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Magnetic signature of sewage polluted river sediments

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Abstract

The present study was designed to characterize the magnetic proxy for sewage-related pollution from river sediments. A suite of mineral magnetic analyses including low-field magnetic susceptibility, isothermal remanent magnetization (IRM) acquisition and demagnetization, back-field IRM treatment, and thermal demagnetization of composite IRMs are carried out for topsoil samples collected from river sediments in Daejeon, South Korea. A 350-m long in situ profile of magnetic susceptibility shows a background mean magnetic susceptibility of 22.4 ± 5.6 × 10−5 SI. The coercivity spectra display dual peaks of lower- and higher-coercivity fractions. The predominance of magnetic signal with maximum unblocking temperatures of 580 °C points to magnetite as the sole magnetic mineral. Hence the lower- and higher-coercivity fractions correspond to coarse-grained and fine-grained magnetite, respectively. Extraordinarily high magnetic susceptibility was observed from BTC02, near to the sewage discharge point. However, its mineral magnetic properties and particle morphologies are not different to those of other soil samples. Then, it is apparent that a high magnetic susceptibility simply reflects the high concentration of magnetites in BTC02. It is likely that a continuous discharge of heavy metal enriched water at the discharging point concentrated significant amount of magnetic particles. It is fortunate that anomalously high magnetic susceptibility (by implication heavy metal concentrations) diminished only several meters away from the discharge point. Perhaps, influences of anthropogenic magnetite were diluted as the high magnetic phases were washed away from the water cycles along the river. In practice, it can be proposed that a periodic replacement of soils near the sewage discharge point is efficient to reduce the heavy metal concentrations.

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Acknowledgments

The authors declare that they have no competing financial interests. All relevant data is contained within the article. The original contributions presented in the study are included in the article/supplementary material. This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (NRF-2018R1A2B6001094).

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  1. Department of Astronomy, Space Science and Geology, Chungnam National University, Daejeon, 34134, Republic of Korea

    Hanul Kim, Raegyung Ha & Yongjae Yu

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Kim, H., Ha, R. & Yu, Y. Magnetic signature of sewage polluted river sediments. Geosci J 25, 685–696 (2021). https://doi.org/10.1007/s12303-020-0056-1

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