corrosion behavior of Mg—2Zn—0.5Sr alloy, J. Mater. Sci. Technol., 34(2018), No. 2, p. 299.
Y. Zhang, J.X. Li, and J.Y. Li, Microstructure, mechanical properties, corrosion behavior and film formation mechanism of Mg—Zn—Mn—xNd in Kokubo’s solution, J. Alloys Compd., 730(2018), p. 458.
H.S. Jiang, Microstructure and Mechanical Properties of High Strength Mg—Zn—(Y/Gd)—Zr—(Ca) Alloys Containing W Phase [Dissertation], Harbin Institute of Technology, Harbin, 2017.
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This work was financially supported by the National Natural Science Foundation of China (Nos. 52005034 and 52027805), the China Postdoctoral Science Foundation Funded Project (No. 2021M691860), the Beijing Postdoctoral Research Foundation (No. 2021-ZZ-073), the Zhuhai Industry-University-Research Cooperation Project (No. ZH22017001200176PWC), and the Tai’an City Science and Technology Innovation Major Project (No. 2021ZDZX011).
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Qi, M., Wei, L., Xu, Y. et al. Effect of trace yttrium on the microstructure, mechanical property and corrosion behavior of homogenized Mg—2Zn—0.1Mn—0.3Ca—xY biological magnesium alloy. Int J Miner Metall Mater 29, 1746–1754 (2022). https://doi.org/10.1007/s12613-021-2327-x
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DOI: https://doi.org/10.1007/s12613-021-2327-x