Skip to main content
Log in

Lab-evaluation of applicability selected hydrogeological tracers in physical/chemical conditions

  • Original Paper
  • Published:
Arabian Journal of Geosciences Aims and scope Submit manuscript

Abstract

In this research, the effects of a number of physical/chemical factors such as pH, sunlight, temperature, and salinity, as well as adsorption in porous media on the applicability of selected groundwater tracers are evaluated. Tracers from different categories as fluorescent dye tracers (uranine, eosin, and rhodamine B), chemical salts (NaCl and KCl), and non-fluorescent dye tracer (KMnO4) have been tested. This research was conducted in the laboratory. The results show that uranine losses its florescence in acid environments, while in alkaline conditions its florescence increases. The results also show that due to photochemical decay, eosin is the most unstable tracer if subjected to sunlight. KMnO4 turns to brown under sunlight and high temperature conditions, and may lose its usefulness as a tracer. Results also confirm that the fluorescence intensity of rhodamine B decreases with increasing temperature and/or salinity. Uranine and eosin have high resistance against high temperature and salinity conditions. An important factor in ground water tracing is adsorption of tracer in porous media environment. Our research show that rhodamine B would easily adsorb to fine grain porous media, while uranine and eosin are of high resistance against adsorption; KMnO4 is adsorbed easily too.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  • Ammann A, Hoehn E, Koch S (2003) Ground water pollution by roof runoff infiltration evidenced. Water Res 37:1143–1153

    Article  Google Scholar 

  • Arsnow GF, Vancil MA, Schreiber RP, Ramacciotti CN (2010) Dye tracer study—tried and true method yields surprising results. Proc Annu Int Conf Soil Sediments Water Energy 15:335–350

    Google Scholar 

  • Benischke R (2005) Fluorescent tracers in hydrology. Austria: Institute for Geothermic and Hydrogeology, Graz

  • Buzády A, Erostyák J, Paál G (2006) Determination of uranine tracer dye from underground water of Mecsek Hill, Hungary. J Biochem Bioph Methods 69:207–214

    Article  Google Scholar 

  • Davis SN, Campbell D, Bentley HW, Flynn TJ (1985) Ground water tracers. National Water Well Association, Worthington Ohio

    Google Scholar 

  • Einsiedl F (2005) Flow system dynamics and water storage of a fissured-porous karst. J Hydrol 312:312–321

    Article  Google Scholar 

  • Gerke KM, Sidle RC, Mallants D (2013) Criteria for selecting fluorescent dye tracers for soil hydrological applications using uranine as an example. J Hydrol Hydromech 61(4):313–325

    Article  Google Scholar 

  • Imes JL, Fredrick BS (2002) Using dye-tracing and chemical analyses to determine effects of a wastewater discharge to Jam Up Creek on water quality of Big Spring, Southeastern Missouri. U.S. Geol. Surv. Fact Sheet 103-02: 6

  • Käss W (1998) Tracing Technique in Geohydrology. Germany: Umkirch, LKr. Breisgau-Hochschwarzwald

  • Leibundgut Ch, Maloszewski P and Külls Ch (2009) Tracers in Hydrology. John Wiley & Sons: 432

  • Lindqvist L (1960) A flash photolysis study of fluorescein. Ark Kemi 16(8):79–137

    Google Scholar 

  • Mon J, Flury M, Harsh JB (2006) Sorption of four trarylmethan dyes in a sandy soil determined by batch and column experiments. J Geoderma 133:217–224

    Article  Google Scholar 

  • Morales T, Valderrama IF, Uriarte JA, Antigüedad I, Olazarn M (2007) Predicting travel times and transport characterization in karst conduits by analyzing tracer breakthrough curves. J Hydrol 334(1–2):183–198

    Article  Google Scholar 

  • Seiler K, Maloszewski P, Behrens H (1989) Hydrodynamic dispersion in karstified limestones and dolomites in the upper Jurassic of the Franconia Alb. J Hydrol 108:235–247

    Article  Google Scholar 

  • Smart PL, Laidlaw IMS (1977) An evaluation of some fluorescent dyes for water tracing. J Water Resour Res 13(1):15–33

    Article  Google Scholar 

Download references

Acknowledgment

The authors wish to thank Water Resources Institute of Iran, Office of Applied Research for financially supporting this research coded WRE-82097.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Fateme Jafari.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jafari, F., Balderer, W.P., Jahani, H.R. et al. Lab-evaluation of applicability selected hydrogeological tracers in physical/chemical conditions. Arab J Geosci 8, 3811–3819 (2015). https://doi.org/10.1007/s12517-014-1428-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12517-014-1428-5

Keywords

Navigation