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Controlling hydrogenation of C=C and C=O bonds in cinnamaldehyde using Pt1/Ni and Pt1/Co single-atom alloy catalysts

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概要

由于肉桂醛分子中的两个不饱和官能团具有复杂的共轭体系，因此选择性氢化肉桂醛分子中的C=C和C=O键以生成所需产物是一项具有挑战性的工作。在本研究中，我们利用了一种简单的球磨法合成Pt基单原子合金催化剂，这种催化剂可作为氢化肉桂醛生成高附加值产物的选择性控制器。具体而言，Pt1/Ni单原子合金催化剂表现出优异的氢化肉桂醛选择性（约82.3%），而 Pt1/Co单原子合金催化剂则表现出较高的肉桂醇选择性（约71.2%）。详细的表征结果表明，不同的产物选择性是由于Ni和Co固有的电子特性，以及它们与Pt物种的相互作用，从而导致肉桂醛分子在Pt1/Ni（平行模式）和Pt1/Co（垂直模式）单原子合金催化剂上的不同吸附构型。此外，Pt和载体之间的协同效应增强了反应活性。这项工作为合理设计用于选择性氢化α,β-不饱和醛的单原子合金催化剂提供了启示。

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Acknowledgements

This study was financially supported by the National key Research and Development Program Nanotechnology Specific Project (No. 2020YFA0210900), the Science and Technology Key Project of Guangdong Province, China (No. 2020B010188002), Guangdong Natural Science Funds for Distinguished Young Scholar (No. 2022B1515020035), Guangdong Provincial Key R&D Programme (No. 2019B110206002), the National Natural Science Foundation of China (Nos. 22078371, 21938001 and 21961160741), Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (No. 2017BT01C102), the NSF of Guangdong Province (No. 2020A1515011141), the Science and Technology Project of Guangzhou City, China (No. 202102020461) and Special funding for “Guangxi Bagui Scholars”.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Guangxi University, Nanning, 530004, China

    Huan-Shi Lan, Yi-Da Yang, Qian He, Ran Chen & Hong-Bing Ji

  2. Key Laboratory of Bioinorganicand Synthetic Chemistry of Ministry of Education, Fine Chemical Industry Research Institute, School of Chemistry, IGCME, Sun Yat-sen University, Guangzhou, 510275, China

    Huan-Shi Lan, Qing-Di Sun, Hao Zhang, Ying Zhang, Xiao-Hui He & Hong-Bing Ji

  3. UBFC, CNRS, ENSMM, FEMTO-ST Institute, 25030, Besançon CEDEX, France

    Yi-Da Yang

  4. College of Chemistry and Materials Science, Hebei University, Baoding, 071002, China

    Guo-Yi Bai

  5. State Key Laboratory Breeding Base of Green-Chemical Synthesis Technology, Institute of Green Petroleum Processing and Light Hydrocarbon Conversion, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, China

    Hong-Bing Ji

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  1. Huan-Shi Lan
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Lan, HS., Yang, YD., Sun, QD. et al. Controlling hydrogenation of C=C and C=O bonds in cinnamaldehyde using Pt1/Ni and Pt1/Co single-atom alloy catalysts. Rare Met. 43, 2859–2868 (2024). https://doi.org/10.1007/s12598-024-02672-2

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