Skip to main content
Log in

Rapid removal of copper impurity from bismuth-copper alloy melts via super-gravity separation

  • Published:
International Journal of Minerals, Metallurgy and Materials Aims and scope Submit manuscript

Abstract

A green method of super-gravity separation, which can enhance the filtration process of bismuth and copper phases, was investigated and discussed for the rapid removal of copper impurity from bismuth-copper alloy melts. After separation by the super-gravity field, the bismuth-rich liquid phases were mainly filtered from the alloy melt along the super-gravity direction, whereas most of the fine copper phases were retained in the opposite direction. With optimized conditions of separation temperature at 280°C, gravity coefficient at 450, and separation time at 200 s, the mass proportion of the separated bismuth from the Bi-2wt%Cu and Bi-10wt%Cu alloys respectively reached 96% and 85%, which indicated the minimal loss of bismuth in the residual. Simultaneously, the removal ratio of impurity copper from the Bi-2wt%Cu and Bi-10wt%Cu alloys reached 88% and 98%, respectively. Furthermore, the separation process could be completed rapidly and is environmentally friendly and efficient.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. F.K. Ojebuoboh, Bismuth—Production, properties, and applications, JOM, 44(1992), No. 4, p. 46.

    Article  CAS  Google Scholar 

  2. Y.L. He, R.D. Xu, S.W. He, H.S. Chen, K. Li, Y. Zhu, and Q.F. Shen, Alkaline pressure oxidative leaching of bismuth-rich and arsenic-rich lead anode slime, Int. J. Miner. Metall. Mater., 26(2019), No. 6, p. 689.

    Article  CAS  Google Scholar 

  3. L.G. Wang, Metallurgy of Bismuth, Metallurgical Industry Press, Beijing, 1986, p. 99.

    Google Scholar 

  4. L.S. Chang, E. Rabkin, B.B. Straumal, B. Baretzky, and W. Gust, Thermodynamic aspects of the grain boundary segregation in Cu(Bi) alloys, Acta Mater., 47(1999), No. 15–16, p. 4041.

    Article  CAS  Google Scholar 

  5. O. Akinlade, R.N. Singh, and F. Sommer, Thermodynamic investigation of viscosity in Cu-Bi and Bi-Zn liquid alloys, J. Alloys Compd., 267(1998), No. 1–2, p. 195.

    Article  CAS  Google Scholar 

  6. W.Z. Guo, Study on Crystallization Refining of Crude Bismuth [Dissertation], Central South University, Changsha, 2014, p. 13.

    Google Scholar 

  7. Y. Chen, T. Liao, G.B. Li, B.Z. Chen, and X.C. Shi, Recovery of bismuth and arsenic from copper smelter flue dusts after copper and zinc extraction, Miner. Eng., 39(2012), p. 23.

    Article  CAS  Google Scholar 

  8. Y.N. Dai and B. Yang, Vacuum Metallurgy of Non-ferrous Metals, Metallurgical Industry Press, Beijing, 2009, p. 128.

    Google Scholar 

  9. J.T. Gao, L. Guo, Y.W. Zhong, H.R. Ren, and Z.C. Guo, Removal of phosphorus-rich phase from high-phosphorous iron ore by melt separation at 1573 K in a super-gravity field, Int. J. Miner. Metall. Mater., 23(2016), No. 7, p. 743.

    Article  CAS  Google Scholar 

  10. L. Meng, Z. Wang, Y.W. Zhong, K.Y. Chen, and Z.C. Guo, Supergravity separation of Pb and Sn from waste printed circuit boards at different temperatures, Int. J. Miner. Metall. Mater., 25(2018), No. 2, p. 173.

    Article  CAS  Google Scholar 

  11. C. Li, J.T. Gao, Z. Wang, and Z.C. Guo, Separation of fine Al2O3 inclusion from liquid steel with super gravity, Metall. Mater. Trans. B, 48(2017), No. 2, p. 900.

    Article  CAS  Google Scholar 

  12. L.X. Zhao, Z.C. Guo, Z. Wang, and M.Y. Wang, Removal of low-content impurities from Al by super-gravity, Metall. Mater. Trans. B, 41(2010), No. 3, p. 505.

    Article  Google Scholar 

  13. G.Y. Song, B. Song, Y.H. Yang, Z.B. Yang, and W.B. Xin, Separating behavior of nonmetallic inclusions in molten aluminum under super-gravity field, Metall. Mater. Trans. B, 46(2015), No. 5, p. 2190.

    Article  CAS  Google Scholar 

  14. X. Lan, J.T. Gao, Y. Li, and Z.C. Guo, A green method of respectively recovering rare earths (Ce, La, Pr, Nd) from rare-earth tailings under super-gravity, J. Hazard. Mater., 367(2019), p. 473.

    Article  CAS  Google Scholar 

  15. Z. Wang, J.T. Gao, A.J. Shi, L. Meng, and Z.C. Guo, Recovery of zinc from galvanizing dross by a method of super-gravity separation, J. Alloys Compd., 735(2018), p. 1997.

    Article  CAS  Google Scholar 

  16. J.T. Gao, Z.L. Huang, Z.W. Wang, and Z.C. Guo, Recovery of crown zinc and metallic copper from copper smelter dust by evaporation, condensation and super-gravity separation, Sep. Purif. Technol., 231(2020), art. No. 115925.

  17. Y.H. Yang, B. Song, G.Y. Song, Z.B. Yang, and W.B. Xin, Enriching and separating primary copper impurity from Pb-3 mass pct Cu melt by super-gravity technology, Metall. Mater. Trans. B, 47(2016), No. 5, p. 2714.

    Article  CAS  Google Scholar 

  18. L. Guo, X.C. Wen, Q.P. Bao, and Z.C. Guo, Removal of tramp elements within 7075 alloy by super-gravity aided rheorefining method, Metals, 8(2018), No. 9, art. No. 701.

  19. C. Li, J.T. Gao, Z. Wang, H.R. Ren, and Z.C. Guo, Separation of Fe-bearing and P-bearing phase from the steelmaking slag by super gravity, ISIJ Int., 57(2017), No. 4, p. 767.

    Article  CAS  Google Scholar 

  20. Y. Lu, J.T. Gao, F.Q. Wang, and Z.C. Guo, Separation of anosovite from modified titanium-bearing slag melt in a reducing atmosphere by supergravity, Metall. Mater. Trans. B, 48(2017), No. 2, p. 749.

    Article  CAS  Google Scholar 

  21. J.T. Gao, Y.W. Zhong, and Z.C. Guo, Selective precipitation and concentrating of perovskite crystals from titanium-bearing slag melt in supergravity field, Metall. Mater. Trans. B, 47(2016), No. 4, p. 2459.

    Article  CAS  Google Scholar 

  22. X. Lan, J.T. Gao, Z.L. Huang, and Z.C. Guo, Rapid separation of copper phase and iron-rich phase from copper slag at low temperature in a super-gravity field, Metall. Mater. Trans. B, 49(2018), No. 3, p. 1165.

    Article  CAS  Google Scholar 

  23. O. Teppo, J. Niemelä and P. Taskinen, An assessment of the thermodynamic properties and phase diagram of the system Bi-Cu, Thermochim. Acta, 173(1990), p. 137.

    Article  CAS  Google Scholar 

  24. Y. Watanabe, Y. Inaguma, H. Sato, and E. Miura-Fujiwara, A novel fabrication method for functionally graded materials under centrifugal force: The centrifugal mixed-powder method, Materials, 2(2009), No. 4, p. 2510.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (No. 51804030), and the project of State Key Laboratory of Advanced Metallurgy, China (41618024).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Lei Guo or Zhan-cheng Guo.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wen, Xc., Guo, L., Bao, Qp. et al. Rapid removal of copper impurity from bismuth-copper alloy melts via super-gravity separation. Int J Miner Metall Mater 28, 1929–1939 (2021). https://doi.org/10.1007/s12613-020-2118-9

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12613-020-2118-9

Keywords

Navigation