Abstract
La2Ce2O7 (LCO) is a promising candidate for thermal barrier coatings (TBCs) due to that it provides better thermal insulation than yttria-stabilized zirconia (YSZ) does. In this work, a TBC LCO was produced by solution precursor plasma spraying (SPPS). After the solution precursors were prepared and the spraying parameters were optimized, the thermophysical properties and thermal shock performance of the coatings were tested. It was found that the SPPS coating with segmentation crack density of 6 mm−1 had the porosities of about 33.5% at spray distances of 35 mm. The thermal conductivity of the SPPS coatings is 0.50–0.75 W·m−1·K−1, much lower than that of the atmospheric plasma spraying (APS) coatings (0.85–1.25 W·m−1·K−1). The thermal shock performance of the SPPS coatings reached 60 cycles, much better than the APS coatings. This improvement is due to the segmentation cracks in the coatings, which can improve strain tolerance and effectively relieve internal stress. This study provides reference significance for further research on thermal barrier coatings.
Similar content being viewed by others
References
Teixeira V, Andritschky M, Gruhn H, Malléner W, Buchkremer HP, Stöver D. Failure of physical vapor deposition/plasma-sprayed thermal barrier coatings during thermal cycling. Rare Met. 2000;9(2):191.
Clarke DR, Phillpot SR. Thermal barrier coating materials. Mater Today. 2005;8(6):22.
Krogstad JA, Leckie RM, Krämer S, Cairney JM, Lipkin DM, Johnson CA, Levi CG. Phase evolution upon aging of air plasma sprayed t’-Zirconia coatings: I-microstructure evolution. J Am Ceram Soc. 2013;96(1):299.
Padture NP, Gell M, Jordan EH. Thermal barrier coatings for gas-turbine engine applications. Science. 2002;296(5566):280.
Cao XQ, Vassen R, Fischer W, Tietz F, Jungen W, Stover D. Lanthanum–cerium oxide as a thermal barrier-coating material for high-temperature applications. Adv Mater. 2003;15(17):1438.
Wang Y, Li MX, Suo HL. Mechanical properties of YSZ thermal barrier coatings with segmented structure. Surf Eng. 2012;28(5):329.
Nelson WA, Orenstein RM. TBC experience in land-based gas turbines. J Therm Spray Technol. 1997;6(2):176.
Ma W, Hong HB, Gong SK, Dong HY. Lanthanum-cerium oxide thermal barrier coatings prepared by atmospheric plasma spraying. J Inorgan Mater. 2009;24(5):983.
Ganvir A, Curry N, Govindarajan S, Markocson N. Characterization of thermal barrier coatings produced by various thermal spray techniques using solid powder, suspension, and solution precursor feedstock material. Int J Appl Ceram Technol. 2016;13(2):324.
Markocsan N, Gupta M, Joshi S, Nylen P. Liquid feedstock plasma spraying: an emerging process for advanced thermal barrier coatings. J Therm Spray Technol. 2017;26(6):1104.
Wang Y, Guo HB, Gong SK. Thermal shock resistance and mechanical properties of La2Ce2O7 thermal barrier coatings with segmented structure. Ceram Int. 2009;35(7):2639.
Khan M, Hu NN, Lan ZH, Wang YZ, Yi Z. Influence of solution-precursor plasma spray (SPPS) processing parameters on the mechanical and thermodynamic properties of 8 YSZ. Ceram Int. 2018;44(7):7794.
Chen J, Jordan EH, Harris AB, Gell M, Roth J. Double-layer gadolinium zirconate/yttria-stabilized zirconia thermal barrier coatings deposited by the solution precursor plasma spray process. J Therm Spray Technol. 2015;24(6):895.
Gell M, Wang JW, Kumar R, Roth J, Chen J, Jordan EH. Higher temperature thermal barrier coatings with the combined use of yttrium aluminum garnet and the solution precursor plasma spray process. J Therm Spray Technol. 2018;27(4):543.
Virendra S, Robert D, Sudipta S. Effect of processing parameters on cerium oxide coating deposition in solution precursor plasma spray. J Am Ceram Soc. 2013;96(8):2437.
Kindole D, Anyadiegwu I, Ando Y, Noda Y, Nishiyama H, Uehara S, Nakajima T, Solonenko OP, Smirnov AV, Golovin AA. Rapid deposition of photocatalytically enhanced TiO2 film by atmospheric SPPS using Ar/N2-vortex plasma jet. Mater Trans. 2018;59(3):462.
Li XH, Ma W, Wen J, Bai Y, Sun L, Chen BD, Dong HY, Shuang YC. Preparation of SrZrO3 thermal barrier coating by solution precursor plasma spray. J Therm Spray Technol. 2017;26(3):371.
Xie LD, Jordan EH, Padture NP, Gell M. Phase and microstructural stability of solution precursor plasma sprayed thermal barrier coatings. Mater Sci Eng, A. 2004;381(1):189.
Wang R, Duan JH, Ye FX. Effect of spraying parameters on the crystallinity and microstructure of solution precursor plasma sprayed coatings. J Alloy Compd. 2018;766(25):886.
Guo HB, Wang Y, Wang L, Gong SK. Thermo-physical properties and thermal shock resistance of segmented La2Ce2O7/YSZ thermal barrier coatings. J Therm Spray Technol. 2009;18(4):665.
Liang B, Ding CX. Microstructure of nanostructure zirconia coating and its thermal shock resistance. J Inorgan Mater. 2006;21(1):250.
Liu Q, Hu YF, Xiong JJ. Experimental study on porosity measurement of graphite porous material. Lubr Eng. 2010;25(10):99.
Liu PS. Determining methods for porosity of porous materials. Titan Ind Prog. 2005;22(6):34.
Kamseu E, Ngouloure ZNM, Ali BN, Zekeng S, Meloa UC, Rossignol S, Leonelli C. Cumulative pore volume, pore size distribution and phases percolation in porous inorganic polymer composites: relation microstructure and effective thermal conductivity. Energy Build. 2015;88(1):45.
Rätzer-Scheibe HJ, Schulz U. The effects of heat treatment and gas atmosphere on the thermal conductivity of APS and EB-PVD PYSZ thermal barrier coatings. Surf Coat Technol. 2007;201(18):7880.
Khan M, Hu NN, Lan ZH, Zhang Y, Zeng Y. Influence of solution-precursor plasma spray (SPPS) processing parametersOn the mechanical and thermodynamic properties of 8 YSZ. Ceram Int. 2018;44(7):7794.
Erich J, Chen J, Jeffrey R, Maurice G. Low thermal conductivity yttria-stabilized zirconia thermal barrier coatings using the solution precursor plasma spray process. J Therm Spray Technol. 2014;23(5):849.
Song XM, Liu ZW, Suhonen T, Varis T, Huang LP, Zheng XB, Zeng Y. Effect of melting state on the thermal shock resistance and thermal conductivity of APS ZrO2-7.5 wt% Y2O3 coatings. Surf Coat Technol. 2015;270(25):132.
Khan M, Zeng Y, Hu NN, Lan ZH, Wang YZ. Optimizing the structure and properties of Y2O3 stabilized zirconia: an atmospheric plasma spray (APS) and solution precursor plasma spray (SPPS) based comparative study. Ceram Int. 2018;44(15):18135.
Wang Y, Guo HB, Li ZY, Gong SK. Segmented lanthanum cerium oxide thermal barrier coatings by atmospheric plasma spray. Surf Eng. 2009;25(7):555.
Keyvani A, Saremi M, Heydarzadeh Sohi M, Valefi Z. A comparison on thermomechanical properties of plasma-sprayed conventional and nanostructured YSZ TBC coatings in thermal cycling. J Alloy Compd. 2012;541(15):488.
Acknowledgments
This study was financially supported by the National Natural Science Foundation of China (Nos. 51571002 and 51401003) and Beijing Municipal Natural Science Foundation (Nos. 2172008 and KZ201310005003).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Feng, BB., Wang, Y., Jia, Q. et al. Thermophysical properties of solution precursor plasma-sprayed La2Ce2O7 thermal barrier coatings. Rare Met. 38, 689–694 (2019). https://doi.org/10.1007/s12598-019-01286-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12598-019-01286-3