Abstract
The electrochemical properties of Ni(OH)2/CNTs prepared by electrochemical deposition were investigated in this article. The results show that deposits of Ni(OH)2 has high purity and can optimize the electronic and ionic conductivity to minimize the total resistance of the system and maximize the performance characteristics as supercapacitor electrodes. The specific capacitance at a scan rate of 2 mV/s reaches as high as 2486 F/g, which gives the composites potential application as high-performance supercapacitor electrode materials. Meanwhile, the products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM).
Similar content being viewed by others
References
Guo C., Zuo Y., Zhao X.H., Zhao J.M., and Xiong J.P., The effects of electrodeposition current density on properties of Ni-CNTs composite coatings, Surf. Coat. Technol., 2008, 202(14): 3246.
Babakhani B., and Ivey D.G., Anodic deposition of manganese oxide electrodes with rod-like structures for application as electrochemical capacitors, J. Power Sources, 2010, 195(7): 2110.
Kim I.H., Kim J.H., Lee Y.H., and Kim K.B., Synthesis and characterization of electrochemically prepared ruthenium oxide on carbon nanotube film substrate for supercapacitor applications, J. Electrochem. Soc., 2005, 152(11): A2170.
Reddy A.L.M., Shaijumon M.M., Gowda S.R., and Ajayan P.M., Multisegmented Au-MnO2/carbon nanotube hybrid coaxial arrays for high-power supercapacitor applications, J. Phys. Chem. C, 2010, 114(1): 658.
Chang J.K., Wu C.M., and Sun I.W., Nano-architectured Co(OH)2 electrodes constructed using an easily-manipulated electrochemical protocol for high-performance energy storage applications, J. Mater. Chem., 2010, 20(13): 3729.
Justin P., Meher S. K., and Rao G.R., Tuning of capacitance behavior of NiO using anionic, cationic, and nonionic surfactants by hydrothermal synthesis, J. Phys. Chem. C, 2010, 114(11): 5203.
Hu L.B., Pasta Mauro, Mantia F.L., Cui L.F., Jeong S., Deshazer H.D., Choi J.W., Han S.M., and Cui Y., Stretchable, porous, and conductive energy textiles, Nano Lett., 2010, 10(2): 708.
Yang G.W., Xu C.L., and Li H.L., Electrodeposited nickel hydroxide on nickel foam with ultrahigh capacitance, Chem. Commun., 2008, (48): 6537.
Wu M.S., Huang C.Y., and Jow J.J., Electrophoretic deposition of network-like carbon nanofiber as a conducting substrate for nanostructured nickel oxide electrode, Electrochem. Commun., 2009, 11(4): 779.
Nam K.W., Kim K.H., Lee E.S., Yoon W.S., Yang X.Q., and Kim K.B., Pseudocapacitive properties of electrochemically prepared nickel oxides on 3-dimensional carbon nanotube film substrates, J. Power Sources, 2008, 182(2): 642.
Hou Y., Cheng Y.W., Hobson T., and Liu J., Design and synthesis of hierarchical MnO2 nanospheres/carbon nanotubes/conducting polymer ternary composite for high performance electrochemical electrodes, Nano. Lett., 2010, 10(7): 2727.
Dai P.Q., Xu W.C., and Huang Q.Y., Mechanical properties and microstructure of nanocrystalline nickel-carbon nanotube composites produced by electrodeposition, Mater. Sci. Eng.. A, 2008, 483–484: 172.
Nam K.W., Lee C.W., Yang X.Q., Cho B.W., Yoon W.S., and Kim K.B., Electrodeposited manganese oxides on three-dimensional carbon nanotube substrate: Supercapacitive be haviour in aqueous and organic electrolytes, J. Power Sources, 2009, 188(1): 323.
Zhou J.S., Song H.H., Chen X.H., and Huo J.P., Diffusion of metal in a confined nanospace of carbon nanotubes induced by air oxidation, J. Am. Chem. Soc., 2010, 132(33): 11402.
Frackowiak E., and Beguin F., Electrochemical storage of energy in carbon nanotubes and nanostructured carbons, Carbon, 2002, 40(10): 1775.
Lee J.Y., Sung J.H., Jang I.B., Park B.J., and Choi H.J., Electrophoretic response of poly(methyl methacrylate) coated TiO2 nanoparticles, Synthetic Metals, 2005, 153(1–3): 221.
Li G.R., Feng Z.P., Ou Y.N., Wu D.C., Fu R.W., and Tong Y.X., Mesoporous MnO2/carbon aerogel composites as promising electrode materials for high-performance supercapacitors, Langmuir, 2010, 26(4): 2209.
Wang D.C., Pang W.B., Ni H., Lu Q.Y., Huang Z.J., and Zhao J.W., Preparation of mesoporous NiO with a bimodal pore size distribution and application in electrochemical capacitors, Electrochim. Acta, 2010, 55(22): 6830.
Wu M.S., Huang Y.A., Jow J.J., Yang W.D., Hsieh C.Y., and Tsai H.M., On the characteristics of Pd thin films prepared by pulsed laser deposition under different helium pressures, Int. J. Hydrogen Energy, 2008, 33(12): 2921..
Wu M.S., Huang C.Y., and Lin K.H., Electrophoretic deposition of nickel oxide electrode for high-rate electrochemical capacitors, J. Power Sources, 2009, 186(2): 557.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Chai, H., Chen, X., Jia, D. et al. Electrochemical deposition of Ni(OH)2/CNTs electrode as electrochemical capacitors. Rare Metals 30 (Suppl 1), 85–89 (2011). https://doi.org/10.1007/s12598-011-0244-2
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12598-011-0244-2