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Green corrosion inhibitors intercalated Mg:Al layered double hydroxide coatings to protect Mg alloy

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Abstract

Mg alloy was protected with Mg:Al layered double hydroxide (LDH) coating intercalated with three green corrosion inhibitors (sodium benzoate, 3-aminopropyltriethoxysilane and 8-hydroxyquinoline). The in-situ hydrothermal approach was adopted to intercalate corrosion inhibitors into Mg:Al LDH coating. The intercalated Mg:Al LDH coating was successfully acquired, and the crystalline structure of Mg:Al LDH coating was verified with X-ray diffraction (XRD). The organic functional groups of corrosion inhibitors were identified with the help of Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). The compact and uniform morphology was confirmed by scanning electron microscopy (SEM). The electrochemical measurement revealed better corrosion resistance of corrosion inhibitor-intercalated Mg:Al LDH coatings as compared to that of pristine Mg alloy. The corrosion protection mechanism of corrosion inhibitors was described and unearthed the corrosion inhibitor with the best performance.

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References

  1. Luo AA. Applications: aerospace, automotive and other structural applications of magnesium. In: Pekguleryuz MO, Kainer K, Kaya AA, editors. Fundamentals of Magnesium Alloy Metallurgy. Cambridge: Woodhead Publishing; 2013. 266.

    Google Scholar 

  2. Herzberg E. Assessing the cost of corrosion to the aerospace industry. In: Benavides S, editor. Corrosion Control in the Aerospace Industry. Cambridge: Woodhead Publishing; 2009. 17.

    Google Scholar 

  3. Luo AA, Sachdev AK. Applications of magnesium alloys in automotive engineering. In: Bettles C, Barnett M, editors. Advances in Wrought Magnesium Alloys. Cambridge: Woodhead Publishing; 2012. 393.

    Google Scholar 

  4. Monteiro WA, Buso SJ, da Silva LV. Application of magnesium alloys in transport. In: Monteiro WA, editor. New Features on Magnesium Alloys. Rijeka: IntechOpen; 2012. 161.

    Google Scholar 

  5. Shimizu Y, Yamamoto A, Mukai T, Shirai Y, Kano M, Kudo T, Kanetaka H, Kikuchi M. Medical application of magnesium and its alloys as degradable biomaterials. In: Proceedings of the Interface Oral Health Science 2009, Tokyo; 2010. 318.

  6. Perejón A, Sánchez-Jiménez PE, Criado JM, Pérez-Maqueda LA. Magnesium hydride for energy storage applications: the kinetics of dehydrogenation under different working conditions. J. Alloys Compd. 2016;681:571.

    Google Scholar 

  7. Blawert C, Hort N, Kainer K. Automotive applications of magnesium and its alloys. Trans Indian Inst Met. 2004;57(4):397.

    CAS  Google Scholar 

  8. Xie ZH, Li D, Skeete Z, Sharma A, Zhong CJ. Nanocontainer-enhanced self-healing for corrosion-resistant Ni coating on Mg alloy. ACS Appl Mater Interfaces. 2017;9(41):36247.

    CAS  Google Scholar 

  9. Peng F, Wang D, Tian Y, Cao H, Qiao Y, Liu X. Sealing the pores of PEO coating with Mg–Al layered double hydroxide: enhanced corrosion resistance, cytocompatibility and drug delivery ability. Sci. Rep. 2017;7(1):8167.

    Google Scholar 

  10. Rives V. Layered Double Hydroxides: Present and Future. New York: Nova Publishers; 2001. 1.

    Google Scholar 

  11. Yao QS, Li ZC, Qiu ZM, Zhang F, Chen XB, Chen DC, Guan SK, Zeng RC. Corrosion resistance of Mg(OH)2/Mg–Al-layered double hydroxide coatings on magnesium alloy AZ31: influence of hydrolysis degree of silane. Rare Met. 2019;38(7):629.

    CAS  Google Scholar 

  12. Zhang Y, Li Y, Ren Y, Wang H, Chen F. Double-doped LDH films on aluminum alloys for active protection. Mater Lett. 2017;192:33.

    CAS  Google Scholar 

  13. Anjum MJ, Zhao J, Zahedi Asl V, Yasin G, Wang W, Wei S, Zhao Z, Qamar Khan W. In-situ intercalation of 8-hydroxyquinoline in Mg–Al LDH coating to improve the corrosion resistance of AZ31. Corros Sci. 2019;157:1.

    CAS  Google Scholar 

  14. Guo L, Wu W, Zhou Y, Zhang F, Zeng R, Zeng J. Layered double hydroxide coatings on magnesium alloys: a review. J Mater Sci Technol. 2018;34(9):1455.

    Google Scholar 

  15. Zhang F, Liu ZG, Zeng RC, Li SQ, Cui HZ, Song L, Han EH. Corrosion resistance of Mg–Al-LDH coating on magnesium alloy AZ31. Surf Coat Technol. 2014;258:1152.

    CAS  Google Scholar 

  16. Geetanjali M, Barsha D, Diptipriya S, Sony P, Mishra BK. Orientation of organic anions in Zn–Al layered double hydroxides with enhanced antibacterial property. Environ Eng Sci. 2017;34(7):516.

    Google Scholar 

  17. Zeng RC, Li XT, Liu ZG, Zhang F, Li SQ, Cui HZ. Corrosion resistance of Zn–Al layered double hydroxide/poly (lactic acid) composite coating on magnesium alloy AZ31. Front. Mater. Sci. 2015;9(4):355.

    Google Scholar 

  18. Nakamura K, Tsunakawa M, Shimada Y, Serizawa A, Ishizaki T. Formation mechanism of Mg–Al layered double hydroxide-containing magnesium hydroxide films prepared on Ca-added flame-resistant magnesium alloy by steam coating. Surf Coat Technol. 2017;328:436.

    CAS  Google Scholar 

  19. Zhang G, Wu L, Tang A, Ma Y, Song GL, Zheng D, Jiang B, Atrens A, Pan F. Active corrosion protection by a smart coating based on a MgAl-layered double hydroxide on a cerium-modified plasma electrolytic oxidation coating on Mg alloy AZ31. Corros Sci. 2018;139:370.

    CAS  Google Scholar 

  20. Wu L, Yang D, Zhang G, Zhang Z, Zhang S, Tang A, Pan F. Fabrication and characterization of Mg–M layered double hydroxide films on anodized magnesium alloy AZ31. Appl Surf Sci. 2018;431:177.

    CAS  Google Scholar 

  21. Zhang F, Zhang C, Zeng R, Song L, Guo L, Huang X. Corrosion resistance of the superhydrophobic Mg(OH)2/Mg–Al layered double hydroxide coatings on magnesium alloys. Metals. 2016;6(4):85.

    CAS  Google Scholar 

  22. Zeng RC, Liu ZG, Zhang F, Li SQ, He QK, Cui HZ, Han EH. Corrosion resistance of in situ Mg–Al hydrotalcite conversion film on AZ31 magnesium alloy by one-step formation. Trans Nonferrous Met Soc China. 2015;25(6):1917.

    CAS  Google Scholar 

  23. Liu Y, Yu T, Cai R, Li Y, Yang W, Caro J. One-pot synthesis of NiAl–CO3 LDH anti-corrosion coatings from CO2-saturated precursors. RSC Adv. 2015;5(37):29552.

    CAS  Google Scholar 

  24. Buchheit RG, Guan H, Mahajanam S, Wong F. Active corrosion protection and corrosion sensing in chromate-free organic coatings. Prog Org Coat. 2003;47(3):174.

    CAS  Google Scholar 

  25. Wang X, Li L, Xie ZH, Yu G. Duplex coating combining layered double hydroxide and 8-quinolinol layers on Mg alloy for corrosion protection. Electrochim Acta. 2018;283:1845.

    CAS  Google Scholar 

  26. Zeng RC, Liu ZG, Zhang F, Li SQ, Cui HZ, Han EH. Corrosion of molybdate intercalated hydrotalcite coating on AZ31 Mg alloy. J. Mater. Chem. A. 2014;2(32):13049.

    CAS  Google Scholar 

  27. Zheludkevich ML, Poznyak SK, Rodrigues LM, Raps D, Hack T, Dick LF, Nunes T, Ferreira MGS. Active protection coatings with layered double hydroxide nanocontainers of corrosion inhibitor. Corros Sci. 2010;52(2):602.

    CAS  Google Scholar 

  28. Guo L, Zhang F, Lu JC, Zeng RC, Li SQ, Song L, Zeng JM. A comparison of corrosion inhibition of magnesium aluminum and zinc aluminum vanadate intercalated layered double hydroxides on magnesium alloys. Front. Mater. Sci. 2018;12(2):198.

    Google Scholar 

  29. Li D, Wang F, Yu X, Wang J, Liu Q, Yang P, He Y, Wang Y, Zhang M. Anticorrosion organic coating with layered double hydroxide loaded with corrosion inhibitor of tungstate. Prog Org Coat. 2011;71(3):302.

    CAS  Google Scholar 

  30. Li L, Pan F, Lei J. Environmental friendly corrosion inhibitors for magnesium alloys. In: Czerwinski F, editor. Magnesium Alloys-Corrosion and Surface Treatments. Rijeka: InTech; 2011. 47.

    Google Scholar 

  31. Neupane MP, Lee SJ, Kang JY, Park IS, Bae TS, Lee MH. Surface characterization and corrosion behavior of silanized magnesium coated with graphene for biomedical application. Mater Chem Phys. 2015;163:229.

    CAS  Google Scholar 

  32. Obot IB, Ankah NK, Sorour AA, Gasem ZM, Haruna K. 8-Hydroxyquinoline as an alternative green and sustainable acidizing oilfield corrosion inhibitor. Sustain. Mater. Technol. 2017;14:1.

    CAS  Google Scholar 

  33. Zhang W, Pan FS, Yang MB, Zhang J, Wen T. Influence of KH-550 silane treatment on the corrosion resistance of AZ31 magnesium alloy. In: Proceedings of the Materials Science Forum; 2009. 927.

  34. Wu L, Wu J, Zhang Z, Zhang C, Zhang Y, Tang A, Li L, Zhang G, Zheng Z, Atrens A, Pan F. Corrosion resistance of fatty acid and fluoroalkylsilane-modified hydrophobic Mg–Al LDH films on anodized magnesium alloy. Appl Surf Sci. 2019;487:569.

    CAS  Google Scholar 

  35. Kaseem M, Ko YG. Benzoate intercalated Mg–Al-layered double hydroxides (LDHs) as efficient chloride traps for plasma electrolysis coatings. J. Alloys Compd. 2019;787:772.

    CAS  Google Scholar 

  36. Li Y, Tang L, Ma X, Wang X, Zhou W, Bai D. Synthesis and characterization of Zn–Ti layered double hydroxide intercalated with cinnamic acid for cosmetic application. J Phys Chem Solids. 2017;107:62.

    Google Scholar 

  37. Xu S, Yu J, Wu W, Xue L, Sun Y. Synthesis and characterization of layered double hydroxides intercalated by UV absorbents and their application in improving UV aging resistance of bitumen. Appl Clay Sci. 2015;114:112.

    CAS  Google Scholar 

  38. Zhang Q, Gao F, Zhang C, Wang L, Wang M, Qin M, Hu G, Kong J. Enhanced dielectric tunability of Ba0.6Sr0.4TiO3/poly(vinylidene fluoride) composites via interface modification by silane coupling agent. Compos. Sci. Technol. 2016;129:93.

    CAS  Google Scholar 

  39. Wei B, Chang Q, Bao C, Dai L, Zhang G, Wu F. Surface modification of filter medium particles with silane coupling agent KH550. Colloids Surf A. 2013;434:276.

    CAS  Google Scholar 

  40. Li M, Liu N, Chen J, Li Q. Simple construction based on epoxy-bonded super-hydrophobic anti-corrosion coating. J. Taiwan Inst. Chem. Eng. 2019;95:682.

    CAS  Google Scholar 

  41. Gao H, Li Q, Dai Y, Luo F, Zhang H. High efficiency corrosion inhibitor 8-hydroxyquinoline and its synergistic effect with sodium dodecylbenzenesulphonate on AZ91D magnesium alloy. Corros Sci. 2010;52(5):1603.

    CAS  Google Scholar 

  42. Ottosson N, Romanova AO, Söderström J, Björneholm O, Öhrwall G, Fedorov MV. Molecular sinkers: X-ray photoemission and atomistic simulations of benzoic acid and benzoate at the aqueous solution/vapor interface. J. Phys. Chem. B. 2012;116(43):13017.

    CAS  Google Scholar 

  43. Wagner C, Passoja D, Hillery H, Kinisky T, Six H, Jansen W, Taylor J. Auger and photoelectron line energy relationships in aluminum–oxygen and silicon–oxygen compounds. J. Vac. Sci. Technol. 1982;21(4):933.

    CAS  Google Scholar 

  44. Zhao J, Duan H, Jiang R. Synergistic corrosion inhibition effect of quinoline quaternary ammonium salt and Gemini surfactant in H2S and CO2 saturated brine solution. Corros Sci. 2015;91:108.

    CAS  Google Scholar 

  45. Brug G, Van Den Eeden A, Sluyters-Rehbach M, Sluyters J. The analysis of electrode impedances complicated by the presence of a constant phase element. J Electroanal Chem Interfacial Electrochem. 1984;176(1–2):275.

    CAS  Google Scholar 

  46. Gong F, Shen J, Gao R, Xie X, Luo X. Enhanced corrosion resistance of magnesium alloy by a silane-based solution treatment after an in situ formation of the Mg(OH)2 layer. Appl Surf Sci. 2016;365:268.

    CAS  Google Scholar 

  47. Bährle-Rapp M. Magnesium benzoate. In: Bährle-Rapp M, editor. Springer Lexikon Kosmetik und Körperpflege. Berlin: Springer; 2007. 335.

    Google Scholar 

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Acknowledgements

This study was financially supported by the National Natural Science Foundation of China (No. 51471021).

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Authors and Affiliations

  1. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, China

    Muhammad Junaid Anjum, Jing-Mao Zhao, Vahdat Zahedi Asl, Muhammad Uzair Malik & Ghulam Yasin

  2. Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing, 100029, China

    Jing-Mao Zhao

  3. Institute of Advanced Materials, Bahauddin Zakariya University, Multan, 60800, Pakistan

    Waheed Qamar Khan

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  1. Muhammad Junaid Anjum
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Correspondence to Jing-Mao Zhao.

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Anjum, M.J., Zhao, JM., Asl, V.Z. et al. Green corrosion inhibitors intercalated Mg:Al layered double hydroxide coatings to protect Mg alloy. Rare Met. 40, 2254–2265 (2021). https://doi.org/10.1007/s12598-020-01538-7

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  • DOI: https://doi.org/10.1007/s12598-020-01538-7

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