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Crystal growth, spectral, thermal, optical and third order nonlinearity studies of optical material: 4-N,N-dimethylamino 4′-N′-methylstilbazolium 4-hydroxybenzenesulfonate

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Abstract

4-N,N-dimethylamino 4′-N′-methylstilbazolium 4-hydroxybenzenesulfonate (DSHS) was synthesized by metathesization of N,N-dimethylamino-N′-methylstilbazolium iodide salt with sodium 4-hydroxybenzenesulfonate. The counter anion exchange reaction mechanism of the stilbazolium salt was executed. The growth of DSHS single crystal was carried out by adopting solution growth technique. X-ray diffraction studies classified the synthesized compound into the monoclinic system with P21/c space group. FTIR spectral analysis confirmed the existence of hydroxyl and sulfonate groups and their corresponding vibrational modes. TG–DTA measurement showed the thermal stability of the compound which is having three decomposition stages with the melting point at 312.6 °C. UV–Vis spectral analysis showed the existence of wide transmission window. PL spectral study revealed the transition mechanism of ions, where a sharp peak observed at 603 nm respectively. Laser induced damage threshold was studied for the grown crystal. Third order nonlinear optical property of DSHS crystal was studied by Z-scan test.

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Authors and Affiliations

  1. Department of Physics, Presidency College, Chennai, 600 005, India

    I. Md Zahid, S. Kalaiyarasi, S. Reena Devi, S. Suresh, T. Ganesh & R. Mohan Kumar

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  1. I. Md Zahid
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  2. S. Kalaiyarasi
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  3. S. Reena Devi
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  4. S. Suresh
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  5. T. Ganesh
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Correspondence to R. Mohan Kumar.

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Md Zahid, I., Kalaiyarasi, S., Reena Devi, S. et al. Crystal growth, spectral, thermal, optical and third order nonlinearity studies of optical material: 4-N,N-dimethylamino 4′-N′-methylstilbazolium 4-hydroxybenzenesulfonate. J Opt 46, 456–464 (2017). https://doi.org/10.1007/s12596-017-0406-1

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  • DOI: https://doi.org/10.1007/s12596-017-0406-1

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