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Peat-accumulation models affected by the transgression-regression: a case study of mineralogy and geochemistry of the Permo-Carboniferous coals in the Lingshi Deposit, Qinshui Basin, China

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Abstract

Mineralogy and geochemistry of Nos.1, 9 and 10 coals in the Lingshi Deposit, Qinshui Basin, China, are investigated in this paper, using industrial analysis, total sulfur and forms of sulfur analyses, optical microscope, scanning electron microscope equipped with energy dispersive X-ray spectrometer, X-ray powder diffraction, X-ray fluorescence, and inductively coupled plasma-mass spectrometers. The results show that the minerals in coals are mainly kaolinite, nacrite, dickite, palygorskite, calcite, pyrite, anatase, dolomite, siderite and barite. Kaolinite of terrigenous origin is commonly discovered in No. 1 coal, which results in a high concentration of SiO2 (up to 6.81%) and Al2O3 (up to 8.42%); In the process of coalification, kaolinite could be converted into dickite and nacrite in Nos. 9 and 10 coal; Pyrite, the host of W, Tl, and As, and palygorskite in Nos. 9 and 10 coals are formed under the influence of the transgression. Besides, Nos. 9 and 10 coals, affected by transgression, are similar in the element contents and distribution patterns with positive δYN anomalies (up to 1.44). However, No. 1 coal, normalized by No. 10 coal, is characterized by high concentration coefficients of Co, Ni, Sb, Li, Be, Sc, V, Cu, Ga, Rb, Cs, Ba, Pb and Th (2 < CC < 10), and these elements are derived from clay minerals of terrigenous origin, which means that Permo-Carboniferous coals in the Lingshi Deposit show the evolution of a regressive process in general.

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References

  • Barker, C.E. and Pawlewicz, M.J., 1994, Calculation of vitrinite reflectance from thermal histories and peak temperatures. In: Mukhopadhyay, P.K. and Dow, W.G. (eds.), Vitrinite Reflectance as a Maturity Parameter. American Chemical Society, Washington, DC, p. 216–229.

    Chapter  Google Scholar 

  • Bau, M. and Dulski, P., 1995, Comparative study of yttrium and rareearth element behaviours in fluorine-rich hydrothermal fluids. Contributions to Mineralogy and Petrology, 119, 213–223.

    Article  Google Scholar 

  • Beek, P.V., Reyss, J.L., Bonte, P., and Schmidt, S., 2003, Sr/Ba in barite: a proxy of barite preservation in marine sediments? Marine Geology, 199, 205–220.

    Article  Google Scholar 

  • Cullers, R.L., 2000, The geochemistry of shales, siltstones and sandstones of Pennsylvanian-Permian age, Colorado, USA: implications for provenance and metamorphic studies. Lithos, 51, 181–203.

    Article  Google Scholar 

  • Chen, P.Y., Wang, M.K., and Yang, D.S., 2001, Mineralogy of dickite and nacrite from northern Taiwan. Clays & Clay Minerals, 49, 586–595.

    Article  Google Scholar 

  • China Coal Research Institute, 2008, GB/T 482-2008. Sampling of Coal Seams; Chinese National Standard. General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, Beijing, 2008. (in Chinese)

    Google Scholar 

  • Coleman, M.L., Berner, R.A., Durand, B., Meadows, P.S., and Eglinton, G., 1985, Geochemistry of diagenetic non-silicate minerals kinetic considerations (and discussion). Philosophical Transactions of the Royal Society A, 315, 55–56.

    Article  Google Scholar 

  • Dai, S.F., Tian, L.W., Chou, C.L., Zhou, Y.P., Zhang, M.Q., Zhao, L., Wang, J.M., Yang, Z., Cao, H.Z., and Ren, D.Y., 2008, Mineralogical and compositional characteristics of Late Permian coals from an area of high lung cancer rate in Xuan Wei, Yunnan, China: occurrence and origin of quartz and chamosite. International Journal of Coal Geology, 76, 318–327.

    Article  Google Scholar 

  • Dai, S.F., Ren, D.Y., Chou, C.L., Finkelman, R.B., Seredin, V.V., and Zhou, Y., 2012, Geochemistry of trace elements in Chinese coals: a review of abundances, genetic types, impacts on human health, and industrial utilization. International Journal of Coal Geology, 94, 3–21.

    Article  Google Scholar 

  • Dai, S., Li, T., Seredin, V.V., Ward, C.R., Hower, J.C., Zhou, Y., Zhang, M., Song, X., Song, W., and Zhao, C., 2014, Origin of minerals and elements in the Late Permian coals, tonsteins, and host rocks of the Xinde Mine, Xuanwei, eastern Yunnan, China. International Journal of Coal Geology, 121, 53–78.

    Article  Google Scholar 

  • Dai, S.F., Seredin, V.V., Ward, C.R., Hower, J.C., Xing, Y.W., Zhang, W.G., Song, W.J., and Wang, P.P., 2015, Enrichment of U-Se-Mo-Re-V in coals preserved within marine carbonate successions: geochemical and mineralogical data from the Late Permian Guiding Coalfield, Guizhou, China. Mineralium Deposita, 50, 159–186.

    Article  Google Scholar 

  • Dai, S.F., Graham, I.T., and Ward, C.R., 2016, A review of anomalous rare earth elements and yttrium in coal. International Journal of Coal Geology, 159, 82–95.

    Article  Google Scholar 

  • Dai, S.F., Xie, P.P., Jia, S.H., Ward, C.R., Hower, J.C., Yan, X.Y., and French, D., 2017, Enrichment of U-Re-V-Cr-Se and rare earth elements in the Late Permian coals of the Moxinpo Coalfield, Chongqing, China: genetic implications from geochemical and mineralogical data. Ore Geology Reviews, 80, 1–17.

    Article  Google Scholar 

  • De, B.J., Dani, N., Ketzer, J.M., and De, R.L.F., 2008, Dickite in shallow oil reservoirs from Recôncavo Basin, Brazil: diagenetic implications for basin evolution. Clay Minerals, 43, 213–233.

    Article  Google Scholar 

  • Dera, G., Pellenard, P., Neige, P., Deconinck, J.F., Puceat, E., and Dommergues, J.L., 2009, Distribution of clay minerals in Early Jurassic Peritethyan seas: palaeoclimatic significance inferred from multiproxy comparisons. Palaeogeography Palaeoclimatology Palaeoecology, 271, 39–51.

    Article  Google Scholar 

  • Diessel, C.F.K., 1982, An appraisal of coal facies based on maceral characteristics. Australian Coal Geology, 4, 474–484.

    Google Scholar 

  • Diessel, C.F.K., 1992, Coal-bearing Depositional Systems. Springer, Berlin, 721 p.

    Book  Google Scholar 

  • Diessel, C.F.K., 2004, Utility of coal petrology for sequence-stratigraphic analysis. International Journal of Coal Geology, 70, 3–34.

    Article  Google Scholar 

  • Ehrenberg, S.N., Aagaard, P., Wilson, M.J., Fraser, A.R., and Duthie, D.M.L., 1993, Depth-dependent transformation of kaolinite to dickite in sandstones of the Norwegian Continental shelf. Clay minerals, 28, 325–352.

    Article  Google Scholar 

  • Elderfield, H. and Greaves, M.J., 1982, The rare earth elements in seawater. Nature, 296, 214–219.

    Article  Google Scholar 

  • Erdenetsogt, B.O., Lee, I., Bat-Erdene, D., and Jargal, L., 2009, Mongolian coal-bearing basins: geological settings, coal characteristics, distribution, and resources. International Journal of Coal Geology, 80, 87–104.

    Article  Google Scholar 

  • Finkelman, R.B., 1995, Modes of occurrence of environmentally-sensitive trace elements in coal. In: Swaine, D.J. and Goodarzi, F. (eds.), Environmental Aspects of Trace Elements in Coal. Kluwer Academic Publishers, Dordrecht, p. 24–55.

    Chapter  Google Scholar 

  • Graham, I.T., Pogson, R.E., Colchester, D.M., Hergt, J., Martin, R., and Williams, P.A., 2007, Pink lanthanite-(Nd) from Whitianga Quarry, Coromandel Peninsula, New Zealand. Canadian Mineralogist, 45, 1389–1396.

    Article  Google Scholar 

  • Gurba, L.W. and Ward, C.R., 2000, Elemental composition of coal macerals in relation to vitrinite reflectance, Gunnedah Basin, Australia, as determined by electron microprobe analysis. International Journal of Coal Geology, 44, 127–147.

    Article  Google Scholar 

  • Han, B.P., 1998, Study on Microkarstification Mechanism. Geological Publishing House, Beijing, 74 p. (in Chinese)

    Google Scholar 

  • Hower, J.C., Ruppert, L.F., and Eble, C.F., 1999, Lanthanide, yttrium, and zirconium anomalies in the Fire Clay coal bed, Eastern Kentucky. International Journal of Coal Geology, 39, 141–153.

    Article  Google Scholar 

  • Hower, J.C., O’Keefe, J.M.K., Eble, C.F., Raymond, A., Valentim, B., Volk, T.J., Richardson, A.R., Satterwhite, A.B., Hatch, R.S., Stucker, J.D., and Watt, M.A., 2011a, Notes on the origin of inertinite macerals in coal: evidence for fungal and arthropod transformations of degraded macerals. International Journal of Coal Geology, 86, 231–240.

    Article  Google Scholar 

  • Hower, J.C., O’Keefe, J.M.K., Eble, C.F., Volk, T.J., Richardson, A.R., Satterwhite, A.B., Hatch, R.S., and Kostova, I.J., 2011b, Notes on the origin of inertinite macerals in coal: funginite associations with cutinite and suberinite. International Journal of Coal Geology, 85, 186–190.

    Article  Google Scholar 

  • Huang, C.M. and Zhou Q.F., 1987, Control of thickness and distribution of coal seams by sedimentary environments in mine area of Huo County, Huoxi Coal Basin, Shanxi Province. Journl of China Coal Society, 73, 918–924. (in Chinese with English abstract)

    Google Scholar 

  • Kevin, H.J. and Zhou, X., 1997, Geochemistry of the rare earth elements in natural terrestrial waters: a review of what is currently known. Acta Geochimica, 1997, 20–42.

    Google Scholar 

  • Ketris, M.P. and Yudovich, Y.E., 2009, Estimations of clarkes for carbonaceous biolithes: world averages for trace element contents in black shales and coals. International Journal of Coal Geology, 78, 135–148.

    Article  Google Scholar 

  • Kogure, T., Elzea, K.J., Johnston, C.T., and Bish, D.L., 2010, Stacking disorder in a sedimentary kaolinite. Clays and Clay Minerals, 58, 62–71.

    Article  Google Scholar 

  • Liang, J.S., Wang, C.W., Liu, Y.H., Gao, Y.J., Feng, R.Y., Zhu, X.S., and Yu, J., 2014, Study on the tight gas accumulation conditions and exploration potential in the Qinshui Basin. Natural Gas Geoscience, 25, 1509–1519. (in Chinese with English abstract)

    Google Scholar 

  • Lim, D.L., Jung, H.S., Yang, S.Y., and Yoo, H.S., 2004, Sewuential growth of early diagenetic freshwater siderites in the Holocene coastal deposits, Korea. Sedimentary Geology, 169, 107–120.

    Article  Google Scholar 

  • Liu, B., Huang, W.H., Ao, W.H., Yan, D.Y., Xu, Q.L., and Teng, J., 2015, Geochemistry characteristics of rare earth elements in the late Paleozoic coal from Qinshui Basin. Journal of China Coal Society, 40, 2916–2926. (in Chinese with English abstract)

    Google Scholar 

  • Liu, B., Huang, W.H., Ao, W.H., Yan, D.Y., Xu, Q.L., and Teng, J., 2016, Geochemistry characteristcs of sulfur and its affect on hazardous elements in the Late Paleozoic coal from the Qinshui Basin. Earth Science Frontiers, 23, 59–67. (in Chinese with English abstract)

    Google Scholar 

  • Liu, D.M., Yao, Y.N., Tang, D.Z., Tang, S.H., Che, Y., and Huang, W.H., 2009, Coal reservoir characteristics and coalbed methane resource assessment in Huainan and Huaibei coalfields, Southern North China. International Journal of Coal Geology, 79, 97–112.

    Article  Google Scholar 

  • Metcalfe, I., 2006, Palaeozoic and Mesozoic tectonic evolution and palaeogeography of East Asian crustal fragments: The Korean Peninsula in context. Gondwana Research, 9, 24–46.

    Article  Google Scholar 

  • McAulay, G.E., Burley, S.D., Fallick, A.E., and Kusznir, N.J., 1994, Palaeohydrodynamic fluid flow regimes during diagenesis of the Brent Group in the Hutton-NW Hutton reservoirs: constraints from oxygen isotope studies of authigenic kaolin and reverse flexural modeling. Clay Minerals, 29, 609–626.

    Article  Google Scholar 

  • McLennan, S.M., 2001, Relationship between the trace element composition of sedimentary rocks and upper continental crust. Geochemistry Geophysics Geosystems, 2, 203–236.

    Article  Google Scholar 

  • Pearson, M.J.,1979, Geochemistry of the Hepworth Carboniferous sediment sequence and origin of the diagenetic iron minerals and concretions. Geochimica et Cosmochimica Acta, 43, 927–941.

    Article  Google Scholar 

  • Pfefferkorn, H.W. and Wang, J., 2007, Early Permian coal-forming floras preserved as compressions from the Wuda District (Inner Mongolia, China). International Journal of Coal Geology, 69, 90–102.

    Article  Google Scholar 

  • Renton, J.J. and Bird, D.S., 1991, Association of coal macerals, sulfur, sulfur species and the iron disulphide minerals in three columns of the Pittsburgh coal. International Journal of Coal Geology, 17, 21–50.

    Article  Google Scholar 

  • Righi, D. and Meunier, A., 1995, Origin of clays by rock weathering and soil formation. In: Velde, B. (ed.), Origin and Mineralogy of Clays. Springer, Berlin, p. 43–161.

    Chapter  Google Scholar 

  • Rimmer, S.M. and Davis, A., 1986, Geologic controls on the inorganic composition of Lower Kittanning coal. In: Vorres, K.S. (ed.), Mineral Matter in Coal. American Chemical Society Symposium Series, 301, p. 41–51.

    Chapter  Google Scholar 

  • Seredin, V.V., 1998, Rare earth mineralization in Late Cenozoic explosion structures (Khanka massif, Primorskii Krai, Russia). Geology of Ore Deposits, 40, 357–371.

    Google Scholar 

  • Seredin, V.V., 2001, Major regularities of the REE distribution in coal. Doklady Earth Sciences, 377, 250–253.

    Google Scholar 

  • Seredin, V.V., 2005, Rare earth elements in germanium-bearing coal seams of the Spetsugli Deposit (Primor’e Region, Russia). Geology of Ore Deposits, 47, 238–255.

    Google Scholar 

  • Seredin, V.V. and Finkelman, R.B., 2008, Metalliferous coals: a review of the main genetic and geochemical types. International Journal of Coal Geology, 76, 253–289.

    Article  Google Scholar 

  • Seredin, V.V. and Dai, S.F., 2012, Coal deposits as potential alternative sources for lanthanides and yttrium. International Journal of Coal Geology, 94, 67–93.

    Article  Google Scholar 

  • Seto, M. and Akagi, T., 2008, Chemical condition for the appearance of a negative Ce anomaly in stream waters and groundwaters. Geochemical Journal, 42, 371–380.

    Article  Google Scholar 

  • Shadfan, H. and Dixon, J.B., 1984, Occurrence of palygorskite in the soils and rocks of the Jordan Valley. Developments in Sedimentology, 37, 187–198.

    Article  Google Scholar 

  • Shao, L.Y., Xiao Z.H., He Z.P., Liu Y.F., Shang L.J., and Zhang P.F., 2006, Palaeogeography and coal accumulation for coal measures of the Carboniferous-Permian in Qinshui Basin, southeastern Shanxi Province. Journal of Palaeogeography, 8, 43–52. (in Chinese with English abstract)

    Google Scholar 

  • Shealy, M. and Dorian, J.P., 2010, Growing Chinese coal use: dramatic resource and environmental implications. Energy Policy, 38, 2116–2122.

    Article  Google Scholar 

  • Silva, M.B. and Kalkreuth, W., 2005, Petrological and geochemical characterization of Candiota coal seams, Brazil — implication for coal facies interpretations and coal rank. International Journal of Coal Geology, 64, 217–238.

    Article  Google Scholar 

  • Singer, A., 1979, Palygorskite in sediments: detrital, diagenetic or neoformed — a critical review. Geologische Rundschau, 68, 996–1008.

    Article  Google Scholar 

  • Singer, A., 1984, Pedogenic palygorskite in the arid environment. Developments in Sedimentology, 37, 169–176.

    Article  Google Scholar 

  • So, Y.S., Rhee, C.W., Choi, P.Y., Kee, W.S., Seo, J.Y., and Lee, E.J., 2013, Distal turbidite fan/lobe succession of The Late Paleozoic Taean Formation, Western Korea. Geosciences Journal, 17, 9–25.

    Article  Google Scholar 

  • Stefanova, M., Markova, K., Marinov. S., and Simoneit, B.R.T., 2005, Molecular indicators for coal-forming vegetation of the Miocene Chukurovo lignite, Bulgaria. Fuel, 84, 1830–1838.

    Article  Google Scholar 

  • Swaine, D.J., 1990, Trace Elements in Coal. Butterworths, London, 278 p.

    Google Scholar 

  • Wang, S., 1996, Coal Accumulation and Coal Resources Evaluation of Ordos Basin, China. China Coal Industry Publishing House, Beijing, 437 p. (in Chinese with English abstract)

    Google Scholar 

  • Ward, C.R., Matulis, C.E., Taylor, J.C., and Dale, L.S., 2001, Quantification of mineral matter in the Argonne Premium coals using interactive Rietveld-based X-ray diffraction. International Journal of Coal Geology, 46, 67–82.

    Article  Google Scholar 

  • Ward, C.R., 2002, Analysis and significance of mineral matter in coal seams. International Journal of Coal Geology 50, 135–168.

    Article  Google Scholar 

  • Webb, G.E. and Kamber, B.S., 2000, Rare earth elements in Holocene reefal microbialites: a new shallow seawater proxy. Geochimica et Cosmochimica Acta, 64, 1557–1565.

    Article  Google Scholar 

  • Yan, M.C., Chi, Q.H., Gu, T.X., and Wang, C.S., 1997, Chemical composition of upper crust in eastern China. Science China Earth Sciences, 40, 530–539.

    Article  Google Scholar 

  • Zhang, J., Amakawa, H., and Nozaki, Y., 1994, The comparative behaviors of yttrium and lanthanides in the seawater of the North Pacific. Geophysical Research Letters, 21, 2677–2680.

    Article  Google Scholar 

  • Ziegler, K., 2006, Clay minerals of the Permian Rotliegend Group in the North Sea and adjacent areas. Clay Minerals, 41, 355–393.

    Article  Google Scholar 

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Zou, Y., Zhao, F., Liu, D. et al. Peat-accumulation models affected by the transgression-regression: a case study of mineralogy and geochemistry of the Permo-Carboniferous coals in the Lingshi Deposit, Qinshui Basin, China. Geosci J 22, 777–791 (2018). https://doi.org/10.1007/s12303-017-0080-y

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