Skip to main content
Log in

Influence of silane on corrosion resistance of magnesium alloy AZ31 with thermally sprayed aluminum coatings

  • Published:
Rare Metals Aims and scope Submit manuscript

Abstract

Aluminum coatings on Mg alloy AZ31 were fabricated using the thermal spraying technique, and then sealed with silane. The surface morphology and chemical groups were discerned using scanning electron microscopy and examined using Fourier transformation infrared spectroscopy, respectively. The salt fog tests and the potentiodynamic electrochemical technique were applied to evaluate the influence of silane on corrosion of the AZ31 alloy with aluminum coatings. The results showed that the corrosion resistance of the aluminum-coated AZ31 alloy was superior to that of the substrate. The aluminum coating sealed with various silane layers led to a further increase in the corrosion resistance of the alloy. Double silane layers were more corrosion-resistant than the single one. Also, it was no longer significant for more than two silane layers to improve the corrosion resistance. It implied that the optimum choice for silane treatment on the aluminum coatings was two layers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Zeng R.C., Ke W., Xu Y.B., and Han E.H., Recent development and application of magnesium alloys, Acta Metall. Sin. (in Chinese), 2001, 37(7): 673.

    CAS  Google Scholar 

  2. Zeng R.C., Zhang J., Huang W.J., Dietzel W., Kainer K.U., Blawert C., and Ke W., Review of studies on corrosion of magnesium alloys, Trans. Nonferrous Met. Soc. China, 2006, 16(Suppl.1): s763.

    Article  Google Scholar 

  3. Zhou W.Q., Shan D.Y., Han E.H., and Ke W., Structure and formation mechanism of phosphate conversion coating on die-cast AZ91D magnesium alloy, Corros. Sci., 2008, 50(2): 329.

    Article  CAS  Google Scholar 

  4. Zucchi F., Frignani A., Grassi V., Trabanelli G., and Monticelli C., Stannate and permanganate conversion coatings on AZ31 magnesium alloy, Corros. Sci., 2007, 49(12): 4542.

    Article  CAS  Google Scholar 

  5. Lin C.S., Lin H.C., Lin K.M., and Lai W.C., Formation and properties of stannate conversion coatings on AZ61 magnesium alloys, Corros. Sci., 2006, 48(1): 93.

    Article  CAS  Google Scholar 

  6. Ardelean H., Frateur I, and Marcus P., Corrosion protection of magnesium alloys by cerium, zirconium and niobium-based conversion coatings, Corros. Sci., 2008, 50(7): 1907.

    Article  CAS  Google Scholar 

  7. Shi Z.M., Song G.L., and Atrens A., The corrosion performance of anodised magnesium alloys, Corros. Sci., 2006, 48(11): 3531.

    Article  CAS  Google Scholar 

  8. Huang C.A., Wang T.H., Weirich T., and Neubert V., Electrodeposition of a protective copper/nickel deposit on the magnesium alloy (AZ31), Corros. Sci., 2008, 50(5): 1385.

    Article  CAS  Google Scholar 

  9. Gray J.E. and Luan B., Protective coatings on magnesium and its alloys-a critical review, J. Alloys Compd., 2002, 336(1–2): 88.

    Article  CAS  Google Scholar 

  10. Jun Y., Sun G.P., Wang H.Y., Jia S.Q., and Jia S.S., Laser (Nd:YAG) cladding of AZ91D magnesium alloys with Al + Si + Al2O3, J. Alloys Compd., 2006, 40(1–2): 201.

    Article  Google Scholar 

  11. Zhu L.Q. and Song G.L., Improved corrosion resistance of AZ91D magnesium alloy by an aluminum-alloyed coating, Surf. Coat. Technol., 2006, 200(8): 2834.

    Article  CAS  Google Scholar 

  12. Chiu L.H., Chen C.C., and Yang C.F., Improvement of corrosion properties in an aluminum-sprayed AZ31 magnesium alloy by a post-hot pressing and anodizing treatment, Surf. Coat. Technol., 2005, 191(2–3): 181.

    Article  CAS  Google Scholar 

  13. Pokhmurskaa H., Wielagea B., Lampkea T., Grunda T., Studentb M., and Chervinska N., Post-treatment of thermal spray coatings on magnesium, Surf. Coat. Technol., 2008, 202(18): 4515.

    Article  Google Scholar 

  14. Zhang J., Wang Y., Zeng R.C., and Huang W.J., Effects of post heat treatment on the interfacial characteristics of aluminum coated AZ91D magnesium alloy, Mater. Sci. Forum, 2007, 546–549: 529.

    Article  Google Scholar 

  15. Van Ooij W.J., Zhu D., Stacy M., Seth A., Mugada T., Gandhi J., and Puomi P., Corrosion protection properties of or-ganofunctional silanes-An overview, Tsinghua Sci. Technol., 2005, 10(6): 639.

    Article  Google Scholar 

  16. Zucchi F., Grassi V., Frignani A., Monticelli C., and Trabanelli G., Influence of a silane treatment on the corrosion resistance of a WE43 magnesium alloy, Surf. Coat. Technol., 2006, 200(12–13): 4136.

    Article  CAS  Google Scholar 

  17. Deflorian F., Rossi S., and Fedrizzi L., Silane pre-treatments on copper and aluminium, Electrochem. Acta, 2006, 51(27): 6097.

    Article  CAS  Google Scholar 

  18. Chen M.A., Yang X., Zhang X.M., Li H.Z., Lu X.B., and Liu C.R., Structure and corrosion resistance of self-assembled sulf-silane film on surface of Mg-Gd-Y-Zr alloy, Chin. J. Nonferrous Met. (in Chinese), 2008, 18: 24.

    Article  Google Scholar 

  19. Zhang J., Wu C.Y, Huang F.X., and Zhang W., Surface treatment on the AZ31B magnesium alloys by silane, J. Chin. Soc. Corros. Prot. (in Chinese), 2008, 28(3): 146.

    MATH  Google Scholar 

  20. Gao Y., Xu X., Yan Z., and Xin G., High hardness alumina coatings prepared by low power plasma spraying, Surf. Coat. Technol., 2002, 154(2–3): 189.

    Article  CAS  Google Scholar 

  21. Shan F.J., Liu C.S., Wang S.H., and Qi G.C., Corrosion resistance of hot dip galvanized steel pretreated with bis-functional silanes modified with nanoalumina, Acta Metall. Sin., 2008, 21(4): 245.

    CAS  Google Scholar 

  22. Mohseni M., Mirabedini M., Hashemi M., and Thompson G.E., Adhesion performance of an epoxy clear coat on aluminum alloy in the presence of vinyl and amino-silane primers, Prog. Org. Coat., 2006, 57(4): 307.

    Article  CAS  Google Scholar 

  23. Zand B.N. and Mahdaian M., Evaluation of the effect of vinyltrimethoxysilane on corrosion resistance and adhesion strength of epoxy coated AA1050, Electrochim. Acta, 2007, 52(23): 6438.

    Article  CAS  Google Scholar 

  24. Zeng R.C., Han E.H., and Ke W., Corrosion of artificial aged magnesium alloy AZ80 in 3.5 wt.% NaCl solution, J. Mater. Sci. Technol., 2007, 23(3): 363.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rongchang Zeng.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zeng, R., Chen, J., Kuang, J. et al. Influence of silane on corrosion resistance of magnesium alloy AZ31 with thermally sprayed aluminum coatings. Rare Metals 29, 193–197 (2010). https://doi.org/10.1007/s12598-010-0033-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12598-010-0033-3

Keywords

Navigation