Abstract
X-ray fluorescence (XRF) scanning, which can be used for the rapid, high-resolution measurement of elements in marine sediments, is advantageous because multiple elements can be simultaneously analysed. However, the use of XRF scan data as quantitative data has limitations. The XRF scanning measures element intensities (cps) of sediments instead of element contents (wt%). In addition, the element intensities are influenced by physical properties, such as water content and lithification. The objective of this study is to establish a calibration method for quantifying the CaCO3 content from XRF Ca data based on comparisons between XRF Ca and inorganic carbon measured CaCO3 contents.
References
Archer DE (1991) Equatorial Pacific calcite preservation cycles: production or dissolution? Paleoceanography 6:561–571. https://doi.org/10.1029/91PA01630
Böning P, Bard E, Rose J (2007) Toward direct, micron-scale XRF elemental maps and quantitative profiles of wet marine sediments. Geochem Geophy Geosy 8:Q05004. https://doi.org/10.1029/2006GC001480
Jarvis S, Croudace IW, Rothwell RG (2015) Parameter optimisation for the ITRAX core scanner. In: Croudace IW, Rothwell RG (eds) Micro-XRF studies of sediment cores: applications of a non-destructive tool for the environmental sciences. Springer, Dordrecht, pp 535–562
Lyle M, Backman J (2013) Data report: calibration of XRF-estimated CaCO3 along the site U1338 splice. In: Proceedings of IODP, 320/321. Integr Ocean Drill Prog. https://doi.org/10.2204/iodp.proc.320321.205.2013
Lyle M, Baldauf J (2015) Biogenic sediment regimes in the neogene equatorial Pacific, IODP Site U1338: burial, production, and diatom community. Palaeogeogr Palaeocl 433:106–128. https://doi.org/10.1016/j.palaeo.2015.04.001
Lyle M, Lyle A, Gorgas T, Holbourn A, Westerhold T, Hathorne E, Kimoto K, Yamamoto S (2012) Data report: raw and normalized elemental data along the Site U1338 splice from X-ray fluorescence scanning. Proceedings of IODP 320/321. Integr Ocean Drill Prog. https://doi.org/10.2204/iodp.proc.320321.203.2012
Ridgwell A, Zeebe R (2005) The role of the global carbonate cycle in the regulation and evolution of the Earth system. Earth Planet Sc Lett 234:299–315. https://doi.org/10.1016/j.epsl.2005.03.006
Rothwell RG, Rack FR (2006) New techniques in sediment core analysis: an introduction. In: Rothwell RG (ed) New techniques in sediment core analysis. Geological Society, London, pp 1–29
Tjallingii R, Röhl U, Kölling M, Bickert T (2007) Influence of the water content on X-ray fluorescence core-scanning measurements in soft marine sediments. Geochem Geophy Geosy 8:Q02004. https://doi.org/10.1029/2006GC001393
Weltje G, Tjallingii R (2008) Calibration of XRF core scanners for quantitative geochemical logging of sediment cores: theory and application. Earth Planet Sci Lett 274:423–438. https://doi.org/10.1016/j.epsl.2008.07.054
Wu J, Liu Z, Zhou C (2013) Provenance and supply of Fe-enriched terrigenous sediments in the western equatorial Pacific and their relation to precipitation variations during the late Quaternary. Global Planet Change 108:56–71. https://doi.org/10.1016/j.gloplacha.2013.06.002
Acknowledgements
We thank the participants of the cruise HI-17-16 on the R/V ISABU for their support. This work was supported by a grant from the National Research Foundation of Korea (Ministry of Science and ICT; Grant no. 2019R1A2C2004951) and grants from the Korea Institute of the Ocean Science and Technology (Grant no. PE99982 and PE99582) awarded to K.E. Lee.
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Lee, I.T., Ko, T.W., Lee, K.E. et al. Calibration of the XRF-Estimated CaCO3 Content in the Western Tropical Pacific Deep-Sea Sediments. Ocean Sci. J. 57, 357–364 (2022). https://doi.org/10.1007/s12601-022-00061-3
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DOI: https://doi.org/10.1007/s12601-022-00061-3