Abstract
In this work, the rheological properties of thermoplastic starch (TPS) were determined using a laboratory scale single screw extruder at different temperatures (110, 130, and 140 °C) and speeds (10, 15, 20, 25, 30, and 35 RPM). Glycerol was used as a plasticizer for preparing TPS. Apparent shear rate (\( {{\mathop{\gamma}\limits^{\cdot}}_a} \)), apparent shear stress (τ a ), apparent shear viscosity (η a ) and flow activation energy at a constant shear rate (E γ ) were determined. The results showed that TPS melts were pseudo plastic (n < 1) and the shear viscosity decreases with increasing shear rate at different temperatures. Also it was found that that shear viscosity of TPS decreases with increasing glycerol content in TPS, according to the values of flow activation energy at a constant shear rate, TPS25 was more sensitive to processing temperature.
Similar content being viewed by others
References
Liu H, Xie F, Yu L, Chen L, Li L (2009) Thermal processing of starch-based polymers. Prog Polym Sci 34:1348–1368
Carvalho A, Job A, Alves N, Curvelo A, Gandini A (2003) Thermoplastic starch/ natural rubber blends. Carbohydr Polym 53:95–99
Gonzalez F, Ramasy B, Favis B (2004) Rheological and thermal properties of thermoplastic starch with high glycerol content. Carbohydr Polym 58:139–147
Rosa D, Guedes C, Carvalho C (2007) Processing and thermal, mechanical and morphological characterization of post-consumer polyolefins/thermoplastic starch blends. J Mater Sci 42:551–557
Teixeira E, Roz A, Carvalho A, Curvelo A (2007) The effect of glycerol/sugar/water and water mixtures on the plasticization of thermoplastic cassava starch. Carbohydr Polym 69:619–624
Bourtoom T (2008) Plasticizer effect on the properties of biodegradable blend film from rice starch- chitosan", Songklankarain. J Sci Technol 30(suppl1):149–165
Yang J, Jiugao Y, Ma X (2006) A novel plasticizer for the preparation of thermoplastic starch. Chine Chem Lett 17:133–136
Yang J, Jiugao Y, Ma X (2006) Preparation and properties of ethylenebisformamide plasticized potato starch (EPTPS). Carbohydr Polym 63:218–223
Yang J, Jiugao Y, Ma X (2006) Study on the properties of ethylenebisformamide and sorbitol plasticized corn starch (ESPTPS). Carbohydr Polym 66:110–116
Wang N, Jiugao Y, Chang P, Ma X (2008) Influence of formamide and water on the properties of thermoplastic starch/poly(lactic acid) blends. Carbohydr Polym 71:109
Ma X, Jiugao Y, Wan J (2006) Urea and ethanolamine as a mixed plasticizer for thermoplastic starch. Carbohydr Polym 64:267–273
Ma X, Jiugao Y (2004) The plasticizers containing amide groups for thermoplastic starch. Carbohydr Polym 57:197–203
Wang N, Jiugao Y, Ma X (2007) Ying. W., "The influence of citric acid on the properties of thermoplastic starch/linear low- density polyethylene blends". Carbohydr Polym 67:446–453
Tajuddin S, Xie F, Nicholson T, Liu P, Halley P (2011) Rheological properties of thermoplastic starch studied by multipass rheometer. Carbohydr Polym 83:914–919
Willett J, Jasberg B, Swanson C (1995) Rheology of thermoplastic starch: Effects of temperature, moisture content, and additives on melt viscosity. Polym Eng Sci 35:202–210
Jiugao Y, Wang N, Ma X (2005) The effects of citric acid on the properties of thermoplastic starch plasticized by glycerol. Starch 57:494–504
Han C (2007) Rheology and processing of polymeric materials (Polymer Rheology). Oxford University Press, New York
Han C (1971) Measurement of the rheological properties of polymer melts with slit rheometer. I. Homopolymer systems. J Appl Polym Sci 15:2567–2577
Han C (1974) Rheological properties of calcium carbonate-filled polypropylene melts. J Appl Polym Sci 18:821–829
Eswaran R, Janeschitz-Kriegl H, Schijf J (1963) A slit viscometer for polymer melts. Rheol Acta 3:83–91
Macosko C (1994) Rheology principles measurements and applications. New York VCH, New York
Han C, Charles M (1971) Measurement of axial pressure distribution of molten polymers in flow through a rectangular duct. Trans Soc Rheol 15:147–161
Gonzalez F, Ramsay B, Favis B (2003) High performance LDPE/thermoplastic starch blends: a sustainable alternative to pure polyethylene. Polymer 44(5):1517
Willett J, Millard M, Jasberg B (1997) Extrusion of waxy maize starch: Melt rheology and molecular weight degradation of amylopectin. Polymer 38(24):5983
Ong NS, Koh YH (2005) Experimental investigation into micro injection molding of plastic part. Mater Manuf Process 20(2):245
Acknowledgement
The authors are grateful to Dr. Ahmed Flaah (Damascus University – Department of Chemistry) for his aid in completing this work.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kaseem, M., Hamad, K. & Deri, F. Slit die rheology of thermoplastic starch during extrusion process. Int J Plast Technol 17, 51–60 (2013). https://doi.org/10.1007/s12588-013-9044-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12588-013-9044-x