Abstract
Co3O4 microspheres were synthesized in mass production by a simple hydrothermal treatment using trisodium citrate as a template. The pristine, discharged and recharged specimens were characterized by XRD, SEM and Raman spectroscopy measurements. The electrochemical behavior was studied by CV curves of Co3O4 at various scan rates in LiOH solution. Co3O4 particles underwent a reversible insertion of Li+ and H+ ions from LiOH solution. A linear relationship between the peak currents and the square root of scan rates for the redox peak pairs were determined, indicating a diffusion-controlled process of the Li+ deintercalation/intercalation in Co3O4 particles. The diffusion coefficients (D Li +) in anodic and cathodic processes are 2.15 × 10−10 and 9.1 × 10−12 cm2/s, respectively.
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References
Shi X.Y., Han S.B., Sanedrin R.J., Galvez C., Ho D.G., Hernandez B., Zhou F.M., and Selke M., Formation of cobalt oxide nanotubes: Effect of intermolecular hydrogen bonding between Co(III) complex precursors incorporated onto colloidal templates, Nano Lett., 2002, 2: 289.
He T., Chen D.R., Jiao X.L., Xu Y.Y., and Gu Y.X., Surfactant-assisted solvothermal synthesis of Co3O4 hollow spheres with oriented-aggregation nanostructures and tunable particle size, Langmuir, 2004, 20: 8404.
Liu Y., and Zhang X.G., Effect of calcination temperature on the morphology and electrochemical properties of Co3O4 for lithium-ion battery, Electrochim. Acta, 2009, 54: 4180.
Yuan Z.Y., Huang F., Feng C.Q., Sun J.T., and Zhou Y.H., Synthesis and electrochemical performance of nanosized Co3O4, Mater. Chem. Phys., 2003, 79: 1.
Cao A.M., Hu J.S., Liang H.P., Song W.G., Wan L.J., He X.L., Gao X.G., and Xia S.H., Hierarchically structured cobalt oxide (Co3O4): the morphology control and its potential in sensors, J. Phys. Chem. B., 2006, 110: 15858.
Tian B.Z., Liu X.Y., Yang H.F., Xie S.H., Yu C.Z., Tu B., and Zhao D.Y., General synthesis of ordered crystallized metal oxide nanoarrays replicated by microwave-digested mesoporous silica, Adv. Mater., 2003, 15: 1370.
Liu Y., Mi C.H., Su L.H., and Zhang X.G., Hydrothermal Synthesis of Co3O4 Microspheres as anode material for lithium-ion batteries, Electrochem. Acta, 2008, 53: 2507.
Hadjiev V.G., Iliev M.N. and Vergilov I.V., The Raman spectra of Co3O4, J. Phys. C: Solid State Phys., 1988, 21: L199.
Liu H.C., and Yen S.K., Characterization of electrolytic Co3O4 thin films as anodes for lithium-ion batteries, J. Power Sources, 2007, 166(2): 478.
Su L.H., Zhang X.G., Mi C.H., and Liu Y., Insights into the electrochemistry of layered double hydroxide containing cobalt and aluminum elements in lithium hydroxide aqueous solution, J. Power Sources, 2008, 179: 388.
Mockenhaupt Ch., Zeiske Th., and Lutz H.D., Crystal structure of brucite-type cobalt hydroxide β-Co(OH)2-neutron diffraction, IR and Raman spectroscopy, J. Molecular Structure 1998, 443: 191.
Song S.W., Han K.S., Sasagawa I., Watanabe T., and Yoshimura M., Effect of LiOH concentration change on simultaneous preparation of LiCoO2 film and powder by hydrothermal method, Solid State Ionics, 2000, 135: 277.
Rao M.M., Jayalakshmi M., Schaf O., Wulff H., Guth U., and Scholz F., Electrochemical behaviour of solid lithium cobaltate (LiCoO2) and lithium manganate (LiMn2O4) in an aqueous electrolyte system, J. Solid State Electr., 2001, 5: 50
Bard A.J. and Faulkner L.R., Electrochemical Methods: Fundamentals and Applications, second ed., John Wiley and Sons, New York, 2001.
Liu Y., Mi C.H., Yuan C.Z., and Zhang X.G., Improvement of electrochemical and thermal stability of LiFePO4 cathode modified by CeO2, J. Electroanal. Chem., 2009, 628: 73.
Rho Y.H., and Kanamura K., Fabrication of thin film electrodes for all solid state rechargeable lithium batteries, J. Electroanal. Chem., 2003, 559: 69.
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Liu, Y., Zhang, X. & Wu, Y. Electrochemical behavior of Co3O4 microspheres in aqueous LiOH solution. Rare Metals 30 (Suppl 1), 90–93 (2011). https://doi.org/10.1007/s12598-011-0245-1
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DOI: https://doi.org/10.1007/s12598-011-0245-1