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Corrosion Behavior of Alloy 22 According to Hydrogen Sulfide, Chloride, and pH in an Anaerobic Environment

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Abstract

The corrosion behavior of Alloy 22 (UNS N06022) according to the hydrogen sulfide, chloride, and pH in an anaerobic environment was investigated through electrochemical tests, surface analyses, and response surface methodology (RSM). Complex corrosion behavior model according to the HS− ion and Cl− ion concentrations and pH was obtained through RSM. The Cl− ion and pH had minimal effects on the corrosion behavior of Alloy 22. Meanwhile, the corrosion behavior of Alloy 22 changed significantly with increased HS− ion concentration. As the HS− ion concentration increases, sulfide ions are adsorbed on the metal surface, increasing the anodic dissolution of metal and suppressing the formation of Cr2O3 passive film, thereby deteriorating the passive properties of Alloy 22. Simultaneously, Mo in Alloy 22 forms MoS2, which acts as a pseudo-passive film to alleviate the corrosion resistance deterioration caused by HS− ions.

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Acknowledgements

This research was supported by the SungKyunKwan University and the BK21 FOUR (Graduate School Innovation) funded by the Ministry of Education (MOE, Korea) and National Research Foundation of Korea (NRF), as well as the Nuclear Research & Development Program of the National Research Foundation of Korea (NRF) funded by the Korea government Ministry of Science and ICT (MSIT) (NRF-2021M2E1A1085195).

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  1. School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, 16419, Republic of Korea

    Yun-Ho Lee, Jin-Seok Yoo, Yong-Won Kim & Jung-Gu Kim

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YHL: Conceptualization, Methodology, Validation, Formal analysis, Investigation, Resources, Writing—Original Draft, Writing—Review and Editing, Visualization. JSY: Conceptualization, Methodology, Data Curation, Writing—Review and Editing. YWK: Methodology, Validation, Data Curation, Writing—Review and Editing. JGK: Conceptualization, Methodology, Writing—Review and Editing, Supervision, Project administration, Funding acquisition.

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Lee, YH., Yoo, JS., Kim, YW. et al. Corrosion Behavior of Alloy 22 According to Hydrogen Sulfide, Chloride, and pH in an Anaerobic Environment. Met. Mater. Int. (2024). https://doi.org/10.1007/s12540-023-01624-2

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