Abstract
The effects of trace Sc, Zr, and Ti on the microstructure and hardness of Al alloys with high Mg content (Al-6Mg, Al-8Mg, and Al-10Mg) were studied by optical microscope, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Brinell hardness. The grain size of the as-cast alloys was refined by the addition of Sc and Zr, and it was further refined by the addition of Ti. With the same contents of Sc, Zr, and Ti, an increase in Mg content was beneficial to the refinement due to the solution of Mg into α-Al. The refined microstructures of the as-cast alloys were favorable for Brinell hardness. Addition of Sc, Zr, and Ti to the Al-10Mg alloy results in the improvement of peak hardness and it is about 45% higher than that of the Al-10Mg alloy, which is due to fine precipitations of Al3(Sc1−x Zr x ), Al3(Sc1−x Ti x ), and Al3(Sc1−x−y Zr x Ti y ).
Similar content being viewed by others
References
Yin Z., Pan Q., Zhang Y., and Jiang F., Effect of minor Sc and Zr on the microstructure and mechanical properties of Al-Mg based alloys, Mater. Sci. Eng. A, 2000, 280: 151.
Singh V., Prasad K.S., and Gokhale A.A., Microstructure and age hardening response of cast Al-Mg-Sc-Zr alloys, J. Mater. Sci., 2004, 39: 2861.
Paglia C.S., Jata K.V., and Buchheit R.G., A cast 7050 friction stir weld with scandium: microstructure corrosion and environmental assisted cracking, Mater. Sci. Eng. A, 2006, 424: 196.
Neubert V., Smola B., Stulíková I., Bakkar A., and Reuter J., Microstructure, mechanical properties and corrosion behaviour of dilute Al-Sc-Zr alloy prepared by powder metallurgy, Mater. Sci. Eng. A, 2007, 464: 358.
Fuller C.B., Seidman D.N., and Dunand D.C., Mechanical properties of Al(Sc,Zr) alloys at ambient and elevated temperatures, Acta. Mater., 2003, 51: 4803.
Zeng F., Xia C., and Gu Y., The isothermal section of the Al-4Mg-Sc-Zr quaternary system in Al-rich range, J. Alloys Compd., 2004, 363: 175.
Prukkanon W., Chanpum S., and Limmaneevichitr C., Effect of Sc on precipitation hardening of AlSi6Mg alloy, J. Mater. Sci. Technol., 2008, 24: 17.
Torma T., Ovacs-Csetenyi E. K., and Turmezey T., Hardening mechanisms in AI-Sc alloys, J. Mater. Sci., 1989, 24: 3924.
Belov N.A., Alabin A.N., Eskin D.G., and Istomin-Kastrovskii V.V., Optimization of hardening of Al-Zr-Sc cast alloys, J. Mater. Sci., 2006, 41: 5890.
van Dalen M.E., Seidman D.N., and Dunand D.C., Creep-and coarsening properties of Al-0.06 at.% Sc-0.06 at.% Ti at 300–450°C, Acta Mater., 2008, 56: 4369.
Kaiser M.S., Datta S., Roychowdhury A., and Banerjee M.K. Effect of Scandium Additions on the Tensile Properties of cast Al-6Mg alloys, J. Mater. Eng. Perform., 2008, 17: 902.
Li Z.J., Liu Z.X., Song M.S., Weng Y.G., Wang M.S., Song T.F., Dong X.P., and Hao H.L. Effect of Sc, Zr, Ti combination alloying on the microstructure and mechanical properties of Al-5Mg Alloy, Chin. Rare Earths (in Chinese), 2006, 27(3): 28.
Roder O., Wirtz T., Gysler A., and Liitjering G., Fatigue properties of Al-Mg alloys with and without scandium, Mater. Sci. Eng. A, 1997, 234: 181.
Hyland R.W., Homogeneous nucleation kinetics of Al3Sc in a dilute Al-Sc alloy, Metall. Trans. A., 1992, 23: 1947.
Nie B., Yin Z., and Zhu D., Effect of homogenization treatment on microstructure and properties of Al-Mg-Mn-Sc-Zr alloy, J. Cent. South. Univ. Technol., 2007, 14: 452.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wang, X., Chen, G., Li, B. et al. Effects of Sc, Zr and Ti on the microstructure and properties of Al alloys with high Mg content. Rare Metals 29, 66–71 (2010). https://doi.org/10.1007/s12598-010-0012-8
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12598-010-0012-8