Abstract
Hydogrochemical investigation of groundwater resources of Paragraph district has been carried out to assess the solute acquisition processes and water quality for domestic and irrigation uses. Fifty-five groundwater samples were collected and analyzed for pH, electrical conductivity, total dissolved solids, hardness, major anions (F−, Cl−, NO3, HCO3 −, SO4 2−) and cations (Ca2+, Mg2+, Na+, K+). Study results reveal that groundwater of the area is alkaline in nature and HCO3 −, Cl−, Mg2+, Na+ and Ca2+ are the major contributing ions to the dissolved solids. The hydrogeochemical data suggest that weathering of rock forming minerals along with secondary contributions from agricultural and anthropogenic sources are mainly controlling the groundwater composition of Pratapgarh district. Alkaline earth metals (Ca2++Mg2+) exceed alkalis (Na++K+) and weak acid (HCO3 −) dominate over strong acids (Cl−+SO4 2−) in majority of the groundwater samples. Ca-Mg-HCO3 and Ca-Mg-Cl-HCO3 are the dominant hydrogeochemical facies in the groundwater of the area. The computed saturation indices demonstrate oversaturated condition with respect to dolomite and calcite and undersaturated with gypsum and fluorite. A comparison of groundwater quality parameters in relation to specified limits for drinking water shows that concentrations of TDS, F−, NO3 − and total hardness exceed the desirable limits in many water samples. Quality assessment for irrigation uses reveal that the groundwater is good for irrigation. However, values of salinity, sodium adsorption ratio (SAR), residual sodium carbonate (RSC), %Na and Kelley index are exceeding the prescribed limit at some sites, demanding adequate drainage and water management plan for the area.
This is a preview of subscription content, access via your institution.
References
Andre, L., Franceschi, M., Pouchan, P. and Atteia, O. (2005) Using geochemical data and modeling to enhance the understanding of groundwater flow in a regional deep aquifer, Aquitaine Basin, south-west of France. Jour. Hydrol., v.305, pp.40–62.
APHA (1998) Standard methods for the examination of water and wastewater, (20th ed.), American Public Health Association, Washington DC.
Appelo, C.A.J. and Postma, D. (1996) Geochemistry, groundwater and pollution; AA Balkema Publ., U.S.A.
Ayers, R.S. and Westcot, D.W. (1985) Water quality for irrigation. FAO Irrigation and Drainage Paper No.20, Rev 1, FAO Rome.
Berner, E.K. and Berner, R.A. (1987) The global water cycle: geochemistry and environment, Prentice-Hall, Englewood Cliffs.
Bhardwaj, V. and Singh, D.S. (2011) Surface and groundwater quality characterization of Deoria District, Ganga Plain, India. Environ. Earth Sci., v.63, pp.383–395.
BIS (2003) Indian standard drinking water specifications IS 10500:1991, edition 2.2 (2003–2009); Bureau of Indian Standards, New Delhi.
Cerling, T.E., Pederson, B.L. and Damm, K.L.V. (1989) Sodiumcalcium ion exchange in the weathering of shales: implication for global weathering budgets. Geology, v.17, pp.552–554.
CGWB (2010) Groundwater quality in shallow aquifers of India. Central Ground Water Board, Faridabad, India. p.117.
Choubisa, S.L. (2001) Endemic fluorosis in southern Rajasthan, India. Fluoride, v.34, pp.61–70.
Collins, R. and Jenkins, A. (1996) The impact of agricultural land use on stream chemistry in the middle hills of the Himalayas, Nepal. Jour. Hydrol., v.185, pp.71–86.
CPCB (2008) Status of groundwater quality in India-Part II.: Groundwater Quality Series: GWQS/10/2007–2008. Central Pollution Control Board, New Delhi, p.431.
Datta, P.S. and Tyagi, S.K. (1996) Major ion chemistry of groundwater of Delhi area: chemical weathering processes and groundwater flow regime. Jour. Geol. Soc. India, v.47, pp.179–188.
Deutsch, W.J. (1997) Groundwater geochemistry: fundamentals and application to contamination. CRC Press, Boca Raton.
Drever, J.I. (1988) The geochemistry of natural waters. Prentice-Hall, Englewood Cliffs.
Eaton, F.M. (1950) Significance of carbonates in irrigation waters. Soil Sci., v.39, pp.123–133.
Fisher, R. and Mullican, W.F. (1997) Hydrochemical evolution of sodium sulphate and sodium chloride groundwater beneath the Northern Chihuahuan desert, Trans-Pecos, Rexas, USA. Hydrogeol. Jour., v.10, pp.455–474.
Freeze, R.A. and Cherry, J.A. (1979) Groundwater. Prentice-Hall, Englewood Cliffs.
García, M.G., Del, V., Hidalgo, M. and Blessa, M.A. (2001) Geochemistry of groundwater in the alluvial plain of Tucuman province, Argentina. Hydrogeol. Jour., v.9, pp.597–610.
Garrels, R.M. and Mackenzie, F.T. (1971) Gregor’s denudation of the continents. Nature, v.231, pp. 382–383.
Ghosh, A. (2007) Current knowledge on the distribution of arsenic in groundwater in five states of India. Jour. Environ. Sci. Health, Part-A, v.42, pp.1–12.
Handa, B.K. (1975) Geochemistry and genesis of fluoride containing groundwater in India. Ground Water, v.13, pp.275–281.
Hem (1991) Study and interpretation of the chemical characteristics of natural water. US Geochemical Survey Water Supply Paper 2254, Scientific Publishers, India
Hounslow, A.W. (1995) Water quality data: analysis and interpretation. CRC Lewis Publ, New York, USA, p.396.
Jacks, G., Bhattacharya, P., Choudhary, V. and Singh K.P. (2005) Controls on the genesis of some high fluoride groundwaters in India. Appl. Geochem., v.20, pp.221–228.
Jalali, M. (2007) Assessment of the chemical components of Famenin groundwater, western Iran. Environ. Geochem. Health, v.29, pp.357–374.
Karanth, K.R. (1989) Groundwater assessment development and management. Tata McGraw-Hill Publ. Com. Ltd. New Delhi, India.
Kelley, W.P. (1946) Permissible composition and concentration of irrigation waters. In: Proc. Amer. Soc. Civil Engg., p. 607.
Kumar, G. (2005) Geology of Uttar Pradesh and Uttaranchal. Geological Society of India, Bangalore, India.
Kumar, R., Singh, R.D. and Sharma, K.D. (2005) Water resources of India. Curr. Sci., v.89, pp.794–811.
Loizidou, M. and Kapetanios, E.G. (1993) Effects of leachates from landfills on underground water quality. Sci. Total Environ. v.128, pp.69–81.
Madhunure, P., Sirsikarm, D.Y., Tiwari, A.N., Ranjan, B. and Malpe, D.B. (2007) Occurrence of fluoride in groundwaters of Pandharkawada area, Yavatmal district, Maharashtra, India. Curr. Sci. v.92, pp.675–679.
Majumdar, D. and Gupta, N. (2000) Nitrate pollution of groundwater and associated human health disorders. Ind. Jour. Environ. Health, v.2, pp.28–39.
Maragella, M., Vitale, C., Petrarulo, M., Rovera, L. and Dutto, F. (1996) Effects of mineral composition of drinking water on risk for stone formation and bone metabolism in idiopathic calcium nephrolithiasis. Clinical Science, v.91, pp.313–318.
Mclean, W., Jankowski, J. and Lavitt, N. (2000) Groundwater quality and sustainability in an alluvial aquifer, Australia. In: O. Sililo et al. (Eds.), Groundwater, past achievements and future challenges (pp. 567–573), Balkema, Rotterdam.
Misra, A.K. and Mishra, A. (2007) Study of quaternary aquifers in Ganga plain, India: Focus on groundwater salinity, fluoride and fluorosis. Jour. Hazard. Mater., v.144, pp.438–448.
Njitchoua, R. and Ngounou, N.B. (1997) Hydrogeochemistry and environmental isotope investigations of the North Diamare plain, Northern Cameroon. Jour. African Earth Sci., v.25, pp.307–316.
Paliwal, K.V. (1967) Effects of gypsum application on the quality of irrigation water; The Madras Agr. Jour. v.59, pp.646–647.
Parkhurst, D.L. and Appelo, C.A.J. (1999) User’s guide to PHREEQC (ver.2) — A computer program for speciation, batchreaction, one-dimensional transport, and inverse geochemical calculations, U.S. Geol. Sur. Water Resources Investigations Report, 99-4259, p.310.
Piper, A.M. (1944) A graphical procedure in the geochemical interpretation of water analysis. Am. Geophys. Union. Trans., v.25, pp.914–928.
Raju, J.N., Dey, S. and Das, K. (2009) Fluoride contamination in groundwaters of Sonbhadra district, Uttar Pradesh, India. Curr. Sci., v.96, pp.979–985.
Raju, J.N., Shukla, U.K. and Ram, P. (2011) Hydrogeochemistry for the assessment of groundwater quality in Varanasi: a fasturbanizing center in Uttar Pradesh, India. Environ. Monit. Assess., v.173, pp.279–300.
Rao, N.S. (2003) Groundwater quality — focus on fluoride concentration in rural parts of Guntur district, Andhra Pradesh, India. Hydrol. Sci. Jour., v.45, pp.835–847.
Reddy, D.V., Nagabhushanam, P. and Perters, E. (2011) Village environs as source of nitrate contamination in groundwater: a case study in basaltic geo-environment in central India. Environ. Monit. Assess., v.174, pp.481–492.
Rose (2002) Comparative major ion geochemistry of piedmont streams in the Atlanta, Georgia region: possible effects of urbanization. Environ. Geol., v.42, pp.102–113.
Sami, K. (1992) Recharge mechanisms and geochemical processes in a semi-arid sedimentary basin, Eastern Cape, South Africa. Jour. Hydrol., v.139, pp.27–48.
Sarin, M.M., Krishnaswamy, S., Dilli, K., Somayajulu, B.L.K. and Moore, W.S. (1989) Major ion chemistry of the Ganga -Brahmaputra river system: weathering processes and fluxes to the Bay of Bengal. Geochim. Cosmochim. Acta., v.53, pp.997–1009.
Sawyer, C.N. and Mccarty, P.L. (1967) Chemistry of sanitary engineers. 2nd edn. McGraw Hill, New York, USA
Saxena, V.K. and Ahmed, S. (2001) Dissolution of fluoride in groundwater: a water-rock interaction study. Environ. Geol., v.40, pp.1084–1087.
Saxena, V.K. and Ahmed, S. (2003) Inferring the chemical parameters for the dissolution of fluoride in groundwater. Environ. Geol., v.43, pp.731–736.
Schoeller, H. (1977) Geochemistry of Groundwater. In: Groundwater Studies-An International Guide for Research and Practice. UNESCO, Paris Ch.15:1–18.
Siever, R. and Woodward, N. (1973) Sorption of silica by clay minerals. Geochim. Cosmochim. Acta., v.37, pp.1851–1880.
Singh, R.B. (2000) Environmental consequences of agricultural development: a case study from the Green Revolution state Haryana, India. Agric. Ecosys Environ., v.82, pp.97–103.
Singh, V.K., Bikundia, D.S., Sarswat, A. and Mohan, D. (2012) Groundwater quality assessment in the village of LutfullapurNawada, Loni, District Ghaziabad, Uttar Pradesh, India. Environ. Monit. Assess., v.184, pp.4473–4488.
Singh, A.K., Mondal, G.C., Singh, P.K., Singh, S., Singh, T.B. and Tewary, B.K. (2005) Hydrochemistry of reservoirs of Damodar River basin, India: weathering processes and water quality assessment. Environ. Geol., v.8, pp.1014–1028.
Singh, A.K., Mondal, G.C., Kumar, S., Singh, T.B., Tewary, B.K. and Sinha, A. (2008) Major ion chemistry, weathering processes and water quality assessment in upper catchment of Damodar River basin, India. Environ. Geol., v.54, pp.745–758.
Srikanth, R. (2009) Challenges of sustainable water quality management in rural India. Curr. Sci., v.3, pp.317–325.
Stumm, W., and Morgan, J.J. (1981) Aquatic chemistry. Wiley Interscience, New York
Stumm, W. (1992) Chemistry of the soild water interface. Wiley Interscience, New York
Subramanian, V. (1974) Water chemistry of the St. Lawrence River. Maritime Sediments, v.10, pp.97–105.
Subramanian, V. (2000) Water: quantity-quality perspectives in South Asia. Kingston International Publishers Ltd. Surrey, UK.
Susheela, A.K. (1999) Fluorosis management programme in India. Curr. Sci., v.77, pp.1259–1256.
Susheela, A.K., Kumar, A., Bhatnagar, M. and Bahadur, M. (1993) Prevalence of endemic fluorosis with gastrointestinal manifestations in people living in some north-Indian villages. Fluoride, v.26, pp.97–104.
Teotia, S.P.S. and Teotia, M. (1984) Endemic fluorosis in India: challenging national health problem. Jour. Assoc. Phys. India. v.32, pp.347–352.
Umar, R., Khan, M.M.A. and Absar, A. (2006) Groundwater hydrochemistry of a sugarcane cultivation belt in parts of Muzaffarnagar district, Uttar Pradesh, India Environ. Geol., v.49, pp.999–1008.
USSL (US Salinity Laboratory) (1954). Diagnosis and improvement of saline and alkali soils. U.S. Department of Agriculture Hand Book, No. 60, p.160.
Vidal, M., Melgar, J., Opez, A.L. and Santoalla, M.C. (2000) Spatial and temporal hydrochemical changes in groundwater under the contaminating effects of fertilizers and wastewater. Jour. Environ. Manag., v.60, pp.215–225.
WHO (2006) Guidelines for drinking-water quality, V.1, Recommendations, World Health Organisation, Geneva.
Wilcox, L.V. (1955) Classification and use of irrigation waters, US Dept of Agricul Cir 969, Washington DC.
Yadav, H.R. (2009) Village development planning. Logos Press, New Delhi.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Tiwari, A.K., Singh, A.K. Hydrogeochemical investigation and groundwater quality assessment of Pratapgarh district, Uttar Pradesh. J Geol Soc India 83, 329–343 (2014). https://doi.org/10.1007/s12594-014-0045-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12594-014-0045-y
Keywords
- Pratapgarh district
- Groundwater quality
- Hydrogeochemical processes
- Sodium percent
- Sodium adsorption ratio
- Residual sodium carbonate
- Kelley index
- Uttar Pradesh