Abstract
This paper optimizes experimental parameters on controlling corrosion performance of the Mg-rare-earth alloys with long period stacking ordered structure using response surface methodology. Different NaCl concentrations, temperatures, and varying pH values are selected as input parameters. The corrosion current density (icorr) and open circuit potential (OCP) are used as the multiple responses to evaluate the corrosion performances. The corrosion surface morphology and corrosion mechanism of the Mg alloys are also investigated by scanning electron microscopy for the optimization. Analysis of variance (ANOVA) has given the impact of individual factors and interactions on the corrosion rate. The results indicated that the three test parameters had significant impacts in controlling the corrosion behavior of Mg alloy. Moreover, the increased NaCl concentration decreased the pitting potential (Epit) of the target materials. Filiform corrosion can be detected in high pH solutions, whereas the matrix suffered from severe dissolution phenomenon in low pH solutions. High temperature aggravated the local destruction and dissolution of the protective film. The interaction of the experimental parameters showed a sizable influence on corrosion performance.
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C. Zhao, X. Chen, F. Pan, J. Wang, S. Gao, T. Tu, C. Liu, J. Yao, A. Atrens, J. Mater. Sci. Technol. 35, 142 (2019)
R. Rakesh, S. Bontha, R. Rames, M. Das, V. Balla, Appl. Surf. Sci. 480, 70 (2019)
L. Wang, J. Jiang, A. Ma, Y. Li, D. Song, Metals 7, 324 (2017)
B. Saleh, J. Jiang, R. Fathi, Q. Xu, L. Wang, A. Ma, Arch. Civ. Mech. Eng. 20, 71 (2020)
R. Fathi, A. Ma, B. Saleh, Q. Xu, J. Jiang, Mater. Today Commun. 24, 101169 (2020)
Y. Wu, C. Liu, H. Liao, J. Jiang, A. Ma, J. Alloy. Compd. 856, 158072 (2021)
B. Saleh, J. Jiang, Q. Xu, R. Fathi, A. Ma, Y. Li, L. Wang, Met. Mater. Int. (2020). https://doi.org/10.1007/s12540-020-00624-w
B.J. Wang, D.K. Xu, S.D. Wang, L.Y. Sheng, R.C. Zeng, E. Han, Int. J. Fatigue 120, 46 (2019)
H. Liu, H. Huang, J. Sun, C. Wang, J. Bai, A. Ma, X. Chen, Acta. Metall. Sin. Engl. 32, 269 (2019)
H. Liu, J. Ju, X. Yang, J. Yan, D. Song, J. Jiang, A. Ma, J. Alloy. Compd. 704, 509 (2017)
G. Garces, P. Pérez, R. Barea, J. Medina, A. Stark, N. Schell, P. Adeva, Metals 9, 221 (2019)
C. Ding, X. Hu, H. Shi, W. Gan, K. Wu, X. Wang, J. Magnes. Alloy. (2020). https://doi.org/10.1016/j.jma.2020.05.012
H. Liu, C. Sun, C. Wang, Y. Li, J. Bai, F. Xue, A. Ma, J. Jiang, J. Mater. Sci. Technol. 59, 61 (2020)
K. Hagihara, Z. Li, M. Yamasaki, Y. Kawamura, T. Nakano, Acta Mater. 163, 226 (2019)
Y. Kawamura, K. Hayashi, A. Inoue, T. Masumoto, Mater. Trans. 42, 1172 (2001)
A. Inoue, Y. Kawamura, M. Matsushita, K. Hayashi, J. Koike, J. Mater. Res. 16, 1894 (2001)
E. Abe, Y. Kawamura, K. Hayashi, A. Inoue, Acta Mater. 50, 3845 (2002)
K. Hagihara, A. Kinoshita, Y. Sugino, M. Yamasaki, Y. Kawamura, H. Yasuda, Y. Umakoshi, Acta Mater. 58, 6282 (2010)
Y. Zhu, A. Morton, J. Nie, Acta Mater. 60, 6562 (2012)
L. Wang, J. Jiang, H. Liu, B. Saleh, A. Ma, J. Magnes. Alloy. 8, 1208 (2020)
L. Wang, J. Jiang, T. Yuan, Q. Xie, H. Liu, A. Ma, Met. Mater. Int. 26, 551 (2020)
L. Wang, J. Jiang, B. Saleh, Q. Xie, Q. Xu, H. Liu, A. Ma, Acta. Metall. Sin. Engl. 33, 1180 (2020)
D. Xu, E. Han, Y. Xu, Prog. Nat. Sci. 26, 117 (2016)
J. Wang, W. Jiang, Y. Ma, Y. Li, S. Huang, Mater. Chem. Phys. 203, 352 (2018)
S. Izumi, M. Yamasaki, Y. Kawamura, Mater. Sci. Forum 654–656, 767 (2010)
Z. Leng, J. Zhang, T. Yin, L. Zhang, X. Guo, Q. Peng, M. Zhang, R. Wu, J. Mech. Behav. Biomed. 28, 332 (2013)
M. Zhao, M. Liu, G. Song, A. Atrens, Corros. Sci. 50, 3168 (2008)
G. Song, A. Atrens, D. John, X. Wu, J. Nairn, Corros. Sci. 39, 1981 (1997)
G. Song, A. Atrens, D. Stjohn, J. Nairn, Y. Li, Corros. Sci. 39, 855 (1997)
M. Song, R. Zeng, Y. Ding, R.W. Li, M. Easton, I. Cole, N. Birbilis, X. Chen, J. Mater. Sci. Technol. 35, 535 (2019)
J. Liu, L. Yang, C. Zhang, B. Zhang, T. Zhang, Y. Li, K. Wu, F. Wang, J. Alloy. Compd. 782, 648 (2019)
S. Inoue, M. Yamasaki, Y. Kawamura, Corros. Sci. 149, 133 (2019)
J. Liu, L. Yang, C. Zhang, B. Zhang, T. Zhang, Y. Li, K. Wu, F. Wang, J. Mater. Sci. Technol. 35, 1644 (2019)
L. Bao, Q. Le, Z. Zhang, C. Esling, Mater. Lett. 235, 189 (2019)
A. Hänzi, I. Gerber, M. Schinhammer, J. Löffler, P. Uggowitzer, Acta Biomater. 6, 1824 (2010)
Z. Huan, M.A. Leeflang, J. Zhou, L.E. Fratila-Apachitei, J. Duszczyk, J. Mater. Sci. Mater. Med. 21, 2623 (2010)
Z. Cui, X. Li, C. Man, K. Xiao, C. Dong, X. Wang, Z. Liu, J. Mater. Eng. Perform. 24, 2885 (2015)
T. Zhang, Y. Yang, Y. Shao, G. Meng, F. Wang, Electrochem. Acta 54, 3915 (2009)
F. Rosalbino, S. De Negri, A. Saccone, E. Angelini, S. Delfino, J. Mater. Sci. Mater. Med. 21, 1091 (2010)
F. Cao, Z. Shi, G. Song, M. Liu, M. Dargusch, A. Atrens, Corros. Sci. 90, 176 (2015)
M. Zhao, M. Liu, G. Song, A. Atrens, Corros. Sci. 50, 1939 (2008)
S. Prithivirajan, S. Narendranath, V. Desai, J. Magnes. Alloy. 8, 1128 (2020)
Z. Shi, F. Cao, G. Song, M. Liu, A. Atrens, Corros. Sci. 76, 98 (2013)
M. Bezerra, R. Santelli, E. Oliveira, L. Villar, L. Escaleira, Talanta 76, 965 (2008)
M. Taheri, J. Kish, N. Birbilis, M. Danaie, E. McNally, J. McDermid, Electrochem. Acta 116, 396 (2014)
M. Pannach, S. Bette, D. Freyer, J. Chem. Eng. Data 62, 1384 (2017)
G. Song, Adv. Eng. Mater. 7, 563 (2005)
G. Song, A. Atrens, Adv. Eng. Mater. 9, 177 (2007)
G. Song, K.A. Unocic, Corros. Sci. 98, 758 (2015)
Z. Shi, J. Jia, A. Atrens, Corros. Sci. 60, 296 (2012)
G. Frankel, A. Samaniego, N. Birbilis, Corros. Sci. 70, 104 (2013)
N. Birbilis, M. Easton, A. Sudholz, S. Zhu, M. Gibson, Corros. Sci. 51, 683 (2009)
A. Dhanapal, S. Boopathy, V. Balasubramanian, J. Alloy. Compd. 523, 49 (2012)
S. Feliu, L. Veleva, F. García-Galvan, Metals 9, 591 (2019)
S. Johnston, Z. Shi, A. Atrens, Corros. Sci. 101, 182 (2015)
A. Atrens, G. Song, M. Liu, Z. Shi, F. Cao, M. Dargusch, Adv. Eng. Mater. 17, 400 (2015)
D. Thirumalaikumarasamy, K. Shanmugam, V. Balasubramanian, J. Magnes. Alloy. 2, 36 (2014)
K. Ralston, G. Williams, N. Birbilis, Corrosion 68, 507 (2012)
M. Esmaily, M. Shahabi-Navid, J. Svensson, M. Halvarsson, L. Nyborg, Y. Cao, L. Johansson, Corros. Sci. 90, 420 (2015)
P.M. Natishan, W.E. O'Grady, J. Electrochem. Soc. 161, C421 (2014)
G. Frankel, J. Electrochem. Soc. 145, 2186 (1998)
M. Danaie, R. Asmussen, P. Jakupi, D. Shoesmith, G. Botton, Corros. Sci. 77, 151 (2013)
M. Esmaily, D. Blücher, J. Svensson, M. Halvarsson, L.G. Johansson, Scripta Mater. 115, 91 (2016)
Acknowledgements
The study was supported by the National Natural Science Foundation of China (Grant Nos. 51774109, 51979099 and 51901068), Natural Science Foundation of Jiangsu Province of China (Grant No. BK 20191303), The Key Research and Development Project of Jiangsu Province of China (Grant No. BE2017148), Public Service Platform Program of Suqian City of China (Grant No. M201614).
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Wang, L., Jiang, J., Saleh, B. et al. Optimization of the Experimental Parameters Affecting the Corrosion Behavior for Mg–Y–Zn–Mn Alloy via Response Surface Methodology. Met. Mater. Int. 27, 5095–5107 (2021). https://doi.org/10.1007/s12540-020-00958-5
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DOI: https://doi.org/10.1007/s12540-020-00958-5