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Manipulating functional groups between polyvinylidene difluoride and nanoparticles for high-performance triboelectric nanogenerator

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Abstract

Interface functional groups play an essential role in regulating the electrical properties of bulk materials. In this work, we designed a novel strategy to explore a new way to enhance triboelectric performance by regulating the functional groups between nano-fillers and polymer matrix without obvious changes in the dielectric constant. The silica nanoparticles (SNPs) modified perfluoro-silane coupling agents (PFSCAs) with different chain lengths were added to the polyvinylidene difluoride to regulate the transferred charge density (TCD) of triboelectric nanogenerators (TENGs). When the doping concentration of perfluorodecyl modified SNPs is 2.25 wt.%, the nanocomposite film based TENG exhibits the maximum TCD of 166 µC/m2 and power density of 3.12 W/m2 which are 6 times and 39 times as big as those of pure polyvinylidene difluoride (PVDF) film. The charge accumulation and decay process show that interface functional groups dominate the performance of TENGs. Then, a Fermi level model is proposed and why the TCD could be regulated by the concentration of nanoparticles in bulk materials is explained. This work provides a new concept for understanding the performance of TENG independent dielectric constant and points out a new direction for enhancing TENG’s performance, since wealthy functional groups with selectivity are applicable.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 52073032 and 51872031) and the Fundamental Research Funds for the Central Universities (No. JB211305).

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Author notes

  1. Zekun Li and Lu Zhang contributed equally to this work.

Authors and Affiliations

  1. CAS Center for Excellence in Nanoscience, Beijing Key Laboratory of Micro-Nano Energy and Sensor, Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing, 101400, China

    Zekun Li, Aifang Yu & Junyi Zhai

  2. School of Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing, 100049, China

    Zekun Li, Aifang Yu & Junyi Zhai

  3. School of Advanced Materials and Nanotechnology, Interdisciplinary Research Center of Smart Sensors, Xidian University, Xi’an, 712000, China

    Lu Zhang & Lihao Guo

  4. School of Aerospace Science and Technology, Xidian University, Xi’an, 712000, China

    Wenwen Hu

Authors
  1. Zekun Li
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  2. Lu Zhang
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  3. Lihao Guo
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  4. Wenwen Hu
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  5. Aifang Yu
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  6. Junyi Zhai
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Corresponding authors

Correspondence to Wenwen Hu, Aifang Yu or Junyi Zhai.

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12274_2023_5426_MOESM1_ESM.pdf

Manipulating functional groups between polyvinylidene difluoride and nanoparticles for high-performance triboelectric nanogenerator

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Li, Z., Zhang, L., Guo, L. et al. Manipulating functional groups between polyvinylidene difluoride and nanoparticles for high-performance triboelectric nanogenerator. Nano Res. 16, 11855–11861 (2023). https://doi.org/10.1007/s12274-023-5426-8

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  • DOI: https://doi.org/10.1007/s12274-023-5426-8

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