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Oxidation behavior of Al0.2CoCrFeNi high-entropy alloy film in supercritical water environment

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摘要

本文通过磁控溅射技术制备了Al0.2CoCrFeNi高熵合金薄膜, 研究了其组织结构并与Al0.2CoCrFeNi高熵合金块体材料以及G115合金的腐蚀性能进行对比。结果表明, Al0.2CoCrFeNi高熵合金薄膜为纳米晶结构, 薄膜内含单一的FCC相。Al0.2CoCrFeNi高熵合金薄膜和块体材料的电化学腐蚀能力均高于G115合金。薄膜在超临界环境 (650 °C, 25 MPa) 下腐蚀12 h后的氧化物由外层的NiO和内层的NiFe2O4组成。NiFe2O4连续致密, 能够有阻止氧扩散, 提高合金抗氧化腐蚀性能。

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Acknowledgements

This work was financially supported by the National Key Research and Development Program of China (Nos. 2016YFB0600103 and 2016YFB0600102). Thanks to the State Key Laboratory of Multiphase Flow at Xi'an Jiaotong University for providing supercritical corrosion equipment and assistance for this research.

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Authors and Affiliations

  1. GRIMAT Engineering Institute Co., Ltd, Beijing, 101407, China

    Bao-Hong Zhu, Hao-Chen Qiu, Wei Jiang & Qing-He Yu

  2. General Research Institute for Nonferrous Metals, Beijing, 100088, China

    Bao-Hong Zhu, Hao-Chen Qiu, Wei Jiang & Qing-He Yu

  3. National Engineering Research Center of Nonferrous Metals Materials and Products for New Energy, GRINM Group Co., Ltd., Beijing, 100088, China

    Qing-He Yu

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  1. Bao-Hong Zhu
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Zhu, BH., Qiu, HC., Jiang, W. et al. Oxidation behavior of Al0.2CoCrFeNi high-entropy alloy film in supercritical water environment. Rare Met. 41, 1217–1222 (2022). https://doi.org/10.1007/s12598-021-01859-1

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