Abstract
Organic nonlinear optical crystal, l-serine methyl ester hydrochloride (SMEH) with dimensions of 14 × 14 × 8 mm3 was grown by the slow cooling technique. The cell parameters of grown crystal were confirmed by single crystal X-ray diffraction study and it belongs to the noncentrosymmetric space group of P21. Optical transmittance study confirms the optical transparency window in the region between 319 and 900 nm. Density functional theory was carried out to analyse the frontier molecular orbitals of the grown crystal. The load dependent parameters of the grown crystal were studied by Vicker’s microhardness technique. The laser damage threshold value of SMEH crystal was measured to be 0.23 GW/cm2 using a 1064 nm Nd:YAG laser radiation. Optical homogeneity of the grown crystal was analysed by birefringence study using Nd:YAG laser. The relative second harmonic generation efficiency of SMEH crystal was found to be 0.92 times that of KDP.
Similar content being viewed by others
References
K.M. Ok, E.O. Chi, P.S. Halasyamani, Bulk characterization methods for non-centrosymmetric materials: second-harmonic generation, piezoelectricity, pyroelectricity, and ferroelectricity. Chem. Soc. Rev. 35, 710 (2006)
X. Liu, X. Wang, X. Yin, S. Zhang, L. Wang, L. Zhu et al., Characterization and strong piezoelectric response of an organometallic nonlinear optical crystal: CdHg(SCN)4(C2H6SO)2. J. Mater. Chem. C 2, 723 (2014)
W. Zhang, X. Tao, C. Zhang, Z. Gao, Y. Zhang, W. Yu et al., Syntheses and structures of four pairs of coordination polymers based on 2,2′-((5-(methoxycarbonyl)-1,3-phenylene)bis(oxy))dipropanoic acid. Cryst. Growth Des. 8, 304 (2007)
A. Facchetti, E. Annoni, L. Beverina, M. Morone, P. Zhu, T.J. Marks et al., Very large electro-optic responses in H-bonded heteroaromatic films grown by physical vapour deposition. Nat. Mater. 3, 910 (2004)
A. Schouten, M. Lutz, l-Alanine methyl ester hydrochloride monohydrate. Acta Cryst. E65, o3026 (2009)
C. Lee, W. Yang, R.G. Parr, Development of the Colle–Salvetti correlation-energy formula into a functional of the electron density. Phys. Rev. B 37, 785 (1988)
Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., et al., Gaussian 03, Revision A.1, Gaussian Inc., Pittsburgh, PA (2003)
RO.MU. Jauhar, S. Kalainathan, P. Murugakoothan, Three dimensional organic framework of 2-amino 4,6 dimethoxypyrimidine p-toluenesulfonic acid monohydrate: synthesis, single crystal growth and its properties. J. Cryst. Growth 424, 42 (2015)
Y.R. Sharma, Organic Spectroscopy and Applications (S. Chand Publications, India, 1980)
C.H. Choi, M. Kertez, Conformational information from vibrational spectra of styrene, trans-stilbene, and cis-stilbene. J. Phys. Chem. A 101, 3823 (1997)
RO.MU. Jauhar, P. Murugakoothan, Optimization, frontier molecular orbitals and dielectric studies on 2,6-diaminopyridiniumtosylate single crystals. AIP Conf. Proc. 1832, 100005 (2017)
RO.MU. Jauhar, Mudasir H. Dar, P. Vivek, D. Narayana Rao, P. Murugakoothan, Investigations on the growth, linear, nonlinear, dielectric tensor and thermal properties of an acidic molecule: diphenylacetic acid single crystal. J. Opt. (2017). https://doi.org/10.1007/s12596-017-0418-x
D. Ashkenasi, M. Lorenz, R. Stoian, A. Rosenfeld, Surface damage threshold and structuring of dielectrics using femtosecond laser pulses: the role of incubation. Appl. Surf. Sci. 150, 101 (1999)
N.L. Boling, M.D. Crisp, G. Dube, Laser induced surface damage. Appl. Opt. 12, 650 (1973)
P. Krishnan, K. Gayathri, P.R. Rajakumar, V. Jayaramakrishnan, S. Gunasekaran, G. Anbalagan, Studies on crystal growth, vibrational, optical, thermal and dielectric properties of new organic nonlinear optical crystal: bis(2,3-dimethoxy-10-oxostrychnidinium) phthalate nonahydrate single crystal. Spectrochim. Acta Part A 131, 114 (2014)
P. Vivek, P. Murugakoothan, Second- and third-order optical studies of 4-bromoanilinium hydrogen phthalate single crystal for nonlinear optical device applications. Appl. Phys. A 115, 1139 (2014)
R.L. Fork, O.E. Martinez, J.P. Gordon, Negative dispersion using pairs of prisms. Opt. Lett. 9, 150 (1984)
C.B. Ponton, R.D. Rawlings, Vickers indentation fracture toughness test. Part 2: application and critical evaluation of standardised indentation toughness equations. Mater. Sci. Technol. 5(14), 865 (1989)
E.M. Onitsch, Microscopia. Observations on the sintering of AAP. Powder Metall. 2, 131 (1947)
S.K. Kurtz, T.T. Perry, A powder technique for the evaluation of nonlinear optical materials. J. Appl. Phys. 36, 3798 (1968)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Arunkumar, R., Benny Anburaj, D., Vivek, P. et al. Synthesis, growth, frontier molecular orbitals, fracture mechanics and nonlinear optical studies of l-serine methyl ester hydrochloride single crystal. J Opt 47, 374–379 (2018). https://doi.org/10.1007/s12596-018-0456-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12596-018-0456-z